US4175175A
Expired / Lapsed
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Polyarylene polyethers
Assignee: BP Corp North America Inc
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Filing: 1978-05-08
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Granted: 1979-11-20
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Expires: 1998-05-08
Abstract
Abstract Polyarylene polyethers composed of recurring units -O-E-O-E'- where E is the residuum of a dihydric phenol and E' is the residuum of a benzenoid compound having an inert electron withdrawing group ortho or para to the valence bonds and where both E and E' are bonded to the ether oxygens through aromatic carbon atoms. The polyarylene polyethers are prepared by reacting a double alkali metal salt of a dihydric phenol with a dihalobenzenoid compound in the presence of certain sulfoxide or sulfone solvents under substantially anhydrous conditions.
Inventors
- 👤 Robert N. Johnson
- 👤 Alford G. Farnham
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 04:22
CPC Classifications
C; C08; C08G; C08G75/00; C08G75/20; C08G75/23; C08G65/00; C08G65/34; C08G65/38; C08G65/40; C08G65/4006; C08G65/4012; C08G65/4018; C08G65/4025
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
134 words
A substantially linear thermoplastic polyarylene polyether composed of recurring units of the general formula: --O--E--O--E'-- where E is the residuum of a dihydric phenol and E' is the residuum of a benzenoid compound having an electron withdrawing group in at least one of the positions ortho and para to the valence bonds, having a sigma* value sufficient to activate halogens in the said valence positions to a level adequate to react with an alkali metal phenolate; wherein both of said residua are valently bonded to ether oxygens through aromatic carbon atoms, with the proviso that E may not be the residuum of a bis(hydroxyphenyl) sulfone where E' is the residuum of bis(halophenyl) sulfone and with the further proviso that E may not be the residuum of hydroxybenzohydroxyphenone when E' is the residuum of halobenzohalophenone.
Claim 2
Dependent Claim
134 words
A substantially linear thermoplastic polyarylene polyether composed of recurring units of the general formula: --O--E--O--E'-- where E is the residuum of a dihydric phenol and E' is the residuum of a benzenoid compound having an electron withdrawing group in at least one of the positions ortho and para to the valence bonds, having a sigma* value sufficient to activate halogens in the said valence positions to a level adequate to react with an alkali metal phenolate; wherein both of said residua are valently bonded to ether oxygens through aromatic carbon atoms, with the proviso that E may not be the residuum of a bis(hydroxyphenyl) sulfone where E' is the residuum of bis(halophenyl) sulfone and with the further proviso that E may not be the residuum of hydroxybenzohydroxyphenone when E' is the residuum of halobenzohalophenone.
Claim 3
Dependent Claim
35 words
A substantially linear thermoplastic polyarylene polyether as described in claim 1 wherein E is a polynuclear residuum in which both valence bonds to ether oxygens are attached to aromatic carbon atoms of different aromatic nuclei.
Claim 4
Dependent Claim
17 words
A substantially linear thermoplastic polyarylene polyether as described in claim 1 wherein E is a mononuclear residuum.
Claim 5
Dependent Claim
39 words
A substantially linear thermoplastic polyarylene polyether as described in claim 2 or claim 3 in which E' is a polynuclear residuum in which both valence bonds to ether oxygens are attached to aromatic carbon atoms of different aromatic nuclei.
Claim 6
Dependent Claim
20 words
A substantially linear thermoplastic polyarylene polyether as described in claim 2 or claim 3 wherein E' is a mononuclear residuum.
Claim 7
Dependent Claim
27 words
A substantially linear thermoplastic polyarylene polyether as described in claim 3 or claim 5 wherein said inert electron withdrawing group is nitro, cyano phenylsulfone, trifluoromethyl or nitroso.
Claim 8
Dependent Claim
64 words
The process for preparing substantially linear polyarylene polyethers which comprises reacting essentially stoichiometric amounts of an alkali metal double salt of a dihydric phenol with a dihalobenzenoid compound wherein said halogen atoms are activated by an inert electron withdrawing group in at least one of the positions ortho and para to the said halogen atoms to a level sufficient to react with said salt.
Claim 9
Dependent Claim
64 words
The process for preparing substantially linear polyarylene polyethers which comprises reacting essentially stoichiometric amounts of an alkali metal double salt of a dihydric phenol with a dihalobenzenoid compound wherein said halogen atoms are activated by an inert electron withdrawing group in at least one of the positions ortho and para to the said halogen atoms to a level sufficient to react with said salt.
Claim 10
Dependent Claim
70 words
A substantially linear thermoplastic polyarylene polyether which comprises the reaction product of essentially stoichiometric amounts of an alkali metal double salt of one or more dihydric phenol compounds and one or more dihhalobenzenoid compounds wherein said halogen atoms are activated by an inert electron withdrawing group in at least one of the positions ortho and para to the said halogen atoms to a level sufficient to react with said salt.
Claim 11
Dependent Claim
70 words
A substantially linear thermoplastic polyarylene polyether which comprises the reaction product of essentially stoichiometric amounts of an alkali metal double salt of one or more dihydric phenol compounds and one or more dihhalobenzenoid compounds wherein said halogen atoms are activated by an inert electron withdrawing group in at least one of the positions ortho and para to the said halogen atoms to a level sufficient to react with said salt.
Claim 12
Dependent Claim
81 words
The process for preparing substantially linear polyarylene polyethers which comprises combining a dihydric phenol and at least two equivalents of an alkali metal base followed by addition of an essentially stoichiometric amount of a dihalobenzenoid compound wherein the halogen substituents of said dihalobenzenoid compound are activated by an inert electron withdrawing group in at least one position ortho or para to the said halogen substituents to a level sufficient to react with an alkali metal salt of a dihydric phenol compound.
Claim 13
Dependent Claim
81 words
The process for preparing substantially linear polyarylene polyethers which comprises combining a dihydric phenol and at least two equivalents of an alkali metal base followed by addition of an essentially stoichiometric amount of a dihalobenzenoid compound wherein the halogen substituents of said dihalobenzenoid compound are activated by an inert electron withdrawing group in at least one position ortho or para to the said halogen substituents to a level sufficient to react with an alkali metal salt of a dihydric phenol compound.
Claim 14
Dependent Claim
113 words
A substantially linear thermoplastic polyarylene polyether composed of recurring units of the general formula: --O--E--O--E'-- where E is the residuum of a dihydric phenol and E' is the residuum of a benzenoid compound having an electron withdrawing group in at least one of the positions ortho and para to the valence bonds, having a sigma* value sufficient to activate halogens in the said valence positions to a level adequate to react with an alkali metal phenolate; wherein both of said residua are valently bonded to ether oxygens through aromatic carbon atoms, with the proviso that E may not be the residuum of a bis(hydroxyphenyl) sulfone where E' is the residuum of bis(halophenyl) sulfone.
Claim 15
Dependent Claim
113 words
A substantially linear thermoplastic polyarylene polyether composed of recurring units of the general formula: --O--E--O--E'-- where E is the residuum of a dihydric phenol and E' is the residuum of a benzenoid compound having an electron withdrawing group in at least one of the positions ortho and para to the valence bonds, having a sigma* value sufficient to activate halogens in the said valence positions to a level adequate to react with an alkali metal phenolate; wherein both of said residua are valently bonded to ether oxygens through aromatic carbon atoms, with the proviso that E may not be the residuum of a bis(hydroxyphenyl) sulfone where E' is the residuum of bis(halophenyl) sulfone.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-11-19 | 1983-05-21 | 1983-11-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-11-19 | 1987-05-21 | 1987-11-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-11-19 | 1991-05-21 | 1991-11-20 | $7700.00 | Window Closed / Lapsed |