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US4156663A Expired / Lapsed US ⏱️ 0.0 years remaining

Flame resistant polymer composition containing phosphorus and bromine containing polymer

Assignee: Kanebo Ltd
•
Filing: 1977-11-28
•
Granted: 1979-05-29
•
Expires: 1997-11-28
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Abstract

Abstract Phosphorus- and bromine-containing polymers having the formula ##STR1## WHEREIN R 1 is an alkylene group having 2-3 carbon atoms; ##STR2## WHEREIN M IS AN INTEGER OF 1-4 AND B is an alkylene or alkylidene group having 1-6 carbon atoms or sulfone group; Z is --R 2 or --OR 2 , provided that R 2 is an alkyl or aryl group; Y is sulfur or oxygen; l is 0 or 1; p and q are integers of at least 1 and a sum of p and q is an integer of not more than 4; and n is an integer of 3-40 are colorless and have an excellent thermal property. The polymers are excellent as a flame retardant for inflammable organic high polymers, and flame resistant compositions having excellent washing resistance, light resistance and whiteness can be obtained by compounding the phosphorus- and bromine-containing polymer with the inflammable organic high polymer.

Inventors

  • 👤 Kazuo Okamoto
  • 👤 Hiroshi Uchio

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 13:09
CPC Classifications
C; C08; C08G; C08G79/00; C08G79/02; C08G79/04; C08L; C08L101/00; Y; Y10; Y10S; Y10S260/00; Y10S260/24

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 227 words
A flame resistant composition comprising an inflammable organic polymer selected from the group consisting of polyesters, polyurethanes, polyamides, acrylic polymers, polyolefins and cellulose, said polymer having blended therein from 3 to 30 percent by weight, based on the weight of said inflammable polymer, of a second polymer having the formula ##STR30## wherein R 1 , A, Z, Y, l, p and q have the same meanings as defined hereinafter and n is 3 to 40, obtained by reacting, in the liquid phase, at least one bromine-containing compound having the formula (I) h(or.sub.1).sub.p OAO(R.sub.1 O).sub.q H (I) wherein R 1 is alkylene having 2 or 3 carbon atoms, p and q are integers of at least 1 and the sum of p and q is an integer of not more than 4 and A is ##STR31## wherein m is an integer of one to 4 and B is alkylene or alkylidene having one to 6 carbon atoms or sulfone, with at least one phosphorus halide compound having the formula (II) ##STR32## wherein Z is --R 2 or --OR 2 , R 2 is alkyl or aryl, X is chlorine or bromine, Y is sulfur or oxygen and l is zero or 1, wherein the molar ratio of the formula (I) compound:formula (II) compound is 1.0:0.9 to 1.5 and wherein the reaction temperature is from zero to 180° C.
Claim 2
Dependent Claim 227 words
A flame resistant composition comprising an inflammable organic polymer selected from the group consisting of polyesters, polyurethanes, polyamides, acrylic polymers, polyolefins and cellulose, said polymer having blended therein from 3 to 30 percent by weight, based on the weight of said inflammable polymer, of a second polymer having the formula ##STR30## wherein R 1 , A, Z, Y, l, p and q have the same meanings as defined hereinafter and n is 3 to 40, obtained by reacting, in the liquid phase, at least one bromine-containing compound having the formula (I) h(or.sub.1).sub.p OAO(R.sub.1 O).sub.q H (I) wherein R 1 is alkylene having 2 or 3 carbon atoms, p and q are integers of at least 1 and the sum of p and q is an integer of not more than 4 and A is ##STR31## wherein m is an integer of one to 4 and B is alkylene or alkylidene having one to 6 carbon atoms or sulfone, with at least one phosphorus halide compound having the formula (II) ##STR32## wherein Z is --R 2 or --OR 2 , R 2 is alkyl or aryl, X is chlorine or bromine, Y is sulfur or oxygen and l is zero or 1, wherein the molar ratio of the formula (I) compound:formula (II) compound is 1.0:0.9 to 1.5 and wherein the reaction temperature is from zero to 180° C.
Claim 3
Dependent Claim 27 words
A flame resistant composition as claimed in claim 1 in which said inflammable polymer is selected from the group consisting of polyesters, acrylic polymers polyurethanes and cellulose.
Claim 4
Dependent Claim 33 words
A flame resistant composition as claimed in claim 1 in which the amount of said second polymer is from 5 to 15 percent by weight, based on the weight of said inflammable polymer.
Claim 5
Dependent Claim 11 words
A fiber made of the flame resistant composition of claim 1.
Claim 6
Dependent Claim 18 words
A flame resistant composition as claimed in claim 1, wherein the Br atoms are bonded in ortho position.
Claim 7
Dependent Claim 16 words
A flame resistant composition as claimed in claim 5, wherein the formula (I) compound is ##STR33##
Claim 8
Dependent Claim 16 words
A flame resistant composition as claimed in claim 5, wherein the formula (I) compound is ##STR34##
Claim 9
Dependent Claim 20 words
A flame resistant composition as claimed in claim 6, wherein the formula (II) compound is phenyldichlorophosphine oxide or phenyldibromophosphine oxide.
Claim 10
Dependent Claim 20 words
A flame resistant composition as claimed in claim 6, wherein the formula (II) compound is phenoxydichlorophosphine oxide or phenoxydibromophosphine oxide.

References Cited (Backward Citations)

US2435252A Cited
US2572076A Cited
US3326852A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-05-28 1982-11-27 1983-05-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-05-28 1986-11-27 1987-05-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-05-28 1990-11-27 1991-05-29 $7700.00 Window Closed / Lapsed

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