US4173619A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Combustion gas desulfurization
Assignee: Individual
•
Filing: 1978-03-14
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Granted: 1979-11-06
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Expires: 1998-03-14
Abstract
Abstract Hot combustion gas from a coal or oil fired furnace is desulfurized by a regenerative molten alkali salt process. The process is both highly efficient and uncomplicated. Only three major pieces of equipment are required-- scrubber, regenerator, and auxiliary combustor. All reactions are adiabatic, no solids handling is required, only steam is required for salt regeneration, and the regeneration product is H 2 S. Process temperature is low enough to minimize corrosion by the salt and to permit efficient fly ash removal prior to salt contact. High regeneration efficiency is achieved using only steam optionally mixed with CO 2 as regenerant as follows: the combustion gas is maintained slightly reducing which causes the dominant sulfur species in the salt to be the sulfide; the salt cation composition is controlled to yield an acceptably high sulfide concentration in the salt; and salt regeneration is conducted at a significantly higher pressure than scrub.
Inventors
- 👤 Donald C. Erickson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 23:56
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/50; B01D53/501
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
152 words
In a regenerative process for removing H 2 S, COS, and SO 2 from a sulfur-containing hot combustion gas which comprises: a. scrubbing the combustion gas by contacting it with a molten alkali salt mixture; b. regenerating the molten salt by contacting it with steam plus CO 2 ; the improvement which comprises: (i) establishing the quality of the combustion gas in the approximate range of 2% to 20% for the scrubbing contacting action; (ii) maintaining the scrubbing salt temperature in the approximate range of 800 K to 950 K; (iii) establishing the alkali cation composition of the salt such that is consists essentially of 40±20% potassium cations, 35±25% lithium cations, and balance sodium cations; (iv) conducting the scrubbing contact within the approximate pressure range of 0.5 to 4 atmospheres; (v) increasing the salt pressure for regeneration to within the approximate range of 2 times scrub pressure to 60 times scrub pressure.
Claim 2
Dependent Claim
152 words
In a regenerative process for removing H 2 S, COS, and SO 2 from a sulfur-containing hot combustion gas which comprises: a. scrubbing the combustion gas by contacting it with a molten alkali salt mixture; b. regenerating the molten salt by contacting it with steam plus CO 2 ; the improvement which comprises: (i) establishing the quality of the combustion gas in the approximate range of 2% to 20% for the scrubbing contacting action; (ii) maintaining the scrubbing salt temperature in the approximate range of 800 K to 950 K; (iii) establishing the alkali cation composition of the salt such that is consists essentially of 40±20% potassium cations, 35±25% lithium cations, and balance sodium cations; (iv) conducting the scrubbing contact within the approximate pressure range of 0.5 to 4 atmospheres; (v) increasing the salt pressure for regeneration to within the approximate range of 2 times scrub pressure to 60 times scrub pressure.
Claim 3
Dependent Claim
20 words
The process according to claim 1 wherein the scrubbing and regeneration contacting actions are both conducted in multiple countercurrent stages.
Claim 4
Dependent Claim
24 words
The process according to claim 2 comprising the additional step of completing the combustion of the desulfurized combustion gas by oxidizing it with air.
Claim 5
Dependent Claim
25 words
The process according to claim 3 wherein the alkali cation composition is 50±10% K + , 30±10% Li + , and balance Na + .
Claim 6
Dependent Claim
62 words
The process according to claim 4 wherein the combustion gas quality is approximately 4 to 8%, the scrub temperature is approximately 850 K, and scrub pressure is approximately atmospheric, the regeneration pressure is within the range of 5 to 30 atmospheres, and comprising the additional step of removing particulate matter from the sulfur-containing hot combustion gas prior to the scrubbing contacting step.
Claim 7
Dependent Claim
26 words
The process according to claim 3 comprising the additional step of establishing the combustion gas quality in the stated range by injecting fuel gas into it.
Claim 8
Dependent Claim
31 words
The process according to claim 3 comprising the additional step of establishing the combustion gas quality in the staged range by supplying less than stoichiometric air to the combustion gas generator.
Claim 9
Dependent Claim
43 words
The process according to claim 3 wherein the desulfurized combustion gas is oxidized with air by injecting both the gas and the air into contact with a molten alkali salt containing sulfate anions and containing no more than trace amounts of sulfide anions.
Claim 10
Dependent Claim
32 words
The process according to claim 3 comprising the additional step of raising the temperature of the sulfur-containing combustion gas to the approximate temperature of the scrubber prior to the scrubbing contact step.
Claim 11
Dependent Claim
85 words
A process for regeneratively scrubbing hydrogen sulfide from a hot sulfur-containing combustion gas having a quality of at least 2% which comprises: a. scrubbing the combustion gas with a molten alkali salt consisting essentially of carbonate, sulfide, and hydroxide anions; b. increasing the salt pressure to at least two times the scrubbing pressure; c. regenerating the salt at the higher pressure by contacting it with steam optionally admixed with CO 2 ; d. decreasing the pressure of the salt for reuse in the scrubbing step.
Claim 12
Dependent Claim
85 words
A process for regeneratively scrubbing hydrogen sulfide from a hot sulfur-containing combustion gas having a quality of at least 2% which comprises: a. scrubbing the combustion gas with a molten alkali salt consisting essentially of carbonate, sulfide, and hydroxide anions; b. increasing the salt pressure to at least two times the scrubbing pressure; c. regenerating the salt at the higher pressure by contacting it with steam optionally admixed with CO 2 ; d. decreasing the pressure of the salt for reuse in the scrubbing step.
Claim 13
Dependent Claim
62 words
The process according to claim 10 wherein the combustion gas quality is in the range 2 to 20%, the scrubbing and regeneration temperatures are in the range 800 to 950 K, the scrubbing pressure is in the range 0.5 to 4 atmospheres, and the salt alkali cation composition consists essentially of 20 to 60% potassium, 10 to 60% lithium, balance sodium cations.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-11-05 | 1983-05-07 | 1983-11-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-11-05 | 1987-05-07 | 1987-11-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-11-05 | 1991-05-07 | 1991-11-06 | $7700.00 | Window Closed / Lapsed |