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Process for the preparation of carbodiimide-isocyanurate foams

Assignee: BASF Corp
•
Filing: 1977-12-05
•
Granted: 1979-08-28
•
Expires: 1997-12-05
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Abstract

Abstract Rigid foams characterized by carbodiimide and isocyanurate linkages are prepared by catalytically condensing an organic polyisocyanate in the presence of (a) a carbodiimide-promoting compound and (b) certain C 1 -C 8 alkali metal carboxylates as trimerization catalysts.

Inventors

  • 👤 Moses Cenker
  • 👤 Thirumurti Narayan
  • 👤 Harald P. Wulff

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 04:07
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/09; C08G18/095; C08G18/02; C08G18/025; C08G2110/00; C08G2110/0025; C08G2110/0041; C08G2110/0083; Y; Y10; Y10S; Y10S521/00; Y10S521/901; Y10S521/902; Y10S521/903

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 46 words
A process for the preparation of foams characterized by carbodiimide and isocyanurate linkages comprising catalytically condensing an organic polyisocyanate in the presence of a catalytically sufficient amount of (a) a compound which promotes the carbodiimide reaction and (b) a C 1 -C 8 alkali metal carboxylate.
Claim 2
Dependent Claim 46 words
A process for the preparation of foams characterized by carbodiimide and isocyanurate linkages comprising catalytically condensing an organic polyisocyanate in the presence of a catalytically sufficient amount of (a) a compound which promotes the carbodiimide reaction and (b) a C 1 -C 8 alkali metal carboxylate.
Claim 3
Dependent Claim 10 words
The process of claim 1 wherein (b) is potassium acetate.
Claim 4
Dependent Claim 10 words
The process of claim 1 wherein (b) is potassium formate.
Claim 5
Dependent Claim 10 words
The process of claim 1 wherein (b) is potassium 2-ethylhexanoate.
Claim 6
Dependent Claim 27 words
The process of claim 1 wherein the organic polyisocyanate is selected from the group consisting of toluene diisocyanate, methylene diphenyl diisocyanate, polyphenyl polymethylene polyisocyanate and mixtures thereof.
Claim 7
Dependent Claim 14 words
The process of claim 1 wherein the carbodiimide-promoting catalyst is furfuryl alcohol or methanol.
Claim 8
Dependent Claim 11 words
The process of claim 1 wherein the carbodiimide-promoting catalyst is 2,4-bis(diethylamino)-6-N-methylethanolamino-s-triazine.
Claim 9
Dependent Claim 47 words
The process of claim 1 carried out in the presence of from 5% to 70% by weight based on the weight of the organic polyisocyanate of a polyol having an average functionality of 2 to 8 and an average hydroxyl equivalent of from about 100 to 1500.

References Cited (Backward Citations)

US3252942A Cited
US3931065A Cited
US3657161A Cited
US3622577A Cited
US3717596A Cited
GB1390231A Cited
US3806475A Cited
US3940517A Cited
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US4051082A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-08-27 1983-02-26 1983-08-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-08-27 1987-02-26 1987-08-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-08-27 1991-02-26 1991-08-28 $7700.00 Window Closed / Lapsed

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