US4164068A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of making bipolar carbon-plastic electrode structure-containing multicell electrochemical device
Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1977-12-19
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Granted: 1979-08-14
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Expires: 1997-12-19
Abstract
Abstract A novel multicell electrochemical device having a plurality of bipolar carbon-plastic electrode structures and a novel method of making the device are described. A plurality of bipolar carbon-plastic electrode structures are formed by first molding thin conductive carbon-plastic sheets from heated mixtures of specified carbon and plastic, and then establishing frames of dielectric plastic material around the sheets and sealing the frames to the sheets so as to render the resulting structures liquid impermeable. A plurality of electrochemical cell elements in addition to the electrode structures, e.g. separators, spacers and the like, are also formed with dielectric plastic frames. The frames of both the electrode structures and the additional elements have projections on at least one surface. The electrode structures and the additional elements are stacked to form a group of items in an electrochemically functional arrangement. The arrangement is such that the projection of each frame contacts a frame surface of the next item in the stack. The items in the stack are joined to one another, e.g. by heat welding or ultrasonic welding, at these areas of contact so as to form a multicell electrochemical device capable of holding liquid therein.
Inventors
- 👤 Joseph A. Shropshire
- 👤 Hsue C. Tsien
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 17:47
CPC Classifications
H; H01; H01M; H01M6/00; H01M6/42; H01M6/46; H01M6/48; H01M10/00; H01M10/04; H01M10/0413; H01M10/0418; Y; Y02; Y02E; Y02E60/00; Y02E60/10; Y02P; Y02P70/00; Y02P70/50; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49108; Y10T29/4911; Y10T29/49114
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
330 words
A method of making a multicell electrochemical device having a plurality of bipolar carbon-plastic electrode structures, comprising: (a) forming a plurality of bipolar carbon-plastic electrode structures, each of said structures being formed by: (i) molding a thin conductive carbon-plastic electrode sheet from a heated mixture of particulate conductive carbon and plastic material, said mixture having sufficient carbon therein so as to produce a sheet having an electrical conductivity of at least about 0.1 mho-cm, said carbon having an average particle size of about 10 millimicrons to about 100 microns; (ii) establishing a frame of dielectric plastic material around said thin conductive carbon-plastic electrode sheet so as to encompass a portion of both sides of said thin conductive carbon-plastic electrode sheet, said frame having inner borders defining an open central area into which said sheet is disposed, and said frame having a front surface and a back surface, at least one of said surfaces having a projection formed thereon; and, (iii) sealing said frame to said sheet at the inner borders of said sheet so as to render the resulting structure liquid impermeable; (b) forming a plurality of electrochemical cell elements, each of said elements having an electrochemical cell-functional center portion circumscribed by a dielectric plastic frame having a front surface and a back surface, at least one of said surfaces having a projection formed thereon; (c) stacking said plurality of electrode structures and plurality of electrochemical cell elements with one another to form a group of items in an electrochemical cell-functional arrangement and in such a manner that the projection on the frame of each item contacts a frame surface of the next item in the stack; and (d) joining each of the items in the stack to one another by sealing each item to the next item at the point where its projection contacts the frame surface of the next item, said sealing being sufficiently established so as to form a continuous electrochemical device capable of holding liquid therein.
Claim 2
Independent Claim
330 words
A method of making a multicell electrochemical device having a plurality of bipolar carbon-plastic electrode structures, comprising: (a) forming a plurality of bipolar carbon-plastic electrode structures, each of said structures being formed by: (i) molding a thin conductive carbon-plastic electrode sheet from a heated mixture of particulate conductive carbon and plastic material, said mixture having sufficient carbon therein so as to produce a sheet having an electrical conductivity of at least about 0.1 mho-cm, said carbon having an average particle size of about 10 millimicrons to about 100 microns; (ii) establishing a frame of dielectric plastic material around said thin conductive carbon-plastic electrode sheet so as to encompass a portion of both sides of said thin conductive carbon-plastic electrode sheet, said frame having inner borders defining an open central area into which said sheet is disposed, and said frame having a front surface and a back surface, at least one of said surfaces having a projection formed thereon; and, (iii) sealing said frame to said sheet at the inner borders of said sheet so as to render the resulting structure liquid impermeable; (b) forming a plurality of electrochemical cell elements, each of said elements having an electrochemical cell-functional center portion circumscribed by a dielectric plastic frame having a front surface and a back surface, at least one of said surfaces having a projection formed thereon; (c) stacking said plurality of electrode structures and plurality of electrochemical cell elements with one another to form a group of items in an electrochemical cell-functional arrangement and in such a manner that the projection on the frame of each item contacts a frame surface of the next item in the stack; and (d) joining each of the items in the stack to one another by sealing each item to the next item at the point where its projection contacts the frame surface of the next item, said sealing being sufficiently established so as to form a continuous electrochemical device capable of holding liquid therein.
Claim 3
Dependent Claim
25 words
The method of claim 1 wherein the frame of step (ii) is established around said sheet by being formed around said sheet by injection molding.
Claim 4
Dependent Claim
42 words
The method of claim 2 wherein said sheet is formed with small holes near its edges and wherein, upon the injection molding of frame around said sheet, the plastic of said frame fills the small holes so as to form continuous rivets.
Claim 5
Dependent Claim
47 words
The method of claim 1 wherein said plastic in the mixture used in step (a) to mold said sheet and the dielectric plastic of said frame are independently selected from plastic containing materials selected from the group consisting of phenol-formaldehyde resins, polyacrylic resins, polyvinyl resins and polyolefins.
Claim 6
Dependent Claim
26 words
The method of claim 4 wherein the frame of step (a) (ii) is established around said sheet by being formed around said sheet by injection molding.
Claim 7
Dependent Claim
42 words
The method of claim 5 wherein said sheet is formed with small holes near its edges and wherein, upon the injection molding of frame around said sheet, the plastic of said frame fills the small holes so as to form continuous rivets.
Claim 8
Dependent Claim
16 words
The method of claim 4 wherein said sheet is sealed to said frame by heat welding.
Claim 9
Dependent Claim
16 words
The method of claim 4 wherein said sheet is sealed to said frame by ultrasonic welding.
Claim 10
Dependent Claim
21 words
The method of claim 4 wherein the plastic of the sheet and the plastic of the frame are substantially the same.
Claim 11
Dependent Claim
12 words
The method of claim 9 wherein the plastic is a polyethylene-polypropylene copolymer.
Claim 12
Dependent Claim
16 words
The method of claim 1 wherein the sealing in step (d) is accomplished by heat welding.
Claim 13
Dependent Claim
40 words
The method of claim 11 wherein the projections on the surfaces of the frames in the stack next to one another have flattened ends with end surfaces adapted to totally contact the frame surface to which it is heat welded.
Claim 14
Dependent Claim
68 words
The method of claim 12 wherein both the front surface and the back surface of each of said frames contain projections having flattened ends, each having end surfaces which are adapted so as to contact the end surface of a projection on the frame of the next item in the stack, and wherein the items are sealed by being heat welded where these end surfaces contact one another.
Claim 15
Dependent Claim
30 words
The method of claim 1 wherein the sealing is accomplished by ultrasonically welding the projection of each frame to the surface of the frame with which it is in contact.
Claim 16
Dependent Claim
19 words
The method of claim 14 wherein the projections have pointed ends adapted so as to enhance said ultrasonic welding.
Claim 17
Dependent Claim
41 words
The method of claim 15 wherein each of the frames has said projection on one surface and has a groove on the opposite surface adapted so as to receive the pointed projection of the frame with which it is in contact.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-08-13 | 1983-02-12 | 1983-08-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-08-13 | 1987-02-12 | 1987-08-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-08-13 | 1991-02-12 | 1991-08-14 | $7700.00 | Window Closed / Lapsed |