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US4168223A Expired / Lapsed US ⏱️ 0.0 years remaining

Electroplating bath for depositing tin or tin alloy with brightness

Assignee: Dipsol Chemicals Co Ltd
•
Filing: 1978-11-15
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Granted: 1979-09-18
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Expires: 1998-11-15
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Abstract

Abstract An electroplating bath for depositing tin or a tin alloy with satisfactory brightness, which comprises a mother bath of a pH-value ranging from 4 to 8 and containing citric acid or its salt, an ammonium salt and a water-soluble polymer as a brightener. The bath may further comprise an aldehyde compound as a co-brightener.

Inventors

  • 👤 Shuji Igarashi
  • 👤 Yoshikazu Fujisawa
  • 👤 Toshio Igarashi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 03:19
CPC Classifications
C; C25; C25D; C25D3/00; C25D3/02; C25D3/30; C25D3/32; C25D3/56; C25D3/60

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 72 words
An electroplating bath for depositing tin or a tin-alloy with brightness, characterized by adding to a tin or tin-alloy mother bath of a pH-value ranging from 4 to 8, which contains citric acid or its salt and an ammonium salt, a brightener comprising a water-soluble polymer selected from the group consisting of a polyoxyethylene, a derivative thereof and a reaction product of an epoxy compound with ethylene glycol, propylene glycol or glycerine.
Claim 2
Dependent Claim 72 words
An electroplating bath for depositing tin or a tin-alloy with brightness, characterized by adding to a tin or tin-alloy mother bath of a pH-value ranging from 4 to 8, which contains citric acid or its salt and an ammonium salt, a brightener comprising a water-soluble polymer selected from the group consisting of a polyoxyethylene, a derivative thereof and a reaction product of an epoxy compound with ethylene glycol, propylene glycol or glycerine.
Claim 3
Dependent Claim 16 words
An electroplating bath as claimed in claim 1, further comprising an aldehyde compound as a co-brightener.
Claim 4
Dependent Claim 37 words
An electroplating bath as claimed in claim 2, wherein the aldehyde compound is at least one selected from the group consisting of formaldehyde, acetaldehyde, propionaldehyde, glyoxal, succindialdehyde, caproaldehyde, aldol, benzaldehyde, p-tolualdehyde, salicylaldehyde, veratraldehyde, anisaldehyde, piperonal and vanillin.
Claim 5
Dependent Claim 28 words
An electroplating bath as claimed in claim 3, wherein the aldehyde compound as co-brightener is added to the mother bath in an amount of 0.1 to 0.5 g/l.
Claim 6
Dependent Claim 56 words
An electroplating bath as claimed in claim 1, wherein the polyoxyethylene or the derivative thereof is at least one compound selected from the group consisting of ##STR21## wherein n 1 , n 2 and n 3 are integrals showing polymerization degree ranging from 20 to 200, from 10 to 100 and from 5 to 50, respectively.
Claim 7
Dependent Claim 28 words
An electroplating bath as claimed in claim 5, wherein the polyoxyethylene or its derivative is added to the mother bath in an amount of 1 to 5 g/l.
Claim 8
Dependent Claim 30 words
An electroplating bath as claimed in claim 1, wherein the epoxy compound is at least one selected from the group consisting of ##STR22## wherein R is a lower alkyl radical.
Claim 9
Dependent Claim 37 words
An electroplating bath as claimed in claim 1, wherein the reaction product of the epoxy compound with ethylene glycol, propylene glycol or glycerine is added to the mother bath in an amount of 1 to 2 g/l.

References Cited (Backward Citations)

US3892637A Cited
US3616306A Cited
US3769182A Cited
US3905878A Cited
GB1469547A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-09-17 1983-03-19 1983-09-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-09-17 1987-03-19 1987-09-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-09-17 1991-03-19 1991-09-18 $7700.00 Window Closed / Lapsed

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