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US4157243A Expired / Lapsed US ⏱️ 0.0 years remaining

Additive useful in oleaginous compositions

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1978-06-19
•
Granted: 1979-06-05
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Expires: 1998-06-19
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Abstract

Abstract Oxazoline reaction products of hydrocarbon substituted dicarboxylic acid, ester, or anhydride, for example octadecenylsuccinic anhydride, with 2,2-disubstituted-2-amino-1-alkanols, such as tris-hydroxymethylaminomethane (THAM), and their derivatives are useful additives in oleaginous compositions, such as sludge dispersants for lubricating oil, or anti-rust agents for gasoline.

Inventors

  • 👤 Jack Ryer
  • 👤 Harold N. Miller
  • 👤 James Zielinski
  • 👤 Stanley J. Brois

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:05
CPC Classifications
C; C10; C10M; C10M133/00; C10M133/52; C10M133/58; C07; C07D; C07D263/00; C07D263/02; C07D263/08; C07D263/10; C07D263/12; C07D263/14; C07F; C07F5/00; C07F5/02; C07F5/04; C08; C08F; C08F8/00; C08F8/30; C08G; C08G63/00; C08G63/68; C08G63/685; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/22; C10L1/221; C10L1/232; C10L1/233; C10L1/234; C10L1/238; C10L1/26; C10L1/2691; C10L1/30; C10L1/301; C10L1/303; C10M1/00; C10M1/08; C10M133/02; C10M133/38; C10M133/48

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 186 words
A petroleum fuel composition comprising: a major amount of petroleum fuel and in the range of 0.001 to 0.5 wt. % of bis-oxazoline of a molar proportion of a hydrocarbon-substituted C 4 -C 10 mono unsaturated dicarboxylic acid material selected from the group consisting of dicarboxylic acid, ester and anhydrides thereof, having in the range of from about 8 to 49 carbon atoms in said hydrocarbon substituent; reacted with about two molar proportions of a 2,2-disubstituted-2-amino-1-alkanol having 2 to 3 hydroxy groups and containing a total of 4 to 8 carbons of the formula: ##STR4## wherein X is alkyl or hydroxy alkyl, said alkyl groups having 1 to 3 carbon atoms, and at least one of said X is a hydroxy alkyl group of the structure --(CH 2 ) n OH where n is 1 to 3; at a temperature in the range of about 140 to 240° C. for about 1/2 to 24 hours with the removal of about three molar proportions of water to thereby produce said bis-oxazoline having the structure ##STR5## wherein R is said hydrocarbon substituent and X is as defined above.
Claim 2
Dependent Claim 186 words
A petroleum fuel composition comprising: a major amount of petroleum fuel and in the range of 0.001 to 0.5 wt. % of bis-oxazoline of a molar proportion of a hydrocarbon-substituted C 4 -C 10 mono unsaturated dicarboxylic acid material selected from the group consisting of dicarboxylic acid, ester and anhydrides thereof, having in the range of from about 8 to 49 carbon atoms in said hydrocarbon substituent; reacted with about two molar proportions of a 2,2-disubstituted-2-amino-1-alkanol having 2 to 3 hydroxy groups and containing a total of 4 to 8 carbons of the formula: ##STR4## wherein X is alkyl or hydroxy alkyl, said alkyl groups having 1 to 3 carbon atoms, and at least one of said X is a hydroxy alkyl group of the structure --(CH 2 ) n OH where n is 1 to 3; at a temperature in the range of about 140 to 240° C. for about 1/2 to 24 hours with the removal of about three molar proportions of water to thereby produce said bis-oxazoline having the structure ##STR5## wherein R is said hydrocarbon substituent and X is as defined above.
Claim 3
Dependent Claim 22 words
A composition according to claim 1, wherein said hydrocarbon substituted dicarboxylic acid material is alkenyl succinic anhydride and said fuel is gasoline.
Claim 4
Dependent Claim 15 words
A composition according to claim 2, wherein said alkenyl group contains about 18 carbon atoms.
Claim 5
Dependent Claim 11 words
A composition according to claim 3, wherein said amino-1-alkanol is 2-amino-2-methyl-1-propanol.
Claim 6
Dependent Claim 11 words
A composition according to claim 3, wherein said amino-1-alkanol is tris-hydroxy-methylaminomethane.

References Cited (Backward Citations)

US2569428A Cited
US2831858A Cited
US2905644A Cited
US3219666A Cited
US3235557A Cited
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US3248397A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-06-04 1982-12-04 1983-06-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-06-04 1986-12-04 1987-06-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-06-04 1990-12-04 1991-06-05 $7700.00 Window Closed / Lapsed

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