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US4175059A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of preparing a novel platelet-type crystalline form of synthetic faujasite

Assignee: WR Grace and Co
•
Filing: 1978-08-07
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Granted: 1979-11-20
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Expires: 1998-08-07
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Abstract

Abstract A process for preparing a synthetic faujasite having a novel platelet-type crystalline shape and a silica to alumina ratio above 2.2 by adding potassium ions to a seeded faujasite synthesis slurry and heating to convert to the synthetic faujasite. The use of the novel zeolite form as a catalyst promoter and an adjuvant for strengthening formed zeolite such as beads, balls, pills and extrudates is also disclosed.

Inventors

  • 👤 Grant C. Edwards
  • 👤 David E. W. Vaughan
  • 👤 Edwin W. Albers

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 12:29
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/08; C; C01; C01B; C01B39/00; C01B39/02; C01B39/20; Y; Y10; Y10S; Y10S423/00; Y10S423/21

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 196 words
In a process for preparing synthetic faujasite type zeolites wherein amorphous aluminosilicate zeolite nucelation centers having a particle size of below 0.1 microns are combined with a zeolite producing reaction mixture which contains alumina, silica, alkali metal hydroxide and water, and the mixture is heated to obtain faujasite type zeolite crystals, the improvement comprising: (a) preparing a reaction mixture containing the following mol ratios of ingredients: Na 2 O/SiO 2 --0.3 to 9 SiO 2 /Al 2 O 3 --3 to 25 H 2 O/Na 2 O--12 to 90 K 2 O/Al 2 O 3 --0.05 to 1.2 (b) adding to said mixture amorphous aluminosilicate zeolite nucleation centers having a particle size of below 0.1 microns, consisting essentially of the following range of composition: Na 2 O--12 to 20 SiO 2 --14 to 19 Al 2 O 3 --0.75-5 H 2 O--100 to 600 (c) heating the reaction mixture at a temperature of 40° to 150° C. for a period of about 10 minutes to 30 hours to obtain a faujasite type zeolite product wherein greater than about 5 percent by weight of the crystals comprising said product are characterized by a platelet flattened octahedron shape.
Claim 2
Dependent Claim 196 words
In a process for preparing synthetic faujasite type zeolites wherein amorphous aluminosilicate zeolite nucelation centers having a particle size of below 0.1 microns are combined with a zeolite producing reaction mixture which contains alumina, silica, alkali metal hydroxide and water, and the mixture is heated to obtain faujasite type zeolite crystals, the improvement comprising: (a) preparing a reaction mixture containing the following mol ratios of ingredients: Na 2 O/SiO 2 --0.3 to 9 SiO 2 /Al 2 O 3 --3 to 25 H 2 O/Na 2 O--12 to 90 K 2 O/Al 2 O 3 --0.05 to 1.2 (b) adding to said mixture amorphous aluminosilicate zeolite nucleation centers having a particle size of below 0.1 microns, consisting essentially of the following range of composition: Na 2 O--12 to 20 SiO 2 --14 to 19 Al 2 O 3 --0.75-5 H 2 O--100 to 600 (c) heating the reaction mixture at a temperature of 40° to 150° C. for a period of about 10 minutes to 30 hours to obtain a faujasite type zeolite product wherein greater than about 5 percent by weight of the crystals comprising said product are characterized by a platelet flattened octahedron shape.
Claim 3
Dependent Claim 48 words
The process of claim 1 wherein said reaction mixture contains the following mol ratios of ingredients: Na 2 O/SiO 2 --0.3 to 1.5 SiO 2 /Al 2 O 3 --3 to 5 H 2 O/Na 2 O--30 to 50 K 2 O/Al 2 O 3 --0.05 to 1.2.
Claim 4
Dependent Claim 48 words
The process of claim 1 wherein said reaction mixture contains the following mol ratios of ingredients: Na 2 O/SiO 2 --0.3 to 9 SiO 2 /Al 2 O 3 --5 to 25 H 2 O/Na 2 O--12 to 90 K 2 O/Al 2 O 3 --0.05 to 1.2.
Claim 5
Dependent Claim 37 words
The process of claim 1 wherein said nucleation centers are included in amounts ranging from about 0.1 to 40 mol percent based on the total amount of alumina in the mixture including that in the nucleation centers.
Claim 6
Dependent Claim 26 words
The process of claim 1 wherein said reaction mixture at step (c) is heated to 60° to 100° C. for about 10 minutes to 30 hours.
Claim 7
Dependent Claim 33 words
A faujasite type zeolite product prepared by way of the process of claim 1 wherein greater than about 5 percent by weight of the crystals are characterized by a platelet flattened octahedron shape.
Claim 8
Dependent Claim 17 words
The zeolite product of claim 6 having a silica to alumina ratio of about 2.2 to 6.
Claim 9
Dependent Claim 25 words
The zeolite product of claim 6 wherein greater than about 90 percent by weight of the crystals are characterized by a platelet flattened octahedron shape.
Claim 10
Dependent Claim 20 words
The zeolite product of claim 6 exchanged with metal ions selected from Group IB through VIII of the periodic table.
Claim 11
Dependent Claim 35 words
An adsorbent composition comprising the zeolite product of claim 6 and up to about 90 percent by weight of an inorganic oxide component selected from the group consisting of silica, alumina, silica-alumina hydrogel and clay.
Claim 12
Dependent Claim 31 words
The adsorbent composition of claim 10 in which the zeolite product is exchanged with metal ions selected from the group consisting of Group IB to Group VIII of the periodic table.
Claim 13
Dependent Claim 11 words
A hydrocarbon conversion catalyst containing the zeolite product of claim 6.
Claim 14
Dependent Claim 12 words
The catalyst of claim 12 which contains an amorphous inorganic oxide matrix.
Claim 15
Dependent Claim 17 words
The catalyst of claim 13 in which the zeolite product is exchanged with rare earth metal ions.
Claim 16
Dependent Claim 23 words
The catalyst of claim 12 exchanged with ions selected from the group consisting of Group IB to Group VIII of the periodic table.

References Cited (Backward Citations)

GB1051621A Cited
US3140251A Cited
US3374058A Cited
GB1111849A Cited
US3574538A Cited
US3767771A Cited
US3808326A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-11-19 1983-05-21 1983-11-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-11-19 1987-05-21 1987-11-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-11-19 1991-05-21 1991-11-20 $7700.00 Window Closed / Lapsed

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