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US4157993A Expired / Lapsed US ⏱️ 0.0 years remaining

Resin-coated sand compositions

Assignee: Sumitomo Durez Co Ltd
•
Filing: 1977-12-22
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Granted: 1979-06-12
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Expires: 1997-12-22
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Abstract

Abstract This invention relates to resin-coated sand compositions useful in the preparation of foundry sand cores and molds comprising sand, a solid novalac resin, a lubricant-containing solid resole resin, and optionally, hexamethylenetetramine in an amount of up to about 5 parts by weight based on 100 parts by weight of the total amount of resin.

Inventors

  • 👤 Kyohei Funabiki
  • 👤 Noriaki Matsushima
  • 👤 Naomitsu Inoue

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 22:55
CPC Classifications
B; B22; B22C; B22C1/00; B22C1/16; B22C1/20; B22C1/22; B22C1/2233; B22C1/2246; B22C1/2253; C; C08; C08L; C08L61/00; C08L61/04; C08L61/06

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 201 words
In the process for preparation of a composition useful as a foundry core or mold consisting essentially of sand and a phenolic resin wherein a mixture of the phenolic resin consisting of solid particles and sand at an elevated temperature sufficient to fluidize said solid resin are mulled to coat the sand with said resin, the improvement wherein the solid phenolic resin comprises a solid novolac phenolic resin and a lubricant-containing solid resole phenolic resin produced by the reaction comprising condensation of a phenol and a formaldehyde source followed by dehydration of the reaction mixture wherein the lubricant is added prior to or during said reaction to produce the solid resole phenolic resin, the novolac resin constituting about 1 to about 40 parts by weight per 100 parts by weight of the phenolic resin, and the lubricant-containing resole phenolic resin constituting the balance of the phenolic resin component, the proportion of the total phenolic resin being about 2 to about 5 parts by weight per 100 parts by weight of the sand and the proportion of lubricant in the resole resin component being about 0.5 to about 10 parts by weight per 100 parts by weight of the resole resin component.
Claim 2
Dependent Claim 201 words
In the process for preparation of a composition useful as a foundry core or mold consisting essentially of sand and a phenolic resin wherein a mixture of the phenolic resin consisting of solid particles and sand at an elevated temperature sufficient to fluidize said solid resin are mulled to coat the sand with said resin, the improvement wherein the solid phenolic resin comprises a solid novolac phenolic resin and a lubricant-containing solid resole phenolic resin produced by the reaction comprising condensation of a phenol and a formaldehyde source followed by dehydration of the reaction mixture wherein the lubricant is added prior to or during said reaction to produce the solid resole phenolic resin, the novolac resin constituting about 1 to about 40 parts by weight per 100 parts by weight of the phenolic resin, and the lubricant-containing resole phenolic resin constituting the balance of the phenolic resin component, the proportion of the total phenolic resin being about 2 to about 5 parts by weight per 100 parts by weight of the sand and the proportion of lubricant in the resole resin component being about 0.5 to about 10 parts by weight per 100 parts by weight of the resole resin component.
Claim 3
Dependent Claim 57 words
The process of claim 1 wherein the lubricant is selected from the group consisting of carnauba wax, montan wax, paraffin wax, polyethylene wax, aliphatic amides, rosin, a complex thermoplastic mixture derived from southern pinewood comprising phenolic constituents in the form of substituted phenolic ethers, polyphenols and phenols of high molecular weight, polyethyleneglycol, polystyrene, talc, and mixtures thereof.
Claim 4
Dependent Claim 16 words
The process of claim 2 wherein the lubricant is an aliphatic amide or a polyethylene wax.
Claim 5
Dependent Claim 17 words
The process of claim 1 wherein the novolac resin comprises a condensation product of phenol and formaldehyde.
Claim 6
Dependent Claim 17 words
The process of claim 1 wherein the resole resin comprises a condensation product of phenol and formaldehyde.
Claim 7
Dependent Claim 15 words
The process of claim 1 wherein the temperature of the sand is 120° C.-140° C.
Claim 8
Dependent Claim 34 words
The process of claim 6 wherein the novolac resin is present in an amount of about 1 to about 30 parts by weight based on 100 parts by weight of the total resin content.
Claim 9
Dependent Claim 17 words
A product useful as a foundry sand core or mold prepared by the process of claim 7.
Claim 10
Dependent Claim 31 words
The process of claim 7 wherein the lubricant is present in an amount of about 1 to about 7 parts by weight based on 100 parts by weight of resole resin.
Claim 11
Dependent Claim 16 words
The process of claim 1 wherein the lubricant-containing resole resin also includes a silane coupling agent.
Claim 12
Dependent Claim 36 words
The process of claim 1 wherein the mixture of sand and resin also includes hexamine in an amount of up to about 5 parts by weight based on 100 parts by weight of the total resin.
Claim 13
Dependent Claim 17 words
A product useful as a foundry sand core or mold prepared by the process of claim 11.
Claim 14
Dependent Claim 17 words
A product useful as a foundry sand core or mold prepared by the process of claim 1.
Claim 15
Dependent Claim 26 words
The process of claim 1 wherein the lubricant is added after completion of the condensation step of the reaction to produce the solid resole phenolic resin.
Claim 16
Dependent Claim 16 words
A product useful as a sand core or mold prepared by the process of claim 14.

References Cited (Backward Citations)

US2888418A Cited
US2813840A Cited
US3850874A Cited
US3857811A Cited
US3944514A Cited
US3993620A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-06-11 1982-12-11 1983-06-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-06-11 1986-12-11 1987-06-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-06-11 1990-12-11 1991-06-12 $7700.00 Window Closed / Lapsed

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