US4168113A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Glass lens with ion-exchanged antireflection coating and process for manufacture thereof
Assignee: Sola International Inc
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Filing: 1977-07-05
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Granted: 1979-09-18
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Expires: 1997-07-05
Abstract
Abstract There is disclosed a glass ophthalmic lens including an ion-exchanged antireflection coating. Metal oxide films including TiO2, CeO2, ZrO2, La2O3, Nd2O3, Al2O3, and SiO2 when evaporated on glass lenses in a vacuum chamber by electron-beam techniques form hard optical coatings which are chemically stabile at high temperatures and allow potassium and sodium ions to traverse the thickness thereof without changing chemical composition or physical integrity thereby enhancing ability of glass lenses to be ion-exchanged in a conventional ion-exchange treatment. This allows antireflection coated glass lenses to pass impact-resistant standards ANZI Z80.1 for prescription ophthalmic lenses and USAS Z87.1 for safety lenses.
Inventors
- 👤 Leei Chang
- 👤 Jon D. Masso
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 12:56
CPC Classifications
G; G02; G02C; G02C7/00; G02C7/02; C; C03; C03C; C03C17/00; C03C17/34; C03C17/3411; C03C17/3417; C03C21/00
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
124 words
A glass ophthalmic lens comprising, a glass lens substrate having an ion-exchanged antireflection coating over at least one surface thereof, said antireflection coating being comprised of metal oxide film of oxides selected from the group consisting of TiO 2 , CeO 2 , ZrO 2 , La 2 O 3 , Nd 2 O 3 , Al 2 O 3 in combination with another oxide of the group, and SiO 2 , said SiO 2 constituting at least the outermost layer of the film, said film, capable of allowing passage of potassium and sodium ions therethrough during ion-exchange treatment of the lens without change in chemical composition or physical integrity of said film, said lenses capable of passing ANZI Z80.1 and USAS Z87.1 tests.
Claim 2
Dependent Claim
124 words
A glass ophthalmic lens comprising, a glass lens substrate having an ion-exchanged antireflection coating over at least one surface thereof, said antireflection coating being comprised of metal oxide film of oxides selected from the group consisting of TiO 2 , CeO 2 , ZrO 2 , La 2 O 3 , Nd 2 O 3 , Al 2 O 3 in combination with another oxide of the group, and SiO 2 , said SiO 2 constituting at least the outermost layer of the film, said film, capable of allowing passage of potassium and sodium ions therethrough during ion-exchange treatment of the lens without change in chemical composition or physical integrity of said film, said lenses capable of passing ANZI Z80.1 and USAS Z87.1 tests.
Claim 3
Dependent Claim
18 words
The lens of claim 1 in which the coating is applied over both surfaces of the lens substrate.
Claim 4
Dependent Claim
48 words
The lens of claim 1 in which the glass substrate is crown glass of an index of about 1.5, and the coating consists of a combination of CeO 2 of an index of about 2.3 and as an outermost layer SiO 2 of an index of about 1.4.
Claim 5
Dependent Claim
48 words
A lens according to claim 1 in which the coating is a bilayer antireflecting coating answering to the formula G 1.0 H 1.0 L, Air in which: ______________________________________
G H L
______________________________________
(n=1.52) SiO.sub.x, 1<x<2
SiO.sub.2 (n=1.46)
(1.47<n<1.90)
MgO--Al.sub.2 O.sub.3 --SiO.sub.2
Schott #8329
Spinel (n=1.68)
Glass (n=1.47)
______________________________________
Claim 6
Dependent Claim
49 words
A lens according to claim 1 in which the coating is a bilayer antireflection coating answering to the formula G 2.0 H 1.0 L, Air in which: ______________________________________
G 2H L
______________________________________
(n=1.52) Nd.sub.2 O.sub.3 (n=1.86)
SiO.sub.2 (n=1.46)
ZrO.sub.2 (n=2.05)
Schott #8329
CeO.sub.2 (n=2.34)
Glass (n=1.47)
TiO.sub.2 (n=2.40)
______________________________________
Claim 7
Dependent Claim
45 words
A lens according to claim 1 in which the coating is a trilayer antireflection coating answering to the formula G 1.0 M 2.0 H 1.0 L, Air in which: ______________________________________
G M 2H L
______________________________________
(n=1.52) SiO.sub.x ZrO.sub.2 SiO.sub.2
Spinel CeO.sub.2 Schott Glass
TiO.sub.2
______________________________________
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-09-17 | 1983-03-19 | 1983-09-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-09-17 | 1987-03-19 | 1987-09-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-09-17 | 1991-03-19 | 1991-09-18 | $7700.00 | Window Closed / Lapsed |