US4172824A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Copolyester melt adhesive having improved flow characteristics containing di- and tri-benzoate modifier
Assignee: Eastman Chemical Co
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Filing: 1978-05-26
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Granted: 1979-10-30
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Expires: 1998-05-26
Abstract
Abstract The flow characteristics of a copolyester melt adhesive prepared from terephthalic acid, adipic acid, ethylene glycol and 1,4-butanediol are improved by the use of a modifying amount of glycerol tribenzoate, neopentyl dibenzoate, triethylene glycol dibenzoate, trimethylolethane tribenzoate, or mixtures thereof.
Inventors
- 👤 Robert C. Harrington, Jr.
- 👤 James D. Hood
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 16:02
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C09; C09J; C09J167/00; Y; Y10; Y10T; Y10T442/00; Y10T442/20; Y10T442/2738; Y10T442/2746
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
149 words
An improved hot melt adhesive composition comprising a copolyester of terephthalic acid or derivatives thereof; adipic acid or derivatives thereof; ethylene glycol or derivatives thereof; and 1,4-butanediol or derivatives thereof, wherein the acid components and the diol components are present in a 1:1 molar ratio, said copolyester having a mole ratio of terephthalic acid to adipic acid within the range of about 60:40 to about 80:20, a mole ratio of ethylene glycol to 1,4-butanediol within the range of about 60:40 to about 80:20, a softening point within the range of about 80°-160° C., and an inherent viscosity of at least 0.5 as measured at 25° C. using 0.25 grams of copolyester per 100 ml. of a solvent consisting of 60 percent by weight phenol and 40 percent by weight tetrachloroethane, and a modifying amount of a compound selected from glyceryl tribenzoate, triethylene glycol dibenzoate, trimethylolethane tribenzoate, and neopentyl dibenzoate.
Claim 2
Dependent Claim
149 words
An improved hot melt adhesive composition comprising a copolyester of terephthalic acid or derivatives thereof; adipic acid or derivatives thereof; ethylene glycol or derivatives thereof; and 1,4-butanediol or derivatives thereof, wherein the acid components and the diol components are present in a 1:1 molar ratio, said copolyester having a mole ratio of terephthalic acid to adipic acid within the range of about 60:40 to about 80:20, a mole ratio of ethylene glycol to 1,4-butanediol within the range of about 60:40 to about 80:20, a softening point within the range of about 80°-160° C., and an inherent viscosity of at least 0.5 as measured at 25° C. using 0.25 grams of copolyester per 100 ml. of a solvent consisting of 60 percent by weight phenol and 40 percent by weight tetrachloroethane, and a modifying amount of a compound selected from glyceryl tribenzoate, triethylene glycol dibenzoate, trimethylolethane tribenzoate, and neopentyl dibenzoate.
Claim 3
Dependent Claim
11 words
The composition of claim 1 bonded to at least one substrate.
Claim 4
Dependent Claim
13 words
The composition of claim 1 wherein the inherent viscosity is at least 0.7.
Claim 5
Dependent Claim
30 words
The composition of claim 1 wherein the mole ratio of terephthalic acid to adipic acid is about 75:25 and the mole ratio of ethylene glycol to 1,4-butanediol is about 75:25.
Claim 6
Dependent Claim
25 words
The composition of claim 1 wherein said modifier is present in an amount of between about 1 and about 35 parts per hundred parts polyester.
Claim 7
Dependent Claim
25 words
The composition of claim 1 wherein said modifier is present in an amount of between about 5 and about 15 parts per hundred parts modifier.
Claim 8
Dependent Claim
11 words
The composition of claim 1 wherein said modifier is glycerol tribenzoate.
Claim 9
Dependent Claim
11 words
The composition of claim 1 wherein said modifier in neopentyl dibenzoate.
Claim 10
Dependent Claim
12 words
The composition of claim 1 wherein said modifier is triethylene glycol dibenzoate.
Claim 11
Dependent Claim
11 words
The composition of claim 1 wherein said modifier is trimethylolethane tribenzoate.
References Cited (Backward Citations)
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Cited
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-10-29 | 1983-04-30 | 1983-10-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-10-29 | 1987-04-30 | 1987-10-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-10-29 | 1991-04-30 | 1991-10-30 | $7700.00 | Window Closed / Lapsed |