US4174373A
Expired / Lapsed
US
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Process for removing sulfur oxides and nitrogen oxides from flue gases
Assignee: Hitachi Ltd
•
Filing: 1975-08-29
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Granted: 1979-11-13
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Expires: 1995-08-29
Abstract
Abstract A catalyst comprising carbonaceous materials such as activated carbon, etc. impregnated with bromine, iodine, chlorine or their compounds, is impregnated with a promoter containing a specific metal, and brought in contact with a flue gas in the presence of ammonia, whereby nitrogen oxides and sulfur oxides contained in the flue gas are removed with a very high percent removal. The removal can be carried out at a temperature much lower than that of the conventional process.
Inventors
- 👤 Kazuetsu Yoshida
- 👤 Michiharu Seki
- 👤 Keiichi Kanehori
- 👤 Katsuhiro Kaneko
- 👤 Yo Sakurai
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 18:15
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/60; Y; Y02; Y02A; Y02A50/00; Y02A50/20
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
93 words
A process for removing at least one of nitrogen oxides and sulfur oxides contained in a flue gas, which comprises contacting a flue gas containing at least one of nitrogen oxides and sulfur oxides with a catalyst comprising a carbonaceous material impregnated with at least one of bromine, iodine, chlorine, ammonium bromide, ammonium iodide, ammonium chloride, hydrogen bromide, hydrogen iodide and hydrogen chloride, and at least one of metal elements of groups 1B, 3B, 4B, 5B, 6B, 2A, 3A and 8 of the periodic table as a promoter in the presence of ammonia.
Claim 2
Dependent Claim
93 words
A process for removing at least one of nitrogen oxides and sulfur oxides contained in a flue gas, which comprises contacting a flue gas containing at least one of nitrogen oxides and sulfur oxides with a catalyst comprising a carbonaceous material impregnated with at least one of bromine, iodine, chlorine, ammonium bromide, ammonium iodide, ammonium chloride, hydrogen bromide, hydrogen iodide and hydrogen chloride, and at least one of metal elements of groups 1B, 3B, 4B, 5B, 6B, 2A, 3A and 8 of the periodic table as a promoter in the presence of ammonia.
Claim 3
Dependent Claim
25 words
A process according to claim 1, wherein the carbonaceous material is at least one of activated carbon, amorphous carbon, graphite, char coal and carbonized char.
Claim 4
Dependent Claim
15 words
A process according to claim 1, wherein the ammonia is supplied from an outside source.
Claim 5
Dependent Claim
15 words
A process according to claim 1, wherein the flue gas contains at least nitrogen oxides.
Claim 6
Dependent Claim
18 words
A process according to claim 1, wherein the flue gas contains at least nitrogen oxides and sulfur oxides.
Claim 7
Dependent Claim
25 words
A process according to claim 1, wherein at least 0.01 g of bromine, iodine or chlorine is impregnated per 1 kg of the carbonaceous material.
Claim 8
Dependent Claim
42 words
A process according to claim 1, wherein at least 0.01 g of the ammonium iodide, ammonium bromide, ammonium chloride, hydrogen bromide, hydrogen iodide or hydrogen chloride, in terms of bromine, iodine or chlorine, is impregnated per 1 kg of the carbonaceous material.
Claim 9
Dependent Claim
12 words
A process according to claim 1, wherein the promoter is vanadium pentoxide.
Claim 10
Dependent Claim
15 words
A process according to claim 1, wherein the promoter is in the form of oxide.
Claim 11
Dependent Claim
15 words
A process according to claim 1, wherein the promoter is in the form of sulfate.
Claim 12
Dependent Claim
15 words
A process according to claim 1, wherein the promoter is in the form of nitrate.
Claim 13
Dependent Claim
15 words
A process according to claim 1, wherein the promoter is in the form of chloride.
Claim 14
Dependent Claim
17 words
A process according to claim 1, wherein the promoter is in the form of organic acid salt.
Claim 15
Dependent Claim
24 words
A process according to claim 1, wherein 0.1 to 10% by weight of the promoter is impregnated on the basis of the carbonaceous material.
Claim 16
Dependent Claim
26 words
A process according to claim 1, wherein the flue gas is contacted with the carbonaceous material at a temperature of the room temperature to 200° C.
Claim 17
Dependent Claim
81 words
A process for removing nitrogen oxides from a gas mixture containing nitrogen oxides comprising simultaneously contacting said gas mixture with (1) ammonia and (2) a catalyst comprising a carbonaceous material impregnated with (a) at least one halogenous material selected from the group consisting of bromine, iodine, chlorine, ammonium bromide, ammonium iodide, ammonium chloride, hydrogen bromide, hydrogen iodide and hydrogen chloride and (b) at least one metal of groups 1B, 3B, 4B, 5B, 6B, 2A, 3A and 8 of the Periodic Table.
Claim 18
Dependent Claim
81 words
A process for removing nitrogen oxides from a gas mixture containing nitrogen oxides comprising simultaneously contacting said gas mixture with (1) ammonia and (2) a catalyst comprising a carbonaceous material impregnated with (a) at least one halogenous material selected from the group consisting of bromine, iodine, chlorine, ammonium bromide, ammonium iodide, ammonium chloride, hydrogen bromide, hydrogen iodide and hydrogen chloride and (b) at least one metal of groups 1B, 3B, 4B, 5B, 6B, 2A, 3A and 8 of the Periodic Table.
Claim 19
Dependent Claim
30 words
The process of claim 16, wherein said at least one metal is in the form of a salt when said carbonaceous material is impregnated with said at least one metal.
Claim 20
Dependent Claim
29 words
The process of claim 17, wherein said salt is selected from the group consisting of a sulphate salt, a nitrate salt, a chloride salt and an organic acid salt.
Claim 21
Dependent Claim
40 words
The process of claim 18, wherein said carbonaceous material is impregnated with 0.1 to 10% by weight of said at least one metal and at least 0.10 gm halogenous material measured as elemental halogen per kgm of said carbonaceous material.
Claim 22
Dependent Claim
24 words
The process of claim 16, wherein said gas mixture is contacted with said carbonaceous material at a temperature between room temperature and 200° C.
Claim 23
Dependent Claim
12 words
The Process of claim 20, wherein said carbonaceous material is activated carbon.
Claim 24
Dependent Claim
15 words
The process of claim 21, wherein said at least one metal is vanadium or copper.
Claim 25
Dependent Claim
16 words
The process of claim 22, wherein said carbonaceous material has thereon vanadium pentoxide or copper oxide.
Claim 26
Dependent Claim
24 words
The process of claim 21, wherein ammonia is mixed with said gas mixture prior to contact of said gas mixture with said carbonaceous material.
Claim 27
Dependent Claim
20 words
The process of claim 21, wherein said gas mixture and said ammonia gas are separately fed to said carbonaceous material.
Claim 28
Dependent Claim
31 words
A process according to claim 1, wherein the amount of ammonia present is stoichiometrically equivalent to or a little more than the total amount of said nitrogen oxides and sulfur oxides.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-11-12 | 1983-05-14 | 1983-11-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-11-12 | 1987-05-14 | 1987-11-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-11-12 | 1991-05-14 | 1991-11-13 | $7700.00 | Window Closed / Lapsed |