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US4174461A Expired / Lapsed US ⏱️ 0.0 years remaining

Stabilized perfluoropolyether fluids

Assignee: Montedison SpA
•
Filing: 1976-12-10
•
Granted: 1979-11-13
•
Expires: 1996-12-10
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Abstract

Abstract Perfluoropolyether compounds and mixtures thereof having the formula: A-O-(C3F6O)P-(CF2O)Q-(C2F4O)R-CF(Z)-CO-N(R)Ar wherein the perfluoroalkyleneoxy groups are randomly distributed and A is a perfluoroalkyl group or a -CF(Z)-CO-N(R)Ar group; P, Q and R are zero but not simultaneously or numbers from 1 to 100, the sum of P, Q and R being 3 to 200; Z is a fluorine atom or a CF3 group; Ar is an aryl group; and R is hydrogen, alkyl, alkyl-aryl or an aryl group. These compounds are excellent stabilizers for perfluoropolyether fluids of the formula: X-O-(C3F6O)P-(CF2O)q-(C2F4O)r-Y wherein p, q and r are each zero or numbers from 1 to 100, the sum of p, q and r being 6 to 200, and X and Y are the same or different and are perfluoroalkyl groups having 1 to 3 carbon atoms.

Inventors

  • 👤 Dario Sianesi
  • 👤 Giuseppe Nelli
  • 👤 Renzo Fontanelli
  • 👤 Valentino Zamboni

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 08:40
CPC Classifications
C; C07; C07D; C07D213/00; C07D213/02; C07D213/04; C07D213/60; C07D213/72; C07D213/73; C07D277/00; C07D277/02; C07D277/20; C07D277/32; C07D277/38; C07D277/44; C07D277/46; C08; C08G; C08G65/00; C08G65/002; C08G65/005; C08G65/007; C10; C10M; C10M105/00; C10M105/56; C10M105/68; C10M107/00; C10M107/38; C10M111/00; C10M111/04; C10M133/00; C10M133/02; C10M133/16; C10M169/00; C10M169/04; C07C; C07C2603/00; C07C2603/02; C07C2603/04; C07C2603/06; C07C2603/10; C07C2603/12; C07C2603/18; C10M2211/00; C10M2211/06; C10M2213/00; C10M2213/02; C10M2213/023; C10M2213/04; C10M2213/043; C10M2213/06; C10M2213/0606; C10M2213/062; C10M2213/0623; C10M2215/00; C10M2215/08; C10M2215/0806; C10M2215/082; C10M2215/086; C10M2215/10; C10M2215/1006; C10M2215/12; C10M2215/122; C10M2215/22; C10M2215/221; C10M2215/225; C10M2215/226; C10M2215/24; C10M2215/28; C10M2215/285; C10M2215/30; C10M2219/00; C10M2219/10; C10M2219/104; C10M2219/108; C10N; C10N2040/00; C10N2040/30; C10N2040/32; C10N2040/34; C10N2040/36; C10N2040/38; C10N2040/40; C10N2040/42; C10N2040/44; C10N2040/50

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 264 words
A composition comprising (A) at least one perfluoropolyether fluid of the formula: X--O--(C.sub.3 F.sub.6 O).sub.p --(CF.sub.2 O).sub.q --(C.sub.2 F.sub.4 O).sub.r --Y wherein the perfluoroalkyleneoxy groups are randomly distributed along the chain; p, q and r are each zero or a number from 1 to 100 inclusive, the sum of p, q and r being 6 to 200; X and Y are the same or different from each other and are perfluoroalkyl groups having 1 to 3 carbon atoms; and (B) from 0.1 to 50 parts by weight per 100 parts of perfluoropolyether fluid of a perfluoropolyether compound having at least one arylamide terminal group and being of the formula: A--O--(C.sub.3 F.sub.6 O).sub.P --(CF.sub.2 O).sub.Q --(C.sub.2 F.sub.4 O).sub.S --CF(Z)--CO--N(R)Ar wherein if two or more of the perfluoroalkyleneoxy groups, (C 3 F 6 O), (CF 2 O) and C 2 Fhd 4O) are simultaneously present in the chain, they are randomly distributed therealong; and wherein A is a perfluoroalkyl group having 1 to 3 carbon atoms or a --CF(Z)--CO--N(R)Ar group; P, Q and S are each zero but not simultaneously or a number ranging from 1 to 100 inclusive, the sum of P, Q and S being 3 to 200; Z is a fluorine atom or a CF 3 group; Ar is an unsubstituted aryl group, or an aryl group which is mono-, di- or tri-substituted with a lower alkyl group, an alkylaryl group, phenyl or halogen, and R is a hydrogen atom, a lower alkyl group, an unsubstituted phenyl or phenyl group which may be bound to Ar either directly or through a sulfur atom.
Claim 2
Dependent Claim 264 words
A composition comprising (A) at least one perfluoropolyether fluid of the formula: X--O--(C.sub.3 F.sub.6 O).sub.p --(CF.sub.2 O).sub.q --(C.sub.2 F.sub.4 O).sub.r --Y wherein the perfluoroalkyleneoxy groups are randomly distributed along the chain; p, q and r are each zero or a number from 1 to 100 inclusive, the sum of p, q and r being 6 to 200; X and Y are the same or different from each other and are perfluoroalkyl groups having 1 to 3 carbon atoms; and (B) from 0.1 to 50 parts by weight per 100 parts of perfluoropolyether fluid of a perfluoropolyether compound having at least one arylamide terminal group and being of the formula: A--O--(C.sub.3 F.sub.6 O).sub.P --(CF.sub.2 O).sub.Q --(C.sub.2 F.sub.4 O).sub.S --CF(Z)--CO--N(R)Ar wherein if two or more of the perfluoroalkyleneoxy groups, (C 3 F 6 O), (CF 2 O) and C 2 Fhd 4O) are simultaneously present in the chain, they are randomly distributed therealong; and wherein A is a perfluoroalkyl group having 1 to 3 carbon atoms or a --CF(Z)--CO--N(R)Ar group; P, Q and S are each zero but not simultaneously or a number ranging from 1 to 100 inclusive, the sum of P, Q and S being 3 to 200; Z is a fluorine atom or a CF 3 group; Ar is an unsubstituted aryl group, or an aryl group which is mono-, di- or tri-substituted with a lower alkyl group, an alkylaryl group, phenyl or halogen, and R is a hydrogen atom, a lower alkyl group, an unsubstituted phenyl or phenyl group which may be bound to Ar either directly or through a sulfur atom.
Claim 3
Dependent Claim 27 words
A composition as claimed in claim 1, wherein the amount of perfluoropolyether compound is from 1 to 20 parts per 100 parts by weight of perfluoropolyether fluid.

References Cited (Backward Citations)

US3250806A Cited
US3274239A Cited
US3250807A Cited
US3250808A Cited
US3393151A Cited
US3493530A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-11-12 1983-05-14 1983-11-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-11-12 1987-05-14 1987-11-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-11-12 1991-05-14 1991-11-13 $7700.00 Window Closed / Lapsed

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