US4167589A — Method for the manufacture of caffeine free black…

Claim 1

Independent Claim 150 words

A process for the production of caffeine free black tea which comprises the steps of: a. Extracting tea leaves with a dry extraction solvent gas having selective dissolving capacity for the aromatic component, and which is maintained in the supercritical state with respect to temperature and presure to extract the aromatic content of the tea and leave a tea residue, b. Separating the aromatic content from the extraction solvent, c. Extracting the tea residue with a moist extraction solvent gas having selective dissolving capacity for the caffeine, and which is supercritical with respect to temperature and pressure to remove the caffeine, d. Redissolving the aromatics separated in Step (b) utilizing an extraction solvent gas which is supercritical with respect to temperature and pressure and separating the aromatics from the gas in the presence of the substantially caffeine free tea residue, thereby to impregnate the residue with the original aromatic content.

Claim 2

Dependent Claim 150 words

A process for the production of caffeine free black tea which comprises the steps of: a. Extracting tea leaves with a dry extraction solvent gas having selective dissolving capacity for the aromatic component, and which is maintained in the supercritical state with respect to temperature and presure to extract the aromatic content of the tea and leave a tea residue, b. Separating the aromatic content from the extraction solvent, c. Extracting the tea residue with a moist extraction solvent gas having selective dissolving capacity for the caffeine, and which is supercritical with respect to temperature and pressure to remove the caffeine, d. Redissolving the aromatics separated in Step (b) utilizing an extraction solvent gas which is supercritical with respect to temperature and pressure and separating the aromatics from the gas in the presence of the substantially caffeine free tea residue, thereby to impregnate the residue with the original aromatic content.

Claim 3

Dependent Claim 46 words

A process according to claim 1 wherein the substantially caffeine free tea residue is extracted with water prior to impregnation with the aromatics; the aqueous extract is spray dried to produce a dry powder which is thereafter impregnated with the aromatics in accordance with step (d).

Claim 4

Dependent Claim 30 words

A process as in claim 1 wherein the temperature in Step (b) is above the critical temperature of the extraction gas and the separation is effected by reducing the pressure.

Claim 5

Dependent Claim 21 words

A process as in claim 1 wherein the temperature in Step (b) is below the critical temperature of the extraction gas.

Claim 6

Dependent Claim 21 words

A process as in claim 1 wherein the selected gas in each of steps (a), (c), and (d) is carbon dioxide.

Claim 7

Dependent Claim 49 words

A process as in claim 1 wherein the selected gas in each of steps (a), (c) and (d) is carbon dioxide and Step (a) is carried out at a temperature of from about 40° C. to 60° C. at a pressure of from about 200 to 400 atmospheres absolute.

Claim 8

Dependent Claim 49 words

A process as in claim 1 wherein the selected gas in each of steps (a), (c), and (d) is carbon dioxide and Step (c) is carried out at a temperature of from about 40° C. to 60° C. and a pressure of from about 200 to 250 atmospheres absolute.

Claim 9

Dependent Claim 37 words

A process as in claim 1 wherein the selected gas in each of steps (a), (c), and (d) is carbon dioxide and the aromatics are impregnated at a temperature of from about -10° C. to 20° C.

Claim 10

Dependent Claim 49 words

A process as in claim 1 wherein the solvent gases are selected from the group consisting of carbon dioxide; saturated and unsaturated hydrocarbons containing up to about three carbon atoms; nitrous oxide; saturated and unsaturated halogenated hydrocarbons containing up to about three carbon atoms; sulfur hexafluoride; and mixtures thereof.

Claim 11

Dependent Claim 116 words

A process for the production of caffeine free black tea, which comprises the steps of: (a) extracting tea leaves with dry extraction solvent gas having selective dissolving capacity for the aromatic content, and which is maintained in the supercritical state with respect to temperature and pressure to extract aromatic content of the tea and leave a dearomatized tea residue. (b) extracting the tea residue with a moist extraction solvent gas having selective dissolving capacity for the caffeine, and which is in the supercritical state with respect to temperature and pressure to remove caffeine and leave a dearomatized and decaffeinated tea residue, (c) impregnating a dearomatized and decaffeinated tea residue with aromatic component extracted in step (a).

Claim 12

Dependent Claim 116 words

A process for the production of caffeine free black tea, which comprises the steps of: (a) extracting tea leaves with dry extraction solvent gas having selective dissolving capacity for the aromatic content, and which is maintained in the supercritical state with respect to temperature and pressure to extract aromatic content of the tea and leave a dearomatized tea residue. (b) extracting the tea residue with a moist extraction solvent gas having selective dissolving capacity for the caffeine, and which is in the supercritical state with respect to temperature and pressure to remove caffeine and leave a dearomatized and decaffeinated tea residue, (c) impregnating a dearomatized and decaffeinated tea residue with aromatic component extracted in step (a).

Claim 13

Dependent Claim 18 words

A process as in claim 10, wherein the solvent gas used in step (b) is moist carbon dioxide.

Claim 14

Dependent Claim 18 words

A process as in claim 11, wherein the solvent gas used in step (a) is dry carbon dioxide.

Claim 15

Dependent Claim 31 words

A process as in claim 12, wherein the temperature in step (a) and step (b) are 40°-100° C. and the pressures in step (a) and step (b) are above 100 atms.

Claim 16

Dependent Claim 38 words

Process as in claim 10, wherein a tea extract is produced from the dearomatized and decaffeinated tea residue produced in step (b), and aromatic component produced in step (a) is added to a dearomatized and decaffeinated tea extract.

Claim 17

Dependent Claim 49 words

A process as in claim 10, wherein the solvent gases are selected from the group consisting of carbon dioxide; saturated and unsaturated hydrocarbons containing up to about 3 carbon atoms; nitrous oxide; saturated and unsaturated halogenated hydrocarbons containing up to about 3 carbon atoms; sulfur hexafluoride; and mixtures thereof.

Claim 18

Dependent Claim 87 words

A process as in claim 1, the separation in step (b) being effected by reducing the pressure, the gas in each of steps (a), (c), and (d) being carbon dioxide, the temperature in step (a) being about 40° to 60° C. and the pressure in step (a) being about 200 to 400 atms., the temperature in step (c) being about 40° to 60° C. and the pressure in step (c) being about 200 to 250 atms., and the aromatics are impregnated at about -10° to 20° C.

Claim 19

Dependent Claim 23 words

A process as in claim 1, wherein the separation in step (b) is effected by reducing the pressure to below the critical pressure.

Claim 20

Dependent Claim 94 words

A process for extracting aromatic constituents and caffeine from tea, which comprises extracting tea leaves with a dry extraction solvent gas having selective dissolving capability for the aromatic component, and which is maintained in the supercritical state with respect to temperature and pressure to extract the aromatic content of the tea and leave the dearomatized residue; recovering the aromatic content; and extracting the tea residue with a moist extraction solvent gas having selective dissolving capacity for the caffeine, and which is in the supercritical state with respect to temperature and pressure to remove caffeine.

Claim 21

Dependent Claim 94 words

A process for extracting aromatic constituents and caffeine from tea, which comprises extracting tea leaves with a dry extraction solvent gas having selective dissolving capability for the aromatic component, and which is maintained in the supercritical state with respect to temperature and pressure to extract the aromatic content of the tea and leave the dearomatized residue; recovering the aromatic content; and extracting the tea residue with a moist extraction solvent gas having selective dissolving capacity for the caffeine, and which is in the supercritical state with respect to temperature and pressure to remove caffeine.

Claim 22

Dependent Claim 26 words

Process according to claim 18, in which said dry extraction solvent gas is dry carbon dioxide and said moist extraction solvent gas is moist carbon dioxide.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1982-09-10	1983-03-12	1983-09-11	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1986-09-10	1987-03-12	1987-09-11	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	1990-09-10	1991-03-12	1991-09-11	$7700.00	Window Closed / Lapsed

Method for the manufacture of caffeine free black tea

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