US4169211A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the production of 2,2-(4,4'-dihydroxydiphenyl)propane
Assignee: Societa Italiana Resine SpA SIR
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Filing: 1977-07-13
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Granted: 1979-09-25
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Expires: 1997-07-13
Abstract
Abstract Process for the production of 2,2-(4,4'-dihydroxydiphenyl) propane comprising reacting phenol with acetone in a molar ratio of at least 2:1 but not exceeding 10:1 in the presence of an acidic agent at a temperature not exceeding 80° C. to substantially complete reaction of the acetone, separating the acidic agent from the reaction product, bringing the product freed from acidic agent into contact with a material chosen from between activated carbon and active earths at a temperature in the range of from about 60° to 120° C. for a time in the range of from about 1 to 120 minutes and distilling the product obtained in the treatment with the active material to recover the 2,2-(4,4'-dihydroxydiphenyl-propane.
Inventors
- 👤 Ferdinando Ligorati
- 👤 Vittorio E. Nova
- 👤 Giancarlo Aglietti
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 19:03
CPC Classifications
C; C07; C07C; C07C37/00; C07C37/11; C07C37/20; C07C37/68; C07C37/70; C07C37/74; C07C37/82
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
186 words
In a process for the production of 2,2-(4,4'-dihydroxydiphenyl)-propane characterized by hazen color not exceeding 25 and a crystallization point of at least 156.5° C. comprising the steps of: (a) reacting phenol with acetone in a molar ratio of at least 2:1 but not exceeding 10:1 in the presence of an acidic agent at a temperature not exceeding 80° C. to substantially complete reaction of the acetone, (b) separating the acidic agent from the reaction product, and (c) distilling the product at a pressure of from about 1 to 20 mm Hg and at a distillation temperature of from about 160° to 200° C. to recover the 2,2-(4,4'-dihydroxydiphenyl)-propane, wherein the improvement comprises bringing the product from step (b) freed from acidic agent into contact with a material selected from the group consisting of activated carbon and active earths at a temperature of from about 60° to 120° C. for a time of from about 10 to 120 minutes prior to carrying out said distillation step (c), whereby said 2,2-(4,4'-dihydroxydiphenyl)-propane having a hazen color not exceeding 25 and a crystallization point of at least 156.5° C. is produced.
Claim 2
Dependent Claim
186 words
In a process for the production of 2,2-(4,4'-dihydroxydiphenyl)-propane characterized by hazen color not exceeding 25 and a crystallization point of at least 156.5° C. comprising the steps of: (a) reacting phenol with acetone in a molar ratio of at least 2:1 but not exceeding 10:1 in the presence of an acidic agent at a temperature not exceeding 80° C. to substantially complete reaction of the acetone, (b) separating the acidic agent from the reaction product, and (c) distilling the product at a pressure of from about 1 to 20 mm Hg and at a distillation temperature of from about 160° to 200° C. to recover the 2,2-(4,4'-dihydroxydiphenyl)-propane, wherein the improvement comprises bringing the product from step (b) freed from acidic agent into contact with a material selected from the group consisting of activated carbon and active earths at a temperature of from about 60° to 120° C. for a time of from about 10 to 120 minutes prior to carrying out said distillation step (c), whereby said 2,2-(4,4'-dihydroxydiphenyl)-propane having a hazen color not exceeding 25 and a crystallization point of at least 156.5° C. is produced.
Claim 3
Dependent Claim
46 words
The process of claim 1, wherein the reaction of phenol with acetone is carried out at a temperature of from about 40° to 80° C. and at a pressure of from about 1 to 20 atmospheres for a time of from about 1 to 10 hours.
Claim 4
Dependent Claim
14 words
The process of claim 1, wherein hydrochloric acid is used as the acidic agent.
Claim 5
Dependent Claim
61 words
The process of claim 1, wherein the reaction of phenol with acetone is carried out in the presence of a solvent in a quantity not exceeding 5% with respect to the weight of the 2,2-(4,4'-dihydroxydiphenyl)propane finally formed, the said solvent being selected from the group consisting of aromatic and paraffinic, chlorinated or unchlorinated hydrocarbons having a boiling point below 150° C.
Claim 6
Dependent Claim
45 words
The process of claim 1, wherein the active material is present in a divided form, with dimensions of from about 1 to 5 mm, a porosity of from about 0.1 to 0.9 cc/g, and pores having a radius of from about 10 to 1000 A.
Claim 7
Dependent Claim
18 words
The process of claim 1, wherein activated carbon obtained from bituminous coals is used as the active material.
Claim 8
Dependent Claim
55 words
The process of claim 1, wherein the contact of the deacidified condensation product with the active material is brought about by allowing the deacidified product to percolate through a fixed bed of activated carbon, the percolation rate being adjusted so that the contact time is in the range of from about 10 to 120 minutes.
Claim 9
Dependent Claim
56 words
The process of claim 1, wherein an aromatic organic solvent having a boiling point below 136° C. or a paraffinic organic solvent having a boiling point below 126° C. is added to the deacidified condensation product in a quantity not exceeding 10% with respect to the weight of the 2,2-(4,4'-dihydroxydiphenyl)-propane present in the condensation product itself.
Claim 10
Dependent Claim
26 words
The process of claim 1, wherein the distillation of the product obtained in the treatment with the active material is carried out by the thin-film technique.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-09-24 | 1983-03-26 | 1983-09-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-09-24 | 1987-03-26 | 1987-09-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-09-24 | 1991-03-26 | 1991-09-25 | $7700.00 | Window Closed / Lapsed |