Patent US5729433A successfully refreshed from Google Patents.
US4174418A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Antibacterial textile finishes utilizing zironyl acetate complexes of inorganic peroxides
Assignee: United States Department of Agriculture
•
Filing: 1978-05-31
•
Granted: 1979-11-13
•
Expires: 1998-05-31
Abstract
Abstract Bacteriostatic, water-insoluble complexes of zirconyl acetate with inorganic peroxides are disclosed. Peroxides operative in forming these complexes are hydrogen peroxide, alkali metal perborates and alkali metal peroxydiphosphates. Processes for in situ formation and deposition of the insoluble complexes on the surfaces of cellulosic textiles are described. The textile finishes so produced inhibit the growth and spreading of odor- and infection-producing gram-negative and gram-positive bacteria on the treated textiles. The antibacterial activity imparted to the textiles is durable to repeated laundering.
Inventors
- 👤 Clark M. Welch
- 👤 Gary F. Danna
- 👤 Tyrone L. Vigo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 22:20
CPC Classifications
D; D06; D06M; D06M16/00; C; C07; C07C; C07C51/00; C07C51/41; C07C51/418; C07C51/42; C07C51/50; C07C53/00; C07C53/08; C07C53/10; D06M13/00; D06M13/10; D06M13/184; D06M13/188; Y; Y10; Y10S; Y10S428/00; Y10S428/907; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2964; Y10T428/2965; Y10T442/00; Y10T442/20; Y10T442/2525
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
234 words
A one-bath process for rendering cellulosic textiles bacteriostatic, which process comprises: (a) preparing an aqueous treating solution containing about from 1% to 35% zirconyl acetate, 0.3% to 35% acetic acid, and 1% to 25% of an inorganic peroxide selected from the class consisting of hydrogen peroxide, an alkali metal perborate monohydrate and an alkali metal perborate tetrahydrate, the solution being made up by adding the inorganic peroxide to a solution of the zirconyl acetate and acetic acid in water, the ratio by weight of acetic acid to zirconyl acetate being from about 0.3:1 to about 5:1, and the mole ratio of zirconyl acetate to inorganic peroxide being from about 0.1:1 to about 3:1, (b) immersing a cellulosic textile in the aqueous treating solution for a period of time sufficient to thoroughly wet the cellulosic textile, (c) removing excess treating solution from the cellulosic textile, (d) heating the cellulosic textile at a temperature of about from 50° C. to 160° C. for about from 0.5 minutes to 30 minutes to dry the cellulosic textile and cause deposition of peroxide complexes of zirconium on the textile, the higher temperatures being maintained for the shorter times, (e) washing the cellulosic textile to remove excess reagents, and (f) drying the treated cellulosic textile at a temperature of 50° C. to 140° C. for from 0.5 minute to 30 minutes, the higher temperatures being used for the shorter times.
Claim 2
Dependent Claim
234 words
A one-bath process for rendering cellulosic textiles bacteriostatic, which process comprises: (a) preparing an aqueous treating solution containing about from 1% to 35% zirconyl acetate, 0.3% to 35% acetic acid, and 1% to 25% of an inorganic peroxide selected from the class consisting of hydrogen peroxide, an alkali metal perborate monohydrate and an alkali metal perborate tetrahydrate, the solution being made up by adding the inorganic peroxide to a solution of the zirconyl acetate and acetic acid in water, the ratio by weight of acetic acid to zirconyl acetate being from about 0.3:1 to about 5:1, and the mole ratio of zirconyl acetate to inorganic peroxide being from about 0.1:1 to about 3:1, (b) immersing a cellulosic textile in the aqueous treating solution for a period of time sufficient to thoroughly wet the cellulosic textile, (c) removing excess treating solution from the cellulosic textile, (d) heating the cellulosic textile at a temperature of about from 50° C. to 160° C. for about from 0.5 minutes to 30 minutes to dry the cellulosic textile and cause deposition of peroxide complexes of zirconium on the textile, the higher temperatures being maintained for the shorter times, (e) washing the cellulosic textile to remove excess reagents, and (f) drying the treated cellulosic textile at a temperature of 50° C. to 140° C. for from 0.5 minute to 30 minutes, the higher temperatures being used for the shorter times.
Claim 3
Dependent Claim
12 words
The process of claim 1 where the inorganic peroxide is hydrogen peroxide.
Claim 4
Dependent Claim
13 words
The process of claim 1 where the inorganic peroxide is sodium perborate tetrahydrate.
Claim 5
Dependent Claim
14 words
As a textile material, the cellulosic textile treated by the process of claim 1.
Claim 6
Dependent Claim
13 words
As a textile material, cotton fabric treated by the process of claim 1.
Claim 7
Dependent Claim
178 words
A one-bath process for rendering cellulosic textiles bacteriostatic, which process comprises: (a) adding a 10%-30% aqueous solution of hydrogen peroxide to a 1%-40% aqueous solution of zirconyl acetate at 10° C.-50° C. to produce a gel, (b) storing the gel at 10° C.-35° C. for 18-24 hours to allow the gel to reliquefy to an aqueous solution, (c) immersing a cellulosic textile in the aqueous solution for a period of time sufficient to thoroughly wet the cellulosic textile, (d) removal of excess treating solution from the cellulosic textile, (e) heating the cellulosic textile at a temperature of about from 50° C. to 160° C. for about from 0.5 minute to 30 minutes to dry the cellulosic textile and cause deposition of peroxide complexes of zirconium on the textile, the higher temperatures being maintained for the shorter times, (f) washing the cellulosic textile to remove excess reagents, and (g) drying the treated cellulosic textile at a temperature of 50° C. to 140° C. for from 0.5 minute to 30 minutes, the higher temperatures being used for the shorter times.
Claim 8
Dependent Claim
178 words
A one-bath process for rendering cellulosic textiles bacteriostatic, which process comprises: (a) adding a 10%-30% aqueous solution of hydrogen peroxide to a 1%-40% aqueous solution of zirconyl acetate at 10° C.-50° C. to produce a gel, (b) storing the gel at 10° C.-35° C. for 18-24 hours to allow the gel to reliquefy to an aqueous solution, (c) immersing a cellulosic textile in the aqueous solution for a period of time sufficient to thoroughly wet the cellulosic textile, (d) removal of excess treating solution from the cellulosic textile, (e) heating the cellulosic textile at a temperature of about from 50° C. to 160° C. for about from 0.5 minute to 30 minutes to dry the cellulosic textile and cause deposition of peroxide complexes of zirconium on the textile, the higher temperatures being maintained for the shorter times, (f) washing the cellulosic textile to remove excess reagents, and (g) drying the treated cellulosic textile at a temperature of 50° C. to 140° C. for from 0.5 minute to 30 minutes, the higher temperatures being used for the shorter times.
Claim 9
Dependent Claim
249 words
A two-bath process for rendering cellulosic textiles bacteriostatic, which process comprises: (a) immersing the cellulosic textile in an aqueous treating solution containing about from 1% to 40% of zirconyl acetate in water, (b) removing excess treating solution from the cellulosic textile, (c) heating the cellulosic textile at about from 50° C. to about 160° C. for from 0.5 minute to 30 minutes to dry the cellulosic textile and to convert the soluble zirconyl acetate to an insoluble zirconium oxyacetate complex deposited on the cellulosic textile, the higher temperatures being used for the shorter times, (d) immersing the cellulosic textile in an aqueous treating solution containing about from 1% to 30% of an inorganic peroxide selected from the class consisting of hydrogen peroxide, an alkali metal perborate monohydrate, an alkali metal perborate tetrahydrate and an alkali metal peroxydiphosphate, the immersion being continued for a time sufficient to thoroughly wet the textile, (e) removal of excess treating solution from the cellulosic textile, (f) heating the cellulosic textile at about from 50° C. to about 160° C. for from 0.5 minute to 30 minutes, the higher temperatures being used for the shorter times, to dry the cellulosic textile and to produce an insoluble peroxide complex of the zirconium oxyacetate deposited on the cellulosic textile, (g) washing the cellulosic textile to remove excess reagents, and (h) drying the treated cellulosic textile at temperatures of 50° C.-140° C. for from 0.5 minutes to 30 minutes, the higher temperatures being used for the shorter times.
Claim 10
Dependent Claim
249 words
A two-bath process for rendering cellulosic textiles bacteriostatic, which process comprises: (a) immersing the cellulosic textile in an aqueous treating solution containing about from 1% to 40% of zirconyl acetate in water, (b) removing excess treating solution from the cellulosic textile, (c) heating the cellulosic textile at about from 50° C. to about 160° C. for from 0.5 minute to 30 minutes to dry the cellulosic textile and to convert the soluble zirconyl acetate to an insoluble zirconium oxyacetate complex deposited on the cellulosic textile, the higher temperatures being used for the shorter times, (d) immersing the cellulosic textile in an aqueous treating solution containing about from 1% to 30% of an inorganic peroxide selected from the class consisting of hydrogen peroxide, an alkali metal perborate monohydrate, an alkali metal perborate tetrahydrate and an alkali metal peroxydiphosphate, the immersion being continued for a time sufficient to thoroughly wet the textile, (e) removal of excess treating solution from the cellulosic textile, (f) heating the cellulosic textile at about from 50° C. to about 160° C. for from 0.5 minute to 30 minutes, the higher temperatures being used for the shorter times, to dry the cellulosic textile and to produce an insoluble peroxide complex of the zirconium oxyacetate deposited on the cellulosic textile, (g) washing the cellulosic textile to remove excess reagents, and (h) drying the treated cellulosic textile at temperatures of 50° C.-140° C. for from 0.5 minutes to 30 minutes, the higher temperatures being used for the shorter times.
Claim 11
Dependent Claim
12 words
The process of claim 7 where the inorganic peroxide is hydrogen peroxide.
Claim 12
Dependent Claim
13 words
The process of claim 7 where the inorganic peroxide is sodium perborate tetrahydrate.
Claim 13
Dependent Claim
12 words
The process of claim 7 where the inorganic peroxide is potassium peroxydiphosphate.
Claim 14
Dependent Claim
14 words
As a textile material, the cellulosic textile treated by the process of claim 7.
References Cited (Backward Citations)
US2681922A
Cited
US3394027A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-11-12 | 1983-05-14 | 1983-11-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-11-12 | 1987-05-14 | 1987-11-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-11-12 | 1991-05-14 | 1991-11-13 | $7700.00 | Window Closed / Lapsed |