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US4173698A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymerization of olefin

Assignee: Mitsubishi Chemical Corp
•
Filing: 1977-05-25
•
Granted: 1979-11-06
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Expires: 1997-05-25
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Abstract

Abstract A solid catalytic component for polymerization of an olefin is prepared by reacting a vanadium trichloride ether complex with aluminum halide.

Inventors

  • 👤 Natsuki Kanoh
  • 👤 Toru Tanaka
  • 👤 Atsushi Murakami

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 10:03
CPC Classifications
B; B01; B01J; B01J31/00; B01J31/02; B01J31/12; B01J31/14; B01J31/143; B01J27/00; B01J27/06; B01J27/08; B01J31/16; B01J31/22; B01J31/2204; B01J31/2208; B01J31/26; B01J31/36; C; C08; C08F; C08F10/00; B01J2231/00; B01J2231/10; B01J2231/12; B01J2531/00; B01J2531/50; B01J2531/56; B01J27/10

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 130 words
In a process for polymerizing ethylene alone or a mixture containing ethylene and a different α-olefin to form copolymers containing less than 10 wt.% of the α-olefin in the presence of a catalyst system comprising an organoaluminum compound and a solid catalytic component, the improvement which comprises preparing said solid catalytic component by the process which comprises: (a) dissolving a vanadium trichloride-ether complex in a solvent to form a solution; (b) adding to said solution a quantity of an aluminum halide sufficient to yield a molar ratio of aluminum halide to the ether in the vanadium trichloride-ether complex of 0.1 to 10, whereby said aluminum halide reacts with said vanadium trichloride-ether complex to form a precipitate consisting essentially of said solid catalytic component; and (c) recovering said solid catalytic component.
Claim 2
Dependent Claim 130 words
In a process for polymerizing ethylene alone or a mixture containing ethylene and a different α-olefin to form copolymers containing less than 10 wt.% of the α-olefin in the presence of a catalyst system comprising an organoaluminum compound and a solid catalytic component, the improvement which comprises preparing said solid catalytic component by the process which comprises: (a) dissolving a vanadium trichloride-ether complex in a solvent to form a solution; (b) adding to said solution a quantity of an aluminum halide sufficient to yield a molar ratio of aluminum halide to the ether in the vanadium trichloride-ether complex of 0.1 to 10, whereby said aluminum halide reacts with said vanadium trichloride-ether complex to form a precipitate consisting essentially of said solid catalytic component; and (c) recovering said solid catalytic component.
Claim 3
Dependent Claim 22 words
The process of claim 1 wherein the solid catalytic component is washed with a solvent before combining it with the organoaluminum compound.
Claim 4
Dependent Claim 13 words
A process according to claim 1, wherein said solvent is a halogenated hydrocarbon.
Claim 5
Dependent Claim 17 words
A process according to claim 1, wherein said vanadium trichloride ether complex is vanadium trichloride tetrahydropyran complex.
Claim 6
Dependent Claim 17 words
A process according to claim 1, wherein said vanadium trichloride ether complex is vanadium trichloride tetrahydrofuran complex.

References Cited (Backward Citations)

US1001820A Cited
US3130003A Cited
US3369011A Cited
US3269996A Cited
US3989881A Cited
US4060593A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-11-05 1983-05-07 1983-11-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-11-05 1987-05-07 1987-11-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-11-05 1991-05-07 1991-11-06 $7700.00 Window Closed / Lapsed

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