Liquid developer for electro photography

Claim 2

In a liquid developer for electrophotography containing a coloring agent, a coating agent, a resistivity controllling agent and a carrier liquid for dispersing or dissolving said coloring agent, coating agent and resistivity controlling agent, the improvement wherein the coating agent comprises: a copolymer obtained by polymerizing (a) acrylic acid components selected from the group consisting of compounds represented by the general formula: ##STR11## and mixtures of (iii) with compounds represented by the general formula ##STR12## with (b) a para-alkylstyrene represented by the general formula ##STR13## and with (c) an acrylic acid compound represented by the general formula ##STR14## wherein R 1 is a hydrogen or methyl, R 2 is hydrogen, R 3 is an alkyl group of 12-18 carbon atoms, R 4 is hydrogen or methyl, R 5 is C m H 2m O--ClH 2l+1 wherein m is 1-3 and l is 1-4, R 6 is hydrogen or methyl and R 7 is an alkyl group of 1-18 carbon atoms.

Claim 3

In a process of producing images by electrostatic photography wherein a high voltage charge is applied to a photoconductive base, the charged base exposed, and the resultant image on the base developed by overprinting the exposed image-bearing base with a liquid developer containing a coloring agent, a coating agent, a resistivity controlling agent, and carrier liquid, the improvement which comprises over-printing the exposed base with a liquid developer containing a coating agent in accordance with claim 1.

Claim 4

A liquid developer according to claim 1, wherein, in the copolymer used as the coating agent, the acrylic acid compound of formula (i) and the para-alkylstyrene of formula (ii), are present in amounts between about 30-90 mole % and between about 10-95 mole % in the copolymer; respectively, and the acrylic acid compound of formula (iii) is present in an amount between 80-10 mole %.

Claim 5

A liquid developer for electro photography according to claim 1, wherein the para-alkylstyrene represented by the general formula (ii) is para-tert-butylstyrene.

Claim 6

A liquid developer for electro photography according to claim 1, wherein the acrylic acid compound represented by the general formula (iii) is butoxyethyl methacrylate.

Claim 7

A liquid developer according to claim 1, wherein said carrier liquid is selected from the group consisting of aliphatic, alicyclic, aromatic, halogenated and isoparaffinic hydrocarbons.

Claim 8

A liquid developer according to claim 1, wherein said carrier liquid is an isoparaffinic hydrocarbon.

Claim 9

A liquid developer according to claim 1, wherein said coloring agent comprises a coloring agent selected from the group consisting of Lithol Maroon Toner, Alizarine Lake B, Bon Red Toner 5B, Calcium Lithol Toner, Barium Lithol Toner, Pigment Scarlet, Bon Red Roner Y, Lithol Rubine, Brilliant Red Lake R, Lake Red C, Benzidine Yellow, Hansa Yellow, Benzidine Orange, Rhodamine 6G Lake, Rhodamine Toner B, Para Red Toner Light, P, T, A Violet Toner, Peacock Blue Toner, Permanent Peacock Blue, Victoria Blue Toner, Copper Phthalocyanine, Alkali Blue Toner, Malachite Green Toner, Phthalocyanine Green, Mogul A, Mogul L and Carbon Black.

Claim 10

A liquid developer according to claim 1, wherein the acrylic acid compound represented by the general formula (i) is contained in an amount of 3-90 mole % in the copolymer.

Claim 11

A liquid developer according to claim 1, wherein the acrylic acid compound represented by the general formula (iv) is contained in an amount of between about 5-90 mole % in the copolymer.

Claim 12

A liquid developer according to claim 1, wherein said coating agent is present in an amount ranging between 100-1600 parts by weight per 100 parts by weight of said coloring agent, said resistivity controlling agent is present in an amount sufficient to provide a liquid resistivity of the developer within the range of 10 9 -10 12 Ω cm and said carrier liquid is present in an amount ranging between 50-1000 parts by weight for each part by weight of said coloring agent.

Claim 13

A liquid developer according to claim 1, wherein said coating agent is a copolymer having a molecular weight ranging between 5×10 2 -10 5 .

Claim 14

A liquid developer according to claim 1, wherein said copolymer comprises the copolymer obtained by the copolymerization of butoxyethyl methacrylate, hydroxyethyl methacrylate, isobutyl methacrylate and p-tert-butylstyrene.

Claim 15

A liquid developer according to claim 1 wherein the compound (ii) is p-tert-butylstyrene and the compound (iii) is butoxyethyl methacrylate.

Claim 16

A liquid developer according to claim 1 wherein the coating agent comprises a copolymer of an acrylic acid compound (i), a para-alkylstyrene of formula (ii), and an acrylic acid compound (iii).

Claim 17

A liquid developer according to claim 1, wherein the coating agent is a copolymer of acrylic compound (iv), acrylic compound (iii), and para-alkylstyrene.

Claim 18

A liquid developer according to claim 1, wherein said copolymer is a copolymer consisting essentially of p-tert-butylstyrene, hydroxyethyl methacrylate, and isobutyl methacrylate.

Claim 19

A liquid developer according to claim 1, wherein said copolymer is a copolymer consisting essentially of p-tert-butylstyrene, hydroxyethyl methacrylate, and octyl methacrylate.

Claim 20

A liquid developer according to claim 1, wherein said copolymer is a copolymer consisting essentially of p-tert-butylstyrene, hydroxyethyl methacrylate, and lauryl acrylate.

Claim 21

A liquid developer according to claim 1, wherein said copolymer is a copolymer consisting essentially of p-octylstyrene, hydroxypropyl methacrylate, and isobutyl methacrylate.

Claim 22

A liquid developer according to claim 1, wherein said copolymer consists essentially of p-tert-butylstyrene, ethoxyethyl methacrylate, and lauryl methacrylate.

Claim 23

A liquid developer according to claim 1, wherein said para-alkylstyrene represented by the general formula (ii) is selected from the group consisting of para-ethylstyrene, para-propylstyrene, para-n-butylstyrene, para-isobutylstyrene, para-tertiary butylstyrene, para-octylstyrene, para-laurylstyrene, and para-stearylstyrene.

Claim 24

A liquid developer according to claim 1, wherein said acrylic acid compound represented by the general formula (iii) is selected from the group consisting of 2-methoxyethyl acrylate, 2-methoxyethyl methacrylate, 2-ethoxyethyl acrylate, 2-ethoxyethyl methacrylate, 2-butoxyethyl acrylate, 2-butoxyethyl methacrylate, 3-methoxypropyl acrylate, and 3-ethoxypropyl acrylate.

Claim 25

A liquid developer according to claim 1, wherein said acrylic acid compound represented by the general formula (iv) is selected from the group consisting of methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, n-propyl acrylate, n-propyl methacrylate, iso-propyl acrylate, iso-propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, iso-butyl acrylate, iso-butyl methacrylate, tert-butyl acrylate, tert-butyl methacrylate, n-amyl acrylate, n-amyl methacrylate, 3-pentyl acrylate, 3-pentyl methacrylate, 2-methyl-1-butyl acrylate, 2-methyl-1-butyl methacrylate, 3-methyl-1-butyl acrylate, n-hexyl acrylate, n-hexyl methacrylate, 2-methyl-1-pentyl acrylate, 2-ethyl-1-butyl acrylate, 4-methyl-2-pentyl acrylate, n-heptyl acrylate, 2-heptyl acrylate, n-octyl acrylate, n-octyl methacrylate, 2-ethyl-1-hexyl acrylate, 2-ethyl-1-hexyl methacrylate, 2-octyl-acrylate, n-nonyl acrylate, n-decyl acrylate, n-decyl methacrylate, 5-ethyl-2-nonyl acrylate, n-dodecyl acrylate, n-dodecyl methacrylate, n-tetradecyl acrylate, n-tetradecyl methacrylate, 2-methyl-7-ethyl-4-undecyl acrylate, n-hexadecyl acrylate, n-hexadecyl methacrylate, n-octadecyl acrylate, n-octadecyl methacrylate, cyclohexyl acrylate, cyclohexyl methacrylate, 2-methyl cyclohexyl acrylate, 2-methyl-cyclohexyl methacrylate, 3-methylcyclohexyl acrylate, 4-methylcyclohexyl acrylate, 3,3,5-trimethylcyclohexyl acrylate, 3,3,5-trimethylcyclohexyl methacrylate, 4-tert-amylcyclohexyl acrylate, 4-cyclohexylcyclohexyl acrylate, 4-cyclohexylcyclohexyl methacrylate, and 2,4-diamylcyclohexyl acrylate.

Claim 26

A liquid developer for electro photography according to claim 1, wherein the para-alkylstyrene represented by the general formula (ii) is contained in an amount of 20-80 mole % in the copolymer.

Claim 27

A liquid developer for electro photography according to claim 25, wherein the para-alkylstyrene is para-tert-butylstyrene.

Claim 28

A liquid developer for electro photography according to claim 1, wherein the acrylic acid compound represented by the general formula (iii) is contained in an amount of 10-80 mole % in the copolymer.

Claim 29

A liquid developer for electro photography according to claim 27, wherein the acrylic acid compound is butoxyethyl methacrylate.

Claim 30

A liquid developer for electrophotography according to claim 1, wherein a soap of an organic acid selected from the group consisting of naphthenic acid, octanoic acid and stearic acid and a polyvalent metal selected from the group consisting of Group I, II, III, IV, VII and transition metals of the Periodic Table is used as the resistivity controlling agent and an isoparaffinic hydrocarbon is used as the carrier liquid.

Claim 31

A liquid developer according to claim 29, wherein said soap of an organic acid and a polyvalent metal is selected from the group consisting of zirconium octenoate, cobalt naphthenate and manganese octenoate.