US4169076A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for producing clear aqueous solution of magnesium salt of anionic surface active agent
Assignee: Lion Fat and Oil Co Ltd
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Filing: 1978-05-16
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Granted: 1979-09-25
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Expires: 1998-05-16
Abstract
Abstract Disclosed is a process for producing a clear aqueous solution of the magnesium salt of an anionic surface active agent by first adding alkylbenzene sulfonic acid to an aqueous slurry containing an anionic surface active agent and an alkaline agent in a specified amount and, then, adding a pH controlling agent to the resultant solution.
Inventors
- 👤 Akira Kawakami
- 👤 Yoshio Aoki
- 👤 Toshiaki Ogoshi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 20:03
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/02; C11D1/12; C11D1/22; Y; Y10; Y10S; Y10S516/00; Y10S516/01; Y10S516/02
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
265 words
A process for producing a clear aqueous solution of the magnesium salt of an anionic surface active agent consisting essentially of the steps of: (a) adding alkylbenzene sulfonic acid to an aqueous slurry containing a water-soluble anionic surface active agent selected from the group consisting of: (1) the sodium and magnesium salts of olefin sulfonic acids of 8 to 22 carbon atoms, (2) the sodium salts of alkylbenzene sulfonic acids of 10 to 15 carbon atoms, (3) the sodium and magnesium salts of alkyl sulfuric esters having alkyl radicals of 8 to 22 carbon atoms, and (4) the sodium and magnesium salts of alkyl ether sulfuric esters having alkyl radicals of 8 to 22 carbon atoms and having an average addition mole number of ethylene oxide of 1 to 10, and containing at least one alkaline compound selected from the group consisting of magnesium hydroxide and magnesium oxide, to thereby provide a clear aqueous solution having a pH of from approximately 2 to approximately 4, the amount of said alkylbenzene sulfonic acid being (i) sufficient to yield a pH within the range of from approximately 2 to approximately 4, and (ii) to provide a weight ratio of the water-soluble anionic surface active agent in the slurry to the alkylbenzene sulfonic acid within the range of from 20:80 to 95:5, and then: (b) adding at least one alkaline compound from the group consisting of alkali metal hydroxides, ammonia and triethanolamine to the aqueous solution in a sufficient amount to adjust the pH of the resultant solution within the range of from approximately 5.5 to approximately 8.
Claim 2
Dependent Claim
265 words
A process for producing a clear aqueous solution of the magnesium salt of an anionic surface active agent consisting essentially of the steps of: (a) adding alkylbenzene sulfonic acid to an aqueous slurry containing a water-soluble anionic surface active agent selected from the group consisting of: (1) the sodium and magnesium salts of olefin sulfonic acids of 8 to 22 carbon atoms, (2) the sodium salts of alkylbenzene sulfonic acids of 10 to 15 carbon atoms, (3) the sodium and magnesium salts of alkyl sulfuric esters having alkyl radicals of 8 to 22 carbon atoms, and (4) the sodium and magnesium salts of alkyl ether sulfuric esters having alkyl radicals of 8 to 22 carbon atoms and having an average addition mole number of ethylene oxide of 1 to 10, and containing at least one alkaline compound selected from the group consisting of magnesium hydroxide and magnesium oxide, to thereby provide a clear aqueous solution having a pH of from approximately 2 to approximately 4, the amount of said alkylbenzene sulfonic acid being (i) sufficient to yield a pH within the range of from approximately 2 to approximately 4, and (ii) to provide a weight ratio of the water-soluble anionic surface active agent in the slurry to the alkylbenzene sulfonic acid within the range of from 20:80 to 95:5, and then: (b) adding at least one alkaline compound from the group consisting of alkali metal hydroxides, ammonia and triethanolamine to the aqueous solution in a sufficient amount to adjust the pH of the resultant solution within the range of from approximately 5.5 to approximately 8.
Claim 3
Dependent Claim
39 words
A process as claimed in claim 1 wherein the addition amount of the alkylbenzene sulfonic acid is within the range of from 1.03 to 1.1 chemical equivalent, based on one chemical equivalent of said alkaline compound in the slurry.
Claim 4
Dependent Claim
32 words
A process as claimed in claim 1 wherein said weight ratio of the water-soluble anionic surface active agent to the alkylbenzene sulfonic acid is within the range of from 20:80 to 80:20.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-09-24 | 1983-03-26 | 1983-09-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-09-24 | 1987-03-26 | 1987-09-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-09-24 | 1991-03-26 | 1991-09-25 | $7700.00 | Window Closed / Lapsed |