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US4172730A Expired / Lapsed US ⏱️ 0.0 years remaining

Radiographic silver halide sensitive materials

Assignee: Fujifilm Holdings Corp
•
Filing: 1977-04-15
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Granted: 1979-10-30
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Expires: 1997-04-15
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Abstract

Abstract Silver halide radiographic sensitive materials comprising at least one silver halide photographic emulsion layer on a support, which are used according to a process which comprises exposure to radiation from a fluorescent intensifying screen which emits light having a maximum emission in the green spectral range by excitation with radiation wherein at least 1/2 of the emission energy is in the wavelength range of above about 400 nm, and carrying out development of the exposed sensitive material to form radiographic images, wherein said silver halide sensitive materials contain below about 8.6 g of silver per square meter and said at least one silver halide photographic emulsion layer contains a combination of at least one dye represented by formula (I) and at least one dye represented by formula (II): ##STR1## wherein A 1 and A 2 each represents a hydrogen atom or a halogen atom; A 3 and A 4 each represents a hydrogen atom, a halogen atom, an alkoxy group or a phenyl group; B 1 , B 2 , B 3 and B 4 each represents a hydrogen atom, a halogen atom or an alkoxy group; R, R 1 and R 2 each represents an alkyl group and at least one of R 1 and R 2 represents a sulfoalkyl group or a carboxyalkyl group; R 0 represents a hydrogen atom or a lower alkyl group, R 3 and R 4 each has the same meaning as R 1 and R 2 ; X 1 represents an anion; m and n each represents an integer of 1 or 2, but m and n are 1 when the dye forms an inner salt; and X 2 represents an anion.

Inventors

  • 👤 Masanao Hinata
  • 👤 Haruo Takei
  • 👤 Nobuaki Miyasaka
  • 👤 Kenji Takahashi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 23:09
CPC Classifications
G; G03; G03C; G03C5/00; G03C5/16; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/28; G03C1/29; Y; Y10; Y10S; Y10S430/00; Y10S430/167

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 275 words
A silver halide radiographic sensitive element comprising (1) a silver halide radiographic sensitive material comprising a support having thereon at least one silver halide photographic emulsion layer containing below about 8.6 g of silver per square meter and containing a combination of at least one dye represented by formula (I) and at least one dye represented by formula (II) ##STR9## wherein A 1 and A 2 each represents a hydrogen atom or a halogen atom; A 3 and A 4 each represents a hydrogen atom, a halogen atom, an alkoxy group or a phenyl group, B 1 , B 2 , B 3 and B 4 each represents a hydrogen atom, a halogen atom or an alkoxy group; R, R 1 and R 2 each represents an alkyl group and at least one of R 1 and R 2 represents a sulfoalkyl group or a carboxylic group; R 0 represents a hydrogen atom or a lower alkyl group, R 3 and R 4 each has the same meaning as R 1 and R 2 ; X 1 represents an anion; m and n each represents an integer of 1 or 2, but m and n are 1 when the dye froms an inner salt, and X 2 represents an anion; and (2) a pair of fluorescent intensifying screens which upon exposure each emits light having a maximum emission in the green spectral range by exitation with radiation wherein at least 1/2 of the emission energy is in the wavelength range of above about 400 nm; wherein said radiographic sensitive material is separate from said fluorescent intensifying screens and is located between said fluorescent intensifying screens.
Claim 2
Dependent Claim 275 words
A silver halide radiographic sensitive element comprising (1) a silver halide radiographic sensitive material comprising a support having thereon at least one silver halide photographic emulsion layer containing below about 8.6 g of silver per square meter and containing a combination of at least one dye represented by formula (I) and at least one dye represented by formula (II) ##STR9## wherein A 1 and A 2 each represents a hydrogen atom or a halogen atom; A 3 and A 4 each represents a hydrogen atom, a halogen atom, an alkoxy group or a phenyl group, B 1 , B 2 , B 3 and B 4 each represents a hydrogen atom, a halogen atom or an alkoxy group; R, R 1 and R 2 each represents an alkyl group and at least one of R 1 and R 2 represents a sulfoalkyl group or a carboxylic group; R 0 represents a hydrogen atom or a lower alkyl group, R 3 and R 4 each has the same meaning as R 1 and R 2 ; X 1 represents an anion; m and n each represents an integer of 1 or 2, but m and n are 1 when the dye froms an inner salt, and X 2 represents an anion; and (2) a pair of fluorescent intensifying screens which upon exposure each emits light having a maximum emission in the green spectral range by exitation with radiation wherein at least 1/2 of the emission energy is in the wavelength range of above about 400 nm; wherein said radiographic sensitive material is separate from said fluorescent intensifying screens and is located between said fluorescent intensifying screens.

References Cited (Backward Citations)

US3864134A Cited
US3832189A Cited
US3854955A Cited
US3953215A Cited
US3912933A Cited
US3923515A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-10-29 1983-04-30 1983-10-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-10-29 1987-04-30 1987-10-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-10-29 1991-04-30 1991-10-30 $7700.00 Window Closed / Lapsed

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