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US4172824A Expired / Lapsed US ⏱️ 0.0 years remaining

Copolyester melt adhesive having improved flow characteristics containing di- and tri-benzoate modifier

Assignee: Eastman Chemical Co
•
Filing: 1978-05-26
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Granted: 1979-10-30
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Expires: 1998-05-26
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Abstract

Abstract The flow characteristics of a copolyester melt adhesive prepared from terephthalic acid, adipic acid, ethylene glycol and 1,4-butanediol are improved by the use of a modifying amount of glycerol tribenzoate, neopentyl dibenzoate, triethylene glycol dibenzoate, trimethylolethane tribenzoate, or mixtures thereof.

Inventors

  • 👤 Robert C. Harrington, Jr.
  • 👤 James D. Hood

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 16:02
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C09; C09J; C09J167/00; Y; Y10; Y10T; Y10T442/00; Y10T442/20; Y10T442/2738; Y10T442/2746

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 149 words
An improved hot melt adhesive composition comprising a copolyester of terephthalic acid or derivatives thereof; adipic acid or derivatives thereof; ethylene glycol or derivatives thereof; and 1,4-butanediol or derivatives thereof, wherein the acid components and the diol components are present in a 1:1 molar ratio, said copolyester having a mole ratio of terephthalic acid to adipic acid within the range of about 60:40 to about 80:20, a mole ratio of ethylene glycol to 1,4-butanediol within the range of about 60:40 to about 80:20, a softening point within the range of about 80°-160° C., and an inherent viscosity of at least 0.5 as measured at 25° C. using 0.25 grams of copolyester per 100 ml. of a solvent consisting of 60 percent by weight phenol and 40 percent by weight tetrachloroethane, and a modifying amount of a compound selected from glyceryl tribenzoate, triethylene glycol dibenzoate, trimethylolethane tribenzoate, and neopentyl dibenzoate.
Claim 2
Dependent Claim 149 words
An improved hot melt adhesive composition comprising a copolyester of terephthalic acid or derivatives thereof; adipic acid or derivatives thereof; ethylene glycol or derivatives thereof; and 1,4-butanediol or derivatives thereof, wherein the acid components and the diol components are present in a 1:1 molar ratio, said copolyester having a mole ratio of terephthalic acid to adipic acid within the range of about 60:40 to about 80:20, a mole ratio of ethylene glycol to 1,4-butanediol within the range of about 60:40 to about 80:20, a softening point within the range of about 80°-160° C., and an inherent viscosity of at least 0.5 as measured at 25° C. using 0.25 grams of copolyester per 100 ml. of a solvent consisting of 60 percent by weight phenol and 40 percent by weight tetrachloroethane, and a modifying amount of a compound selected from glyceryl tribenzoate, triethylene glycol dibenzoate, trimethylolethane tribenzoate, and neopentyl dibenzoate.
Claim 3
Dependent Claim 11 words
The composition of claim 1 bonded to at least one substrate.
Claim 4
Dependent Claim 13 words
The composition of claim 1 wherein the inherent viscosity is at least 0.7.
Claim 5
Dependent Claim 30 words
The composition of claim 1 wherein the mole ratio of terephthalic acid to adipic acid is about 75:25 and the mole ratio of ethylene glycol to 1,4-butanediol is about 75:25.
Claim 6
Dependent Claim 25 words
The composition of claim 1 wherein said modifier is present in an amount of between about 1 and about 35 parts per hundred parts polyester.
Claim 7
Dependent Claim 25 words
The composition of claim 1 wherein said modifier is present in an amount of between about 5 and about 15 parts per hundred parts modifier.
Claim 8
Dependent Claim 11 words
The composition of claim 1 wherein said modifier is glycerol tribenzoate.
Claim 9
Dependent Claim 11 words
The composition of claim 1 wherein said modifier in neopentyl dibenzoate.
Claim 10
Dependent Claim 12 words
The composition of claim 1 wherein said modifier is triethylene glycol dibenzoate.
Claim 11
Dependent Claim 11 words
The composition of claim 1 wherein said modifier is trimethylolethane tribenzoate.

References Cited (Backward Citations)

US2044612A Cited
US3039982A Cited
US3186961A Cited
CA893153A Cited
US3669921A Cited
US3970631A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-10-29 1983-04-30 1983-10-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-10-29 1987-04-30 1987-10-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-10-29 1991-04-30 1991-10-30 $7700.00 Window Closed / Lapsed

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