Method for combining coal liquefaction and gasification processes

Claim 2

A combination bituminous coal liquefaction-gasification process comprising passing mineral-containing bituminous feed coal, hydrogen, recycle dissolved liquid solvent, recycle normally solid dissolved coal and recycle mineral residue to a coal liquefaction zone to dissolve hydrocarbonaceous material from mineral residue and to hydrocrack said hydrocarbonaceous material to produce a mixture comprising hydrocarbon gases, dissolved liquid, normally solid dissolved coal and suspended mineral residue; separaring distillate liquid and hydrocarbon gases from a slurry comprising said normally solid dissolved coal, solvent and mineral residue; recycling to said liquefaction zone a portion of said slurry; passing the remainder of said slurry to distillation means including a vacuum distillation tower for distillation, the slurry bottoms from said vacuum distillation tower comprising a gasifier feed slurry; said gasifier feed slurry comprising substantially the entire 850° F.+ normally solid dissolved coal and mineral residue yield of said liquefaction zone substantially without normally liquid coal and hydrocarbon gases; passing said gasifier feed slurry to a gasification zone; said gasifier feed slurry comprising substantially the entire hydrocarbonaceous feed to said gasification zone; said gasification zone including an oxidation zone for the conversion of the hydrocarbonaceous material therein to synthesis gas; converting a portion of said synthesis gas in a shift reaction to a gaseous hydrogen-rich stream and passing said hydrogen-rich stream to said liquefaction zone to satisfy the process hydrogen requirement thereof; the amount of 850° F.+ normally solid dissolved coal in said gasifier feed slurry being in excess of the amount of normally solid dissolved coal necessary to satisfy the process hydrogen requirement of said liquefaction zone; the amount of 850° F.+ normally solid dissolved coal in said gasifier slurry in excess of the amount necessary to satisfy the process hydrogen requirement increases the thermal efficiency of said process by producing an excess amount of synthesis gas for burning as fuel in said process and is in the range as defined by the formula R=13+(8-0)-3(Fe-1.5) where Fe=iron content of feed coal in weight percent O=oxygen content of feed coal in weight percent R=range of the yields of 850° F.+ dissolved coal in excess of the yield of 850° F.+ dissolved coal necessary to satisfy the process hydrogen requirement, where the yields are expressed in weight percent of dry feed coal; the combustion heating value of said excess amount of synthesis gas being between 5 and 100 percent of the total energy requirement of said process; and burning said excess amount of synthesis gas as fuel within said process.

Claim 3

The process of claim 1 including the removal of mineral residue as slag from said gasifier zone.

Claim 4

The process of claim 1 wherein there is no step for the separation of mineral residue from normally solid dissolved coal.

Claim 5

The process of claim 1 wherein the maximum temperature in said gasification zone is between 2,200° and 3,600° F.

Claim 6

The process of claim 1 wherein the maximum temperature in said gasification zone is between 2,500° and 3,600° F.

Claim 7

The process of claim 1 wherein the total coke yield in said liquefaction zone is less than 1 weight percent, based on feed coal.

Claim 8

The process of claim 1 wherein some synthesis gas is converted to another fuel.

Claim 9

A combination coal liquefaction-gasification process comprising passing mineral-containing sub-bituminous or mineral-containing lignite feed coal, recycle dissolved liquid solvent, recycle normally solid dissolved coal and recycle mineral residue to a coal liquefaction zone to dissolve hydrocarbonaceous material from mineral residue and to hydrocrack said hydrocarbonaceous material to produce a mixture comprising hydrocarbon gases, dissolved liquid, and normally solid dissolved coal and suspended mineral residue; separating distillate liquid and hydrocarbon gases from a slurry comprising said normally solid dissolved coal, solvent and mineral residue; recycling to said liquefaction zone a portion of said slurry; passing the remainder of said slurry to distillation means including a vacuum distillation tower for distillation, the slurry bottoms from said vacuum distillation tower comprising a gasifier feed slurry; said gasifier feed slurry comprising substantially the entire 850° F.+ normally solid dissolved coal and mineral residue yield of said liquefaction zone substantially without normally liquid coal and hydrocarbon gases; passing said gasifier feed slurry to a gasification zone; said gasifier feed slurry comprising substantially the entire hydrocarbonaceous feed to said gasification zone; said gasification zone including an oxidation zone for the conversion of the hydrocarbonaceous material therein to synthesis gas; converting a portion of said synthesis gas in a shift reaction to a gaseous hydrogen-rich stream and passing said hydrogen-rich stream to said liquefaction zone to satisfy the process hydrogen requirement thereof; the amount of 850° F.+ normally solid dissolved coal in said gasifier feed slurry being in excess of the amount of normally solid dissolved coal necessary to satisfy the process hydrogen requirement of said liquefaction zone; the amount of 850° F.+ normally solid dissolved coal in said gasifier slurry in excess of the amount necessary to satisfy the process hydrogen requirement increasing the thermal efficiency of said process by producing an excess amount of synthesis gas for burning as fuel in said process and is in the range defined by the formula: R=13+(18-0)-3(Fe-0.5) where Fe=iron content of feed coal in weight percent O=oxygen content of feed coal in weight percent R=range of the yields of 850° F.+ dissolved coal in excess of the yield of 850° F.+ dissolved coal necessary to satisfy the process hydrogen requirement, where the yields are expressed in weight percent of dry feed coal; the combustion heating value of said excess amount of synthesis gas being between 5 and 100 percent of the total energy requirements of said process; and burning said excess amount of synthesis gas as fuel within said process.

Claim 10

A combination coal liquefaction-gasification process comprising passing mineral-containing sub-bituminous or mineral-containing lignite feed coal, recycle dissolved liquid solvent, recycle normally solid dissolved coal and recycle mineral residue to a coal liquefaction zone to dissolve hydrocarbonaceous material from mineral residue and to hydrocrack said hydrocarbonaceous material to produce a mixture comprising hydrocarbon gases, dissolved liquid, and normally solid dissolved coal and suspended mineral residue; separating distillate liquid and hydrocarbon gases from a slurry comprising said normally solid dissolved coal, solvent and mineral residue; recycling to said liquefaction zone a portion of said slurry; passing the remainder of said slurry to distillation means including a vacuum distillation tower for distillation, the slurry bottoms from said vacuum distillation tower comprising a gasifier feed slurry; said gasifier feed slurry comprising substantially the entire 850° F.+ normally solid dissolved coal and mineral residue yield of said liquefaction zone substantially without normally liquid coal and hydrocarbon gases; passing said gasifier feed slurry to a gasification zone; said gasifier feed slurry comprising substantially the entire hydrocarbonaceous feed to said gasification zone; said gasification zone including an oxidation zone for the conversion of the hydrocarbonaceous material therein to synthesis gas; converting a portion of said synthesis gas in a shift reaction to a gaseous hydrogen-rich stream and passing said hydrogen-rich stream to said liquefaction zone to satisfy the process hydrogen requirement thereof; the amount of 850° F.+ normally solid dissolved coal in said gasifier feed slurry being in excess of the amount of normally solid dissolved coal necessary to satisfy the process hydrogen requirement of said liquefaction zone; the amount of 850° F.+ normally solid dissolved coal in said gasifier slurry in excess of the amount necessary to satisfy the process hydrogen requirement increasing the thermal efficiency of said process by producing an excess amount of synthesis gas for burning as fuel in said process and is in the range defined by the formula: R=13+(18-0)-3(Fe-0.5) where Fe=iron content of feed coal in weight percent O=oxygen content of feed coal in weight percent R=range of the yields of 850° F.+ dissolved coal in excess of the yield of 850° F.+ dissolved coal necessary to satisfy the process hydrogen requirement, where the yields are expressed in weight percent of dry feed coal; the combustion heating value of said excess amount of synthesis gas being between 5 and 100 percent of the total energy requirements of said process; and burning said excess amount of synthesis gas as fuel within said process.

Claim 11

The process of claim 8 including the removal of mineral residue as slag from said gasifier zone.

Claim 12

The process of claim 8 wherein there is no step for the separation of mineral residue from normally solid dissolved coal.

Claim 13

The process of claim 8 wherein the maximum temperature in said gasification zone is between 2,200° and 3,600° F.

Claim 14

The process of claim 8 wherein the maximum temperature in said gasification zone is between 2,500° and 3,600° F.

Claim 15

The process of claim 8 wherein the total coke yield in said liquefaction zone is less than 1 weight percent, based on feed coal.

Claim 16

The process of claim 8 wherein some synthesis gas is converted to another fuel.