US4171243A — Spray drying method

Claim 1

Independent Claim 276 words

In a method including spray drying material in a spray drying tower and then removing solid particulates and fumes from the hot effluent gases leaving said tower, wherein said tower receives a solids-containing, aqueous, liquid slurry and a heated gas stream for drying the solids contained in said slurry, the steps comprising: discharging from said spray drying tower hot effluent gases containing steam and having a temperature above the dew point of said discharged gases; dividing said discharged hot gases into a first portion and a second portion; heating said first portion of the discharged hot gases to a temperature above the temperature of the solids-containing, aqueous, liquid slurry, and further above the dew point of said discharged gases, without cooling said first portion below its dew point between said dividing step and said heating step; recycling said first portion to said spray drying tower as part of said heated gas stream, following said heating step, to increase the moisture content of said discharged gases; contacting said solids-containing, aqueous, liquid slurry in said spray drying tower with said heated gas stream including said recycled, heated gases to dry said slurry with said heated gas stream; subjecting said second portion of the discharged gases, having said increased moisture content resulting from said recycling step, to a condensing step by cooling said gases to agglomerate said solid particulates and fumes therein; and then removing said agglomerated solid particulates and fumes from said cooled gases, without heating said second portion between said condensing and removing steps; the moisture content of the discharged hot gases undergoing said condensing step being higher than the moisture content thereof absent said recycling step.

Claim 2

Dependent Claim 276 words

In a method including spray drying material in a spray drying tower and then removing solid particulates and fumes from the hot effluent gases leaving said tower, wherein said tower receives a solids-containing, aqueous, liquid slurry and a heated gas stream for drying the solids contained in said slurry, the steps comprising: discharging from said spray drying tower hot effluent gases containing steam and having a temperature above the dew point of said discharged gases; dividing said discharged hot gases into a first portion and a second portion; heating said first portion of the discharged hot gases to a temperature above the temperature of the solids-containing, aqueous, liquid slurry, and further above the dew point of said discharged gases, without cooling said first portion below its dew point between said dividing step and said heating step; recycling said first portion to said spray drying tower as part of said heated gas stream, following said heating step, to increase the moisture content of said discharged gases; contacting said solids-containing, aqueous, liquid slurry in said spray drying tower with said heated gas stream including said recycled, heated gases to dry said slurry with said heated gas stream; subjecting said second portion of the discharged gases, having said increased moisture content resulting from said recycling step, to a condensing step by cooling said gases to agglomerate said solid particulates and fumes therein; and then removing said agglomerated solid particulates and fumes from said cooled gases, without heating said second portion between said condensing and removing steps; the moisture content of the discharged hot gases undergoing said condensing step being higher than the moisture content thereof absent said recycling step.

Claim 3

Dependent Claim 34 words

In a method as recited in claim 1 and comprising: conducting said hot gases discharged from said spray drying tower through a cyclone separator before dividing said gases into said first and second portions.

Claim 4

Dependent Claim 26 words

In a method as recited in claim 1 wherein said removing step comprises directly scrubbing said second portion of gases to remove contaminants from said gases.

Claim 5

Dependent Claim 45 words

In a method as recited in claim 3 wherein said scrubbing step produces a mixture of scrubbed gases and scrubbing solution, said method further comprising: subjecting said mixture to a separating step in a cyclone separator to separate said scrubbed gases from said scrubbing solution.

Claim 6

Dependent Claim 35 words

In a method as recited in claim 1 wherein: said removing step comprises subjecting said second portion of gases to an electrostatic precipitation step after said condensing step for removal of contaminants from said gases.

Claim 7

Dependent Claim 87 words

In a method as recited in claim 5 wherein said solids-containing, aqueous, liquid slurry received in said spray drying tower is detergent slurry from a detergent-making process involving sulfonation, and wherein: said second portion of the discharged gases has a moisture content greater than 20% by volume; said second portion of the discharged gases is cooled to a temperature in the range 100°-130° F. prior to said electrostatic precipitation step; and the plume density of the gases following said electrostatic precipitation step being in the range 0-10%.

Claim 8

Dependent Claim 23 words

In a method as recited in claim 5 wherein: said condensing step comprises subjecting said second portion of gases to a scrubbing operation.

Claim 9

Dependent Claim 87 words

In a method as recited in claim 5 wherein said solids-containing, aqueous, liquid slurry received in said spray drying tower is detergent slurry from a detergent-making process involving sulfonation, and wherein: said second portion of the discharged gases has a moisture content greater than 20% by volume; said second portion of the discharged gases is cooled to a temperature in the range 100°-130° F. prior to said electrostatic precipitation step; and the plume density of the gases following said electrostatic precipitation step being in the range 0-10%.

Claim 10

Dependent Claim 41 words

In a method as recited in claim 6 and comprising: subjecting said gases to an entrainment separating step between said condensing step and said electrostatic precipitation step to remove some of the contaminants from said gases before the electrostatic precipitation step.

Claim 11

Dependent Claim 16 words

In a method as recited in claim 1 wherein said first portion comprises the major portion.

Claim 12

Dependent Claim 15 words

In a method as recited in claim 1 wherein said heating step utilizes indirect heating.

Claim 13

Dependent Claim 15 words

In a method as recited in claim 1 wherein said heating step utilizes direct heating.

Claim 14

Dependent Claim 66 words

In a method as recited in claim 1 wherein: said first portion of discharged hot gases has a first temperature, above the dew point thereof, at the time said first portion is subjected to said heating step; and said first portion has a second temperature substantially higher than said first temperature at the time it is recycled to said spray drying tower following said heating step.

Claim 15

Dependent Claim 178 words

In a method of spray drying material in a spray drying tower wherein said tower receives a solids-containing, aqueous, slurry and a heated gas stream containing air and stream for drying the solids contained in said slurry, and wherein hot gases containing solid particles, steam and other vaporous constituents are discharged from said tower, the steps comprising: discharging said hot gases at a temperature above the dew point of said vaporous constituents; dividing said discharged hot gases into a first portion and a second portion; recycling said first portion of the discharged hot gases back to said spray drying tower to increase the moisture content of said discharged gases; cooling the unrecycled second portion of said hot gases, having said increased moisture content due to said recycling step, to a temperature below the dew point of said vaporous constituents to reduce the volume of said gases and agglomerate said other vaporous constituents thereof; and then subjecting said cooled gases to an electrostatic precipitation step to remove contaminants from said gases while said gases are at said cooled temperature.

Claim 16

Dependent Claim 178 words

In a method of spray drying material in a spray drying tower wherein said tower receives a solids-containing, aqueous, slurry and a heated gas stream containing air and stream for drying the solids contained in said slurry, and wherein hot gases containing solid particles, steam and other vaporous constituents are discharged from said tower, the steps comprising: discharging said hot gases at a temperature above the dew point of said vaporous constituents; dividing said discharged hot gases into a first portion and a second portion; recycling said first portion of the discharged hot gases back to said spray drying tower to increase the moisture content of said discharged gases; cooling the unrecycled second portion of said hot gases, having said increased moisture content due to said recycling step, to a temperature below the dew point of said vaporous constituents to reduce the volume of said gases and agglomerate said other vaporous constituents thereof; and then subjecting said cooled gases to an electrostatic precipitation step to remove contaminants from said gases while said gases are at said cooled temperature.

Claim 17

Dependent Claim 152 words

In a method as recited in claim 14 wherein: said slurry is a detergent slurry made by a process in which organic reactants are sulfonated; said slurry comprises a first unreacted organic reactant when the slurry enters said spray drying tower; said heated gas stream has a temperature above 300° F. and up to about 1000° F. when the gas stream is received within said spray drying tower; at least part of said unreacted organic reactant is converted, by said heated gas stream within said spray drying tower, to a second unreacted organic reactant having a lower dew point than said first unreacted organic reactant; said other vaporous constituents, in the hot gases discharged from said tower, comprise unreacted organic reactants including at least said second unreacted organic reactant; and said cooling step comprises cooling said hot gases to a cooled temperature below the dew point of said second unreacted organic reactant.

Claim 18

Dependent Claim 63 words

In a method as recited in claim 14 wherein: said slurry is a detergent slurry made by a process in which organic reactants are sulfonated; said gases subjected to said electrostatic separation step are cooled to a temperature in the range 100°-130° F.; and the moisture content of said gases as a result of said recycling step, is greater than 20% by volume.

Claim 19

Dependent Claim 26 words

In a method as recited in claim 14 wherein: said gases are subjected to a scrubbing step between said cooling step and said electrostatic precipitation step.

Claim 20

Dependent Claim 42 words

In a method as recited in claim 14 and comprising: condensing said vaporous constituents to liquid during said cooling step; and removing, from said cooled gases, prior to said electrostatic precipitation step, a portion of the liquid condensed during said cooling step.

Claim 21

Dependent Claim 31 words

In a method as recited in claim 18 wherein: said removing step comprises passing said cooled gases through an entrainment separator after said condensing step and before said electrostatic precipitation step.

Claim 22

Dependent Claim 53 words

In a method as recited in claim 14 wherein: said cooling step is conducted at least in part in a scrubber; and said cooled gases are subjected to a separating step, in a cyclone separator, between said cooling step and said electrostatic precipitation step, to separate said cooled gases from the scrubbing solution.

Claim 23

Dependent Claim 40 words

In a method as recited in claim 20 wherein: said cooling step comprises passing said hot gases through a heat exchanger immediately prior to said scrubber to cool at least some of said vaporous constituents below the dew point thereof.

Claim 24

Dependent Claim 28 words

In a method as recited in claim 14 wherein: said cooling and electrostatic precipitation steps are performed solely on said second portion of gases after said dividing step.

Claim 25

Dependent Claim 22 words

In a method as recited in claim 14 and comprising: separating solid particles from said discharged hot gases, before said cooling step.

Claim 26

Dependent Claim 43 words

In a method as recited in claim 14 wherein: the moisture content and the temperature of the gases subjected to said electrostatic precipitation step are controlled to provide said gases, following said electrostatic precipitation step, with a plume density in the range 0-10%.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1982-10-15	1983-04-16	1983-10-16	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1986-10-15	1987-04-16	1987-10-16	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	1990-10-15	1991-04-16	1991-10-16	$7700.00	Window Closed / Lapsed

Spray drying method

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