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US4170538A Expired / Lapsed US ⏱️ 0.0 years remaining

Diaphragm having zirconium and magnesium compounds in a porous matrix

Assignee: PPG Industries Inc
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Filing: 1978-10-20
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Granted: 1979-10-09
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Expires: 1998-10-20
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Abstract

Abstract Disclosed is a diaphragm having a porous matrix, e.g., a polymeric or asbestos matrix with a layer of magnesium oxide and a hydrous oxide of zirconium therein.

Inventors

  • 👤 Robert B. Simmons

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 10:38
CPC Classifications
C; C25; C25B; C25B13/00; C25B13/04; C25B13/05; C25B13/07

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 49 words
In a method of preparing a hydrophilic matrix comprising contacting a porous matrix with a zirconium compound and converting the zirconium compound to a hydrous oxide of zirconium, the improvement comprising depositing a magnesium compound and the zirconium compound in the porous matrix and converting both compounds to oxides.
Claim 2
Dependent Claim 49 words
In a method of preparing a hydrophilic matrix comprising contacting a porous matrix with a zirconium compound and converting the zirconium compound to a hydrous oxide of zirconium, the improvement comprising depositing a magnesium compound and the zirconium compound in the porous matrix and converting both compounds to oxides.
Claim 3
Dependent Claim 14 words
The method of claim 1 comprising codepositing the zirconium compound and the magnesium compound.
Claim 4
Dependent Claim 30 words
The method of claim 2 comprising contacting the porous body with an aqueous solution comprising 1 to 30 weight percent Mg, basis total weight of magnesium and zirconium as oxides.
Claim 5
Dependent Claim 58 words
The method of claim 2 wherein the Mg is present in the solution as magnesium chloride, the zirconium is present in the solution as zirconium oxychloride, comprising contacting the porous matrix with the aqueous solution of zirconium oxychloride and magnesium chloride, and thereafter contacting the porous matrix with ammonia whereby to hydrolyze the zirconium oxychloride and magnesium chloride.
Claim 6
Dependent Claim 13 words
The method of claim 2 wherein the porous matrix is a hydrophobic fluorocarbon.
Claim 7
Dependent Claim 23 words
The method of claim 5 comprising depositing a hydrophilic fluorocarbon within the hydrophobic hydrocarbon porous matrix and thereafter codepositing the zirconium and magnesium.
Claim 8
Dependent Claim 13 words
The method of claim 2 wherein the porous matrix is an asbestos mat.
Claim 9
Dependent Claim 28 words
A diaphragm for a chlor-alkali electrolytic cell comprising: a porous matrix; and a codeposited film of magnesium oxide and a hydrous oxide of zirconium in said porous matrix.
Claim 10
Dependent Claim 28 words
A diaphragm for a chlor-alkali electrolytic cell comprising: a porous matrix; and a codeposited film of magnesium oxide and a hydrous oxide of zirconium in said porous matrix.
Claim 11
Dependent Claim 23 words
The diaphragm of claim 8 comprising about 1 to 30 weight percent magnesium oxide, basis total magnesium oxide and hydrous oxide of zirconium.
Claim 12
Dependent Claim 14 words
The diaphragm of claim 8 wherein the porous matrix is a porous, hydrophobic fluorocarbon.
Claim 13
Dependent Claim 13 words
The diaphragm of claim 8 wherein the porous matrix is an asbestos mat.

References Cited (Backward Citations)

US1942183A Cited
US2661288A Cited
US3056647A Cited
US3541030A Cited
US3479266A Cited
US3479267A Cited
US3703413A Cited
US3702267A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-10-08 1983-04-09 1983-10-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-10-08 1987-04-09 1987-10-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-10-08 1991-04-09 1991-10-09 $7700.00 Window Closed / Lapsed

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