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US4163741A Expired / Lapsed US ⏱️ 0.0 years remaining

Sand mold compositions containing as catalyst, methyl alcohol solutions of benzenesulphonic acid

Assignee: Individual
•
Filing: 1977-04-15
•
Granted: 1979-08-07
•
Expires: 1997-04-15
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Abstract

Abstract A sand for making cores and moulds which comprises 100 parts by weight of a refractory filler, between 1.0 and 3.0 parts by weight of a binder, and between 0.4 and 2.0 parts by weight of an acid catalyst of crystal hydrate benzene-sulphonic acid in the form of an 80- to 92-percent solution in methyl alcohol. The present invention makes it possible to prepare a sand for making cores and moulds which displays a cold setting rate and strength higher than ever before. The cold setting rate in terms of the time after mixing at which the pattern or corebox can be removed satisfactorily is not over 1 min. and the compression strength of the sand is at least 60 N/cm 2 at the time of removing the pattern or corebox.

Inventors

  • 👤 Sergie S. Zhukovsky
  • 👤 Nikolai I. Shadrin
  • 👤 Sergei D. Teplyakov
  • 👤 Abram M. Lyass, deceased
  • 👤 administrator by Inna E. Lyass

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 08:56
CPC Classifications
B; B22; B22C; B22C1/00; B22C1/16; B22C1/20; B22C1/22; B22C1/2233; B22C1/2246; B22C1/2253; C; C04; C04B; C04B26/00; C04B26/02; C04B26/10; C04B26/12; C04B26/122

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 75 words
A cold setting composition for making cores and molds consisting essentially of 100 parts by weight of a refractory filler, between 1.0 and 3.0 parts by weight of a resol phenol-formaldehyde resin binder and between 0.4 and 2.0 parts by weight of a crystal hydrate benzenesulphonic acid catalyst in the form of an 80- to 92-percent solution in methyl alcohol, whereby said cores and molds have compression strength of at least 60 N/cm 2 .
Claim 2
Dependent Claim 75 words
A cold setting composition for making cores and molds consisting essentially of 100 parts by weight of a refractory filler, between 1.0 and 3.0 parts by weight of a resol phenol-formaldehyde resin binder and between 0.4 and 2.0 parts by weight of a crystal hydrate benzenesulphonic acid catalyst in the form of an 80- to 92-percent solution in methyl alcohol, whereby said cores and molds have compression strength of at least 60 N/cm 2 .
Claim 3
Dependent Claim 39 words
The composition of claim 1, wherein the refractory filler is quartz sand having a silicon dioxide content of at least 98%, a clay content of not over 0.5%, and a particle size averaging 0.2 millimeters in the main fractions.
Claim 4
Dependent Claim 22 words
The composition of claim 1, wherein the binder is synthesized from phenol and formaldehyde in molar ratios of 1:1.2 to 1:2.0, respectively.
Claim 5
Independent Claim 61 words
A method for improving the cold setting rate and strength of cores and moles which comprises contacting 100 parts by weight of refractory filler with 1 to 3 parts by weight of resol phenol-formaldehyde resin binder and 0.4 to 2.0 parts by weight of crystal hydrate benzene sulfonic acid in the form of an 80 to 92% solution in methyl alcohol.
Claim 6
Independent Claim 61 words
A method for improving the cold setting rate and strength of cores and moles which comprises contacting 100 parts by weight of refractory filler with 1 to 3 parts by weight of resol phenol-formaldehyde resin binder and 0.4 to 2.0 parts by weight of crystal hydrate benzene sulfonic acid in the form of an 80 to 92% solution in methyl alcohol.
Claim 7
Dependent Claim 39 words
The method of claim 4, wherein the refractory filler is quartz sand having a silicon dioxide content of at least 98%, a clay content of not over 0.5% and a particle size averaging 0.2 millimeters in the main fractions.
Claim 8
Dependent Claim 21 words
The method of claim 4, wherein the binder is synthesized from phenol and formaldehyde in ratios of 1:1.2 to 1:2.0, respectively.
Claim 9
Dependent Claim 22 words
The composition of claim 1, also containing a silane in amounts varying from 0.1 to 0.5% by weight of the resin binder.
Claim 10
Dependent Claim 10 words
The composition of claim 7, wherein said silane is α-aminopropyl-triethoxysilane.
Claim 11
Dependent Claim 28 words
The method of claim 4, wherein the refractory filler is also contacted with a silane in amounts varying from 0.1 to 0.5% by weight of the resin binder.
Claim 12
Dependent Claim 10 words
The method of claim 9, wherein said silane is α-aminopropyl-triethoxysilane.

References Cited (Backward Citations)

US2233875A Cited
GB763812A Cited
US2813846A Cited
GB853766A Cited
US3536575A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-08-06 1983-02-05 1983-08-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-08-06 1987-02-05 1987-08-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-08-06 1991-02-05 1991-08-07 $7700.00 Window Closed / Lapsed

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