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US4155958A Expired / Lapsed US ⏱️ 0.0 years remaining

Beta-phosphosulfoxy alcohols

Assignee: BP Corp North America Inc
•
Filing: 1977-09-26
•
Granted: 1979-05-22
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Expires: 1997-09-26
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Abstract

Abstract Beta-phosphosulfoxy alcohols and preparation thereof by reacting an olefinically unsaturated compound and a poly-thiophosphoric acid with oxygen using actinic radiation as an energy source at a temperature of from -10° to 70° C., preferably in the presence of a dye sensitizer.

Inventors

  • 👤 Ellis K. Fields

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 08:58
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/02; C07F9/06; C07F9/16; C07F9/165; C07F9/17; C07F9/1654

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 139 words
A beta phosphosulfoxy alcohol compound of the general formula ##STR12## wherein A is selected from the group consisting of RO-- and RS--, and B is selected from the group consisting of R'O-- and R'S-- and wherein R and R' are individually selected from the group consisting of hydrogen and alkyl groups of 1 to 24 carbon atoms, and wherein R" is selected from the group consisting of hydrogen, an alkyl group of 1 to 22 carbon atoms, phenyl, naphthyl, anthranyl, phenanthryl and cyclohexyl moieties, said R and R' being optionally substituted, said substitutions being selected from the group consisting of halogens and nitro moieties, and said R" being optionally substituted, said substitutions being selected from the group consisting of halogen, nitro, methoxy, ethoxy, propoxy, butoxy, dialkylamino, hydrogen, methyl, ethyl and ##STR13## wherein A and B are defined as herein.
Claim 2
Dependent Claim 139 words
A beta phosphosulfoxy alcohol compound of the general formula ##STR12## wherein A is selected from the group consisting of RO-- and RS--, and B is selected from the group consisting of R'O-- and R'S-- and wherein R and R' are individually selected from the group consisting of hydrogen and alkyl groups of 1 to 24 carbon atoms, and wherein R" is selected from the group consisting of hydrogen, an alkyl group of 1 to 22 carbon atoms, phenyl, naphthyl, anthranyl, phenanthryl and cyclohexyl moieties, said R and R' being optionally substituted, said substitutions being selected from the group consisting of halogens and nitro moieties, and said R" being optionally substituted, said substitutions being selected from the group consisting of halogen, nitro, methoxy, ethoxy, propoxy, butoxy, dialkylamino, hydrogen, methyl, ethyl and ##STR13## wherein A and B are defined as herein.
Claim 3
Dependent Claim 10 words
The compound of claim 1 which comprises 1-(0,0-diamyl thiophosphoryl sulfoxy)-2-phenyl-2-ethanol.
Claim 4
Dependent Claim 10 words
The compound of claim 1 which comprises 1-(0,0-diisoamyl thiophosphoryl sulfoxy)-2-phenyl-2-ethanol.
Claim 5
Dependent Claim 10 words
The compound of claim 1 which comprises 1-(0,0-diisoamyl thiophosphoryl sulfoxy)-2-octanol.
Claim 6
Dependent Claim 10 words
The compound of claim 1 which comprises 1,6-bis(0,0-diisoamyl thiophosphoryl sulfoxy)-hexane-2,5-diol.
Claim 7
Dependent Claim 10 words
The compound of claim 1 which comprises 1-(0,0-diisoamyl thiophosphoryl sulfoxy)-2-(3-cyclohexenyl-1)-2-ethanol.
Claim 8
Dependent Claim 12 words
The compound of claim 1 which comprises 1-(0,0-diisoamyl thiophosphoryl sulfoxy)-2-[4-hydroxy-3-(0,0-diisoamyl thiophosphoryl sulfoxy)-cyclohexyl]-2-ethanol.
Claim 9
Dependent Claim 10 words
The compound of claim 1 which comprises 1-(0,0-didodecyl thiophosphoryl sulfoxy)-2-dodecanol.
Claim 10
Dependent Claim 9 words
The compound of claim 1 which comprises 1-(S,S-didodecanethiothiophosphoryl sulfoxy)-2-phenyl-2-ethanol.
Claim 11
Dependent Claim 9 words
The compound of claim 1 which comprises 1-(S,S-didodecanethiothiophosphoryl sulfoxy)-2-pentanol.
Claim 12
Dependent Claim 10 words
The compound of claim 1 which comprises 1-(0,0-dimethyl thiophosphoryl sulfoxy)-2-ethanol.

References Cited (Backward Citations)

US2910500A Cited
US3179688A Cited
US3454679A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-05-21 1982-11-20 1983-05-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-05-21 1986-11-20 1987-05-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-05-21 1990-11-20 1991-05-22 $7700.00 Window Closed / Lapsed

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