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US4170480A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermally developable light-sensitive material

Assignee: Fujifilm Holdings Corp
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Filing: 1977-09-07
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Granted: 1979-10-09
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Expires: 1997-09-07
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Abstract

Abstract A thermally developable light-sensitive material comprising a support having therein or in at least one layer thereon (a) an organic silver salt, (b) a photocatalyst, and (c) a reducing agent, and additionally (d) at least one 1,2,4-triazole compound.

Inventors

  • 👤 Shinpei Ikenoue
  • 👤 Takao Masuda
  • 👤 Harumi Katsuyama
  • 👤 Nobuyoshi Sekikawa
  • 👤 Tadao Shishido
  • 👤 Nobuo Sakai

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 16:30
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/494; G03C1/498; G03C1/49836; G03C1/49845

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 372 words
A thermally developable light-sensitive material comprising a support having therein or in at least one layer thereon (a) an organic silver salt, (b) a light sensitive silver halide or a component capable of forming a light sensitive silver halide upon reaction with said organic silver salt (a), and (c) a reducing agent, and additionally (d) at least one 1,2,4-triazole compound represented by the following formula (I): ##STR5## wherein M represents a hydrogen atom or an alkali metal atom and R 1 and R 2 , which may be the same or different, each represents a halogen atom, a nitro group or a carbon-containing substituent selected from the group consisting of an alkyl group having 1 to 18 carbon atoms, which may be straight chain, branched chain or cyclic and which may be substituted with one or more of a halogen atom, a hydroxyl group, a carboxyl group or a carbon-containing substituent having 1 to 12 carbon atoms; an aryl group having 6 to 18 carbon atoms which may be monocyclic or bicyclic and which may be substituted with one or more of a halogen atom, a nitro group, a hydroxy group, a carboxy group or a carbon-containing substituent having 1 to 12 carbon atoms; a substituted oxy group, a substituted thio group, a substituted sulfinyl group, a substituted sulfonyl group or a substituted amino group having the general formulas, respectively: R'--o-- r'--s-- r'--so 2 -- r'--so 3 -- r' n --NH m -- or R"═N-- wherein n and m each represents 0 or an integer of 1 to 2, where n+m is equal to 2, and R' represents a carbon-containing substituent having 1 to 12 carbon atoms and wherein R" represents a 5- or 6-membered heterocyclic ring containing a nitrogen atom which may form a fused ring together with a benzene nucleus and which may be substituted with one or more alkyl groups having 1 to 4 carbon atoms; or a 5- or 6-membered heterocyclic ring which may form a fused ring together with a benzene ring and which may be substituted with one or more alkyl groups having 1 to 4 carbon atoms; wherein said component (d) is added after formation of a mixture of said component (a) and component (b).
Claim 2
Dependent Claim 372 words
A thermally developable light-sensitive material comprising a support having therein or in at least one layer thereon (a) an organic silver salt, (b) a light sensitive silver halide or a component capable of forming a light sensitive silver halide upon reaction with said organic silver salt (a), and (c) a reducing agent, and additionally (d) at least one 1,2,4-triazole compound represented by the following formula (I): ##STR5## wherein M represents a hydrogen atom or an alkali metal atom and R 1 and R 2 , which may be the same or different, each represents a halogen atom, a nitro group or a carbon-containing substituent selected from the group consisting of an alkyl group having 1 to 18 carbon atoms, which may be straight chain, branched chain or cyclic and which may be substituted with one or more of a halogen atom, a hydroxyl group, a carboxyl group or a carbon-containing substituent having 1 to 12 carbon atoms; an aryl group having 6 to 18 carbon atoms which may be monocyclic or bicyclic and which may be substituted with one or more of a halogen atom, a nitro group, a hydroxy group, a carboxy group or a carbon-containing substituent having 1 to 12 carbon atoms; a substituted oxy group, a substituted thio group, a substituted sulfinyl group, a substituted sulfonyl group or a substituted amino group having the general formulas, respectively: R'--o-- r'--s-- r'--so 2 -- r'--so 3 -- r' n --NH m -- or R"═N-- wherein n and m each represents 0 or an integer of 1 to 2, where n+m is equal to 2, and R' represents a carbon-containing substituent having 1 to 12 carbon atoms and wherein R" represents a 5- or 6-membered heterocyclic ring containing a nitrogen atom which may form a fused ring together with a benzene nucleus and which may be substituted with one or more alkyl groups having 1 to 4 carbon atoms; or a 5- or 6-membered heterocyclic ring which may form a fused ring together with a benzene ring and which may be substituted with one or more alkyl groups having 1 to 4 carbon atoms; wherein said component (d) is added after formation of a mixture of said component (a) and component (b).
Claim 3
Dependent Claim 37 words
The thermally developable light-sensitive material of claim 1, wherein said material additionally contains an acid stabilizer selected from the group consisting of a rosin, a long-chain aliphatic carboxylic acid, an aromatic carboxylic acid and a dicarboxylic acid.
Claim 4
Dependent Claim 30 words
The thermally developable light-sensitive material of claim 1, wherein said organic silver salt (a) is a silver salt of a long-chain aliphatic carboxylic acid having 10 to 40 carbon atoms.
Claim 5
Dependent Claim 48 words
The thermally developable light-sensitive material of claim 1, wherein said organic silver salt (a), said light-sensitive silver halide or said component capable of forming said light-sensitive silver halide (b), said reducing agent (c) and said 1,2,4-triazole compount (d) are all present in the same layer on said support.
Claim 6
Dependent Claim 83 words
The thermally developable light-sensitive material of claim 1, wherein said organic silver salt (a), said light-sensitive silver halide or said component capable of forming said light-sensitive silver halide (b) and said 1,2,4-triazole compound (d) are all present in the same layer on said support and said reducing agent (c) is present in a layer adjacent said layer containing said organic silver salt (a), said light-sensitive silver halide or said component capable of forming said light-sensitive silver halide (b) and said 1,2,4-triazole compound (d).
Claim 7
Dependent Claim 14 words
The thermally developable light-sensitive material of claim 1, wherein said 1,2,4-triazole compound is ##STR6##
Claim 8
Dependent Claim 33 words
The thermally developable light-sensitive material of claim 1, wherein said 1,2,4-triazole compound is present in an amount of about 10 -5 mol to 0.5 mol per mol of said organic silver salt (a).
Claim 9
Dependent Claim 24 words
The thermally developable light-sensitive material of claim 1, wherein said material additionally contains at least one of a thiosulfonic acid or a sulfinic acid.
Claim 10
Dependent Claim 35 words
The thermally developable light-sensitive material of claim 1, wherein said organic silver salt is a silver salt of an organic compound containing an imino group, a mercapto group, a thione group or a carboxyl group.

References Cited (Backward Citations)

US3617289A Cited
US3832186A Cited
US4065312A Cited
US3893860A Cited
DE2641964A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-10-08 1983-04-09 1983-10-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-10-08 1987-04-09 1987-10-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-10-08 1991-04-09 1991-10-09 $7700.00 Window Closed / Lapsed

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