US4170482A
Expired / Lapsed
US
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Jet printing ink composition containing an acetylenic compound and a lactone
Assignee: M&T Chemicals Inc
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Filing: 1978-09-08
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Granted: 1979-10-09
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Expires: 1998-09-08
Abstract
Abstract An ink composition for use in jet printing comprising an aqueous solution of a water-soluble dye and a humectant consisting of the combination of at least one water-soluble acetylenic compound and the internal anhydride of at least one carboxylic acid in a ratio of 90:1 of the former to 1:90 of the latter.
Inventors
- 👤 Ishwar R. Mansukhani
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 23:08
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
275 words
In a process for information recording comprising producing a fine jet of colored aqueous liquid, directing the jet of colored liquid onto a recording medium, modulating the density of the applied jet by an electric field in accordance with the information to be recorded, the improvement comprising the presence as a humectant consisting of the combination of at least one water-soluble acetylenic compound selected from α-substituted acetylenic compounds exhibiting the structural formula: ##STR6## in which each of R 1 and R 2 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and R 1 and R 2 may together be a carbonyl oxygen; R 3 may be a substituent of the group consisting of hydrogen, halogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkenyl and alkynyl groups, and substituted-alkyl groups having the formula: ##STR7## in which each of R 4 and R 5 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, and hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and when R 1 and R 2 together are carbonyl oxygen, R 3 may be an aryl group, including hydroxy and alkoxy and alkyl-substituted aryl; each of R.sub.α and R.sub.α' may be substituents selected from the group consisting of hydroxy, alkoxy, carboxy-substituted alkoxy, formoxy, alkanoxy, halogen and polyoxy groups and the internal anhydride of at least one carboxylic acid selected from the group consisting of the lactones of fatty acids, the lactones of alicyclic acids, the lactones of acetylenic acids, and the lactones of aromatic acids in a ratio of 90:1 of the former to 1:90 of the latter.
Claim 2
Dependent Claim
275 words
In a process for information recording comprising producing a fine jet of colored aqueous liquid, directing the jet of colored liquid onto a recording medium, modulating the density of the applied jet by an electric field in accordance with the information to be recorded, the improvement comprising the presence as a humectant consisting of the combination of at least one water-soluble acetylenic compound selected from α-substituted acetylenic compounds exhibiting the structural formula: ##STR6## in which each of R 1 and R 2 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and R 1 and R 2 may together be a carbonyl oxygen; R 3 may be a substituent of the group consisting of hydrogen, halogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkenyl and alkynyl groups, and substituted-alkyl groups having the formula: ##STR7## in which each of R 4 and R 5 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, and hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and when R 1 and R 2 together are carbonyl oxygen, R 3 may be an aryl group, including hydroxy and alkoxy and alkyl-substituted aryl; each of R.sub.α and R.sub.α' may be substituents selected from the group consisting of hydroxy, alkoxy, carboxy-substituted alkoxy, formoxy, alkanoxy, halogen and polyoxy groups and the internal anhydride of at least one carboxylic acid selected from the group consisting of the lactones of fatty acids, the lactones of alicyclic acids, the lactones of acetylenic acids, and the lactones of aromatic acids in a ratio of 90:1 of the former to 1:90 of the latter.
Claim 3
Dependent Claim
12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 1,4-di-(β-hydroxyethoxy)-2-butyne.
Claim 4
Dependent Claim
12 words
The process of claim 1 wherein said water-soluble acethylenic compound is 1,4-di-(β-hydroxy-γ-chloropropoxy)-2-butyne.
Claim 5
Dependent Claim
12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 1,4-di-(β-,γ-epoxypropoxy)-2-butyne.
Claim 6
Dependent Claim
12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 1,4-di-(β-hydroxy-γ-butenoxy)-2-butyne.
Claim 7
Dependent Claim
12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 1,4-di-(2'-hydroxy-4'-oxa-6'-heptenoxy)-2-butyne.
Claim 8
Dependent Claim
12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 2-butyne-1,4-diol.
Claim 9
Dependent Claim
13 words
The process of claim 1 wherein said water-soluble acetylenic compound is propargyl alcohol.
Claim 10
Dependent Claim
12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 2-methyl-3-butyn-2-ol.
Claim 11
Dependent Claim
12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 1,4-di-(β-sulfoethoxy)-2-butyne.
Claim 12
Dependent Claim
12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 3-(β-hydroxyethoxy)-propyne.
Claim 13
Dependent Claim
12 words
The process of claim 1 wherein said water-soluble acetylenic compound is 3-(β-hydroxypropoxy)-propyne.
Claim 14
Dependent Claim
11 words
The process of claim 1 wherein said internal anhydride is butyrolactone.
Claim 15
Dependent Claim
242 words
An ink composition for use in jet printing comprising an aqueous solution of a water-soluble dye and a humectant consisting of the combination of at least one water-soluble acetylenic compound selected from α-substituted acetylenic compounds exhibiting the structural formula: ##STR8## in which each of R 1 and R 2 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and R 1 and R 2 may together be a carbonyl oxygen; R 3 may be a substituent of the group consisting of hydrogen, halogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkenyl and alkynyl groups, and substituted-alkyl groups having the formula: ##STR9## in which each of R 4 and R 5 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, and hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and when R 1 and R 2 together are carbonyl oxygen, R 3 may be an aryl group, including hydroxy and alkoxy and alkyl-substituted aryl; each of R.sub.α and R.sub.α' may be substituents selected from the group consisting of hydroxy, alkoxy, carboxy-substituted alkoxy, formoxy, alkanoxy, halogen and polyoxy groups and the internal anhydride of at least one carboxylic acid selected from the group consisting of the lactones of fatty acids, the lactones of alicyclic acids, the lactones of acetylenic acids, and the lactones of aromatic acids in a ratio of 90:1 of the former to 1:90 of the latter.
Claim 16
Dependent Claim
242 words
An ink composition for use in jet printing comprising an aqueous solution of a water-soluble dye and a humectant consisting of the combination of at least one water-soluble acetylenic compound selected from α-substituted acetylenic compounds exhibiting the structural formula: ##STR8## in which each of R 1 and R 2 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and R 1 and R 2 may together be a carbonyl oxygen; R 3 may be a substituent of the group consisting of hydrogen, halogen, alkyl, alkenyl, alkynyl, hydroxy-substituted and alkoxy-substituted alkenyl and alkynyl groups, and substituted-alkyl groups having the formula: ##STR9## in which each of R 4 and R 5 may be substituents selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, and hydroxy-substituted and alkoxy-substituted alkyl, alkenyl, and alkynyl groups, and when R 1 and R 2 together are carbonyl oxygen, R 3 may be an aryl group, including hydroxy and alkoxy and alkyl-substituted aryl; each of R.sub.α and R.sub.α' may be substituents selected from the group consisting of hydroxy, alkoxy, carboxy-substituted alkoxy, formoxy, alkanoxy, halogen and polyoxy groups and the internal anhydride of at least one carboxylic acid selected from the group consisting of the lactones of fatty acids, the lactones of alicyclic acids, the lactones of acetylenic acids, and the lactones of aromatic acids in a ratio of 90:1 of the former to 1:90 of the latter.
Claim 17
Dependent Claim
12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 1,4-di-(β-hydroxyethoxy)-2-butyne.
Claim 18
Dependent Claim
12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 1,4-di-(β-hydroxy-γ-chloropropoxy)-2-butyne.
Claim 19
Dependent Claim
12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 1,4-di-(β-,γ-epoxypropoxy)-2-butyne.
Claim 20
Dependent Claim
12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 1,4-di-(β-hydroxy-γ-butenoxy)-2-butyne.
Claim 21
Dependent Claim
12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 1,4-di-(2'-hydroxy-4'-oxa-6'-heptenoxy)-2-butyne.
Claim 22
Dependent Claim
12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 2-butyne-1,4-diol.
Claim 23
Dependent Claim
13 words
The composition of claim 14 wherein said water-soluble acetylenic compound is propargyl alcohol.
Claim 24
Dependent Claim
12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 2-methyl-3-butyn-2-ol.
Claim 25
Dependent Claim
12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 1,4-di-(β-sulfoethoxy)-2-butyne.
Claim 26
Dependent Claim
12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 3-(β-hydroxyethoxy)-propyne.
Claim 27
Dependent Claim
12 words
The composition of claim 14 wherein said water-soluble acetylenic compound is 3-(β-hydroxypropoxy)-propyne.
References Cited (Backward Citations)
US3692548A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-10-08 | 1983-04-09 | 1983-10-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-10-08 | 1987-04-09 | 1987-10-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-10-08 | 1991-04-09 | 1991-10-09 | $7700.00 | Window Closed / Lapsed |