US4168277A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Production of tetraethyl ammonium perfluoroalkyl sulphonate
Assignee: Bayer AG
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Filing: 1977-12-07
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Granted: 1979-09-18
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Expires: 1997-12-07
Abstract
Abstract Production of tetraethyl ammonium perfluoroalkyl sulphonates (C 2 H 5 ) 4 N⊕R F SO 3 ⊖, wherein R F represents a perfluorinated alkyl radical with about 4 to 10 carbon atoms, by reacting crude perfluoroalkyl sulphonic acid fluoride, i.e. perfluoroalkyl sulphonic acid fluoride which has not been especially purified, with triethylamine and an ethoxy silane, preferably dimethyl diethoxy silane, methyl triethoxy silane or tetraethoxy silane in an inert solvent at temperatures of about 10° to 60° C., preferably about 20° to 40° C. The process according to the invention is particularly suitable for the production of tetraethyl ammonium perfluorooctane sulphonate.
Inventors
- 👤 Karl-Heinz Mitschke
- 👤 Hans Niederprum
- 👤 Johann-Nikolaus Meussdoerffer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 10:59
CPC Classifications
C; C07; C07C; C07C309/00; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/12; C07F7/121; C07F7/123
Claims Analysis
Total Claims: 3
Claim 1
Independent Claim
95 words
A process for the production of a tetraethyl ammonium perfluoroalkyl sulphonate comprising reacting a perfluoroalkyl sulphonyl fluoride with triethylamine and an ethoxysilane selected from the group consisting of dimethyldiethoxysilane, methyltriethoxysilane and tetraethoxysilane, the perfluoroalkyl sulphonyl fluoride being of a purity of the order of about 60% and being an electrolysis product from an anodic fluorination of an octane sulphohalide in anhydrous hydrogen fluoride, the ethoxysilane being employed in at least about a 20% stoichiometric excess, the reaction being effected in an inert solvent medium and at a temperature of about 10° C. to 60° C.
Claim 2
Dependent Claim
95 words
A process for the production of a tetraethyl ammonium perfluoroalkyl sulphonate comprising reacting a perfluoroalkyl sulphonyl fluoride with triethylamine and an ethoxysilane selected from the group consisting of dimethyldiethoxysilane, methyltriethoxysilane and tetraethoxysilane, the perfluoroalkyl sulphonyl fluoride being of a purity of the order of about 60% and being an electrolysis product from an anodic fluorination of an octane sulphohalide in anhydrous hydrogen fluoride, the ethoxysilane being employed in at least about a 20% stoichiometric excess, the reaction being effected in an inert solvent medium and at a temperature of about 10° C. to 60° C.
Claim 3
Dependent Claim
24 words
A process as claimed in claim 1, wherein the temperature is about 20° to 40° C. and the solvent is chlorobenzene, toluene or ether.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-09-17 | 1983-03-19 | 1983-09-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-09-17 | 1987-03-19 | 1987-09-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-09-17 | 1991-03-19 | 1991-09-18 | $7700.00 | Window Closed / Lapsed |