US4158028A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polyphenylene ether-styrene graft copolymer composition and preparation thereof
Assignee: Asahi Kasei Corp
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Filing: 1978-08-18
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Granted: 1979-06-12
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Expires: 1998-08-18
Abstract
Abstract A thermoplastic resin composition containing (I) a graft copolymer of a polyphenylene ether with a styrene type compound, containing substantially no homopolymer of polyphenylene ether, and (II) a graft copolymer of an ethylene copolymer of ethylene and not more than 40 mol percent of at least one unsaturated compound of the formula CH 2 =CH--OCOR 1 or CH 2 =CR 2 --COOR 3 (wherein R 1 denotes an alkyl group having one to four carbon atoms and R 2 and R 3 each denote a hydrogen atom or an alkyl group having one to four carbon atoms) with a styrene type compound has improved properties such as Izod impact strength, oil resistance and weathering resistance.
Inventors
- 👤 Shinichi Izawa
- 👤 Jurou Ohzeki
- 👤 Tsuyoshi Yahata
- 👤 Atsuo Nakanishi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 22:29
CPC Classifications
C; C08; C08F; C08F283/00; C08F283/06; C08F283/08; C08L; C08L51/00; C08L51/003; C08L51/08
Claims Analysis
Total Claims: 34
Claim 1
Independent Claim
161 words
A method for the manufacture of a graft copolymer composition which comprises polymerizing under continued agitation a styrene in the presence of 20 to 85 percent by weight based on the final composition of a polyphenylene ether represented by the general formula: ##STR2## wherein R and R 1 each denote a hydrogen atom or an alkyl group having one to four carbon atoms and n the degree of polymerization, 3 to 40 percent by weight of an ethylene copolymer comprising ethylene and 1.0 to 40 mol percent of at least one unsaturated compound represented by the general formula of CH 2 ═CHOCOR 1 or CH 2 ═CR 2 COOR 3 wherein, R 1 denotes an alkyl group having one to four carbon atoms and R 2 and R 3 each denote a hydrogen atom or an alkyl group having one to four carbon atoms and a radical polymerization initiator, at a temperature in the range of from 120° to 290° C.
Claim 2
Independent Claim
161 words
A method for the manufacture of a graft copolymer composition which comprises polymerizing under continued agitation a styrene in the presence of 20 to 85 percent by weight based on the final composition of a polyphenylene ether represented by the general formula: ##STR2## wherein R and R 1 each denote a hydrogen atom or an alkyl group having one to four carbon atoms and n the degree of polymerization, 3 to 40 percent by weight of an ethylene copolymer comprising ethylene and 1.0 to 40 mol percent of at least one unsaturated compound represented by the general formula of CH 2 ═CHOCOR 1 or CH 2 ═CR 2 COOR 3 wherein, R 1 denotes an alkyl group having one to four carbon atoms and R 2 and R 3 each denote a hydrogen atom or an alkyl group having one to four carbon atoms and a radical polymerization initiator, at a temperature in the range of from 120° to 290° C.
Claim 3
Dependent Claim
25 words
A method as in claim 1 wherein the polyphenylene ether is poly(2,6-dimethylphenylene-1,4-ether) and the temperature for polymerizing the styrene is from 180° to 250° C.
Claim 4
Dependent Claim
19 words
A method as in claim 2 wherein the styrene is styrene alone or a mixture of styrene with acrylonitrile.
Claim 5
Dependent Claim
19 words
A method as in claim 3 wherein the ethylene copolymer is an ethylene-methyl methacrylate copolymer or ethylene-vinyl acetate copolymer.
Claim 6
Dependent Claim
48 words
A method as in claim 4 wherein 4 to 200 parts by weight of the ethylene copolymer, 10 to 200 parts by weight of the styrene and 0.3 to 15 parts by weight of a radical initiator are used per 100 parts by weight of the polyphenylene ether.
Claim 7
Dependent Claim
20 words
A method as in claim 5 wherein the styrene is in the range from 15 to 180 parts by weight.
Claim 8
Dependent Claim
21 words
A method as in claim 6 wherein the radical initiator is in the range from 0.5 to 12 parts by weight.
Claim 9
Dependent Claim
19 words
A method as in claim 1 wherein the styrene is styrene alone or a mixture of styrene with acrylonitrile.
Claim 10
Dependent Claim
19 words
A method as in claim 1 wherein the ethylene copolymer is an ethylene-methyl methacrylate copolymer or ethylene-vinyl acetate copolymer.
Claim 11
Dependent Claim
48 words
A method as in claim 1 wherein 4 to 200 parts by weight of the ethylene copolymer, 10 to 200 parts by weight of the styrene and 0.3 to 15 parts by weight of a radical initiator are used per 100 parts by weight of the polyphenylene ether.
Claim 12
Dependent Claim
20 words
A method as in claim 10 wherein the styrene is in the range from 15 to 180 parts by weight.
Claim 13
Dependent Claim
21 words
A method as in claim 10 wherein the radical initiator is in the range from 0.5 to 12 parts by weight.
Claim 14
Dependent Claim
25 words
A method as in claim 1 wherein polymerization is carried out in the presence of 1 to 10 percent by weight of a rubbery substance.
Claim 15
Dependent Claim
21 words
A method as in claim 13 wherein a styrene type compound polymer and/or a high impact styrene copolymer is further added.
Claim 16
Dependent Claim
21 words
A method as in claim 1 wherein a styrene type compound polymer and/or a high impact styrene copolymer is further added.
Claim 17
Dependent Claim
25 words
A method as in claim 13 wherein the polyphenylene ether is poly(2,6-dimethylphenylene-1,4-ether) and the temperature for polymerizing the styrene is from 150° to 230° C.
Claim 18
Dependent Claim
19 words
A method as in claim 16 wherein the styrene is styrene alone or a mixture of styrene with acrylonitrile.
Claim 19
Dependent Claim
20 words
A method as in claim 17 wherein the ethylene copolymer is an ethylene-methyl methacrylate copolymer or an ethylene-vinyl acetate copolymer.
Claim 20
Dependent Claim
29 words
A method as in claim 18 wherein the rubbery substance is selected from the group consisting of polybutadiene, styrene-butadiene random copolymer, styrenebutadiene block copolymer and ethylene-propylene-non-conjugated diene copolymer rubber.
Claim 21
Dependent Claim
34 words
A method as in claim 14 wherein the styrene polymer and/or the high impact styrene copolymer is at least one selected from the group consisting of polystyrene, rubber reinforced polystyrene, styrene-acrylonitrile copolymer, styrene-acrylonitrile-butadiene copolymer.
Claim 22
Dependent Claim
74 words
A method as in claim 20 wherein 5 to 120 parts by weight of the ethylene copolymer, 2 to 30 parts by weight of the rubbery substance, 10 to 50 parts by weight of the -styrene polymer and/or high impact styrene copolymer, 0.3 to 15 parts by weight of the radical polymerization initiator and 10 to 200 parts by weight of the styrene are used per 100 parts by weight of the polyphenylene ether.
Claim 23
Dependent Claim
20 words
A method as in claim 21 wherein the styrene is in the range from 15 to 180 parts by weight.
Claim 24
Dependent Claim
21 words
A method as in claim 22 wherein the radical initiator is in the range from 0.5 to 12 parts by weight.
Claim 25
Dependent Claim
19 words
A method as in claim 13 wherein the styrene is styrene alone or a mixture of styrene with acrylonitrile.
Claim 26
Dependent Claim
20 words
A method as in claim 13 wherein the ethylene copolymer is an ethylene-methyl methacrylate copolymer or an ethylene-vinyl acetate copolymer.
Claim 27
Dependent Claim
29 words
A method as in claim 13 wherein the rubbery substance is selected from the group consisting of polybutadiene, styrene-butadiene random copolymer, styrenebutadiene block copolymer and ethylene-propylene-non-conjugated diene copolymer rubber.
Claim 28
Dependent Claim
34 words
A method as in claim 15 wherein the styrene polymer and/or the high impact styrene copolymer is at least one selected from the group consisting of polystyrene, rubber reinforced polystyrene, styrene-acrylonitrile copolymer, styrene-acrylonitrile-butadiene copolymer.
Claim 29
Dependent Claim
75 words
A method as in claim 13 wherein 4 to 120 parts by weight of the ethylene copolymer, 2 to 30 parts by weight of the rubbery substance, 10 to 50 parts by weight of the styrene polymer and/or the high impact styrene copolymer, 0.3 to 15 parts by weight of the radical polymerization initiator and 10 to 200 parts by weight of the styrene are used per 100 parts by weight of the polyphenylene ether.
Claim 30
Dependent Claim
20 words
A method as in claim 28 wherein the styrene is in the range from 15 to 180 parts by weight.
Claim 31
Dependent Claim
21 words
A method as in claim 28 wherein the radical initiator is in the range from 0.5 to 12 parts by weight.
Claim 32
Dependent Claim
31 words
A method as in claim 13, wherein polymerization is carried out by extrusion of a mixture of the polyphenylene ether, the radical initiator, the styrene, ethylene copolymer and the rubbery substance.
Claim 33
Dependent Claim
40 words
A method as in claim 14, wherein polymerization is carried out by extrusion of a mixture of the polyphenylene ether, the radical initiator, the styrene, ethylene copolymer, the rubbery substance, and the styrene polymer and/or the high impact styrene copolymer.
Claim 34
Dependent Claim
29 words
A method as in claim 1, wherein polymerization is carried out by extrusion of a mixture of the polyphenylene ether, the radical initiator, the styrene and the ethylene copolymer.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-06-11 | 1982-12-11 | 1983-06-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-06-11 | 1986-12-11 | 1987-06-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-06-11 | 1990-12-11 | 1991-06-12 | $7700.00 | Window Closed / Lapsed |