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US4174289A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid detergent-bleach concentrates having high alkalinity

Assignee: BASF Corp
•
Filing: 1978-08-28
•
Granted: 1979-11-13
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Expires: 1998-08-28
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Abstract

Abstract There are disclosed liquid detergent-bleach concentrates of high alkalinity which are clear solutions having excellent long term stability at elevated temperatures and at low temperatures. The concentrate compositions consist essentially of an alkali metal hypochlorite, alkali metal chloride, an alkali metal salt of an alkylated diphenyl oxide sulfonic acid, and metal chelating agents in an aqueous composition having a high proportion of alkali metal hydroxide. The concentrates are useful upon dilution in forming hard surface cleaning compositions which are particularly useful in removal of oily soils, derived from animal and vegetable oils.

Inventors

  • 👤 Malachi E. Sorgenfrei
  • 👤 Donald F. Garvin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 08:41
CPC Classifications
C; C11; C11D; C11D7/00; C11D7/02; C11D7/04; C11D7/06; C11D3/00; C11D3/395; C11D3/3953; C11D3/3956

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 124 words
A cleaning and bleaching liquid composition consisting essentially of an aqueous solution of: A. about 2% to about 15% by weight, calculated as available chlorine, of an alkali metal hypochlorite, B. about 15% to about 200% by weight of an alkali metal salt of an alkylated diphenyl oxide sulfonic acid based upon said alkali metal hypochlorite weight, C. about 5% to about 20% by weight of an alkali metal hydroxide, and D. about 0.1 mole to about 1.5 mole of an alkali metal chloride per mole of said hypochlorite wherein said alkali metal is selected from the group consisting of sodium, potassium, and lithium, and wherein said alkylated diphenyl oxide sulfonic acid contains about 8 to about 22 carbon atoms in the alkyl moiety.
Claim 2
Dependent Claim 124 words
A cleaning and bleaching liquid composition consisting essentially of an aqueous solution of: A. about 2% to about 15% by weight, calculated as available chlorine, of an alkali metal hypochlorite, B. about 15% to about 200% by weight of an alkali metal salt of an alkylated diphenyl oxide sulfonic acid based upon said alkali metal hypochlorite weight, C. about 5% to about 20% by weight of an alkali metal hydroxide, and D. about 0.1 mole to about 1.5 mole of an alkali metal chloride per mole of said hypochlorite wherein said alkali metal is selected from the group consisting of sodium, potassium, and lithium, and wherein said alkylated diphenyl oxide sulfonic acid contains about 8 to about 22 carbon atoms in the alkyl moiety.
Claim 3
Dependent Claim 72 words
The composition of claim 1 wherein said hypochlorite is selected from the group consisting of sodium hypochlorite and potassium hypochlorite and is present in the proportion of about 3% to about 10% by weight, calculated as available chlorine, and said alkali metal salt of an alkylated diphenyl oxide sulfonic acid is present in the proportion of about 30% to about 175% by weight on the basis of the weight of said hypochlorite.
Claim 4
Dependent Claim 31 words
The composition of claim 2 wherein said alkali metal salt of an alkylated diphenyl oxide sulfonic acid contains an average of about 1.8 to 2.3 sulfonate groups per diphenyl oxide moiety.
Claim 5
Dependent Claim 55 words
The composition of claim 3 wherein said composition consists essentially of about 2% to about 4% by weight of potassium hypochlorite, calculated as available chlorine, an equimolar amount of potassium chloride and about 100% to about 200% by weight of the basis of the weight of said potassium hypochlorite of said sulfonated alkyl diphenyl oxide.
Claim 6
Dependent Claim 39 words
The composition of claim 4 wherein said composition contains on a weight basis about 8% to about 15% of potassium hydroxide, about 2% potassium silicate, and about 6% sodium tripolyphosphate and wherein about 3.5% phosphoric acid is added thereto.
Claim 7
Dependent Claim 48 words
A method of cleaning hard surfaces comprising: A. forming an aqueous solution of about 0.5% to about 5% by weight active solution concentration of the composition of claim 1, B. applying an effective amount of said mixture to said hard surface, and C. rinsing said surface with water.
Claim 8
Dependent Claim 31 words
The method of claim 6 wherein said mixture is applied at a temperature of about 15° C. to about 80° C. to hard surfaces soiled with animal and vegetable-based oily soils.
Claim 9
Dependent Claim 47 words
A method of cleaning hard surfaces comprising: A. forming an aqueous solution of 0.5% to about 5% by weight active solution concentration of the composition of claim 5, B. applying an effective amount of said mixture to said hard surface, and C. rinsing said surface with water.

References Cited (Backward Citations)

FR715910A Cited
US3172681A Cited
US3728266A Cited
US3758409A Cited
US3793212A Cited
US3929661A Cited
US4029591A Cited
US4071463A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-11-12 1983-05-14 1983-11-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-11-12 1987-05-14 1987-11-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-11-12 1991-05-14 1991-11-13 $7700.00 Window Closed / Lapsed

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