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US4153424A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymer combinations useful in distillate hydrocarbon oils to improve cold flow properties

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1977-04-22
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Granted: 1979-05-08
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Expires: 1997-04-22
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Abstract

Abstract Oil soluble ethylene polymers or copolymers having a Mn less than about 4000 in combination with an oil soluble polyester material such as a homopolymer or copolymer comprising, at least 10% by weight C4 to C16 substantially straight-chain alkyl esters of acrylic or methacrylic acid, are useful in improving the cold flow properties of distillate hydrocarbon oils.

Inventors

  • 👤 Max J. Wisotsky

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 20:21
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/146; C10L1/16; C10L1/1625; C10L1/1633; C10L1/1641; C10L1/18; C10L1/192; C10L1/195; C10L1/196; C10L1/1963; C10L1/1966; C10L1/197; C10L1/1973; C10L1/20; C10L1/206; C10L1/207; C10L1/208; C10L1/22; C10L1/234; C10L1/236

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 178 words
A fuel oil consisting of a middle distillate petroleum fuel oil boiling in the range of about 150° C. to about 400° C., and of which at least 5 wt. % boils above 350° C., which has been improved in its low temperature flow properties, containing in the range of about 0.001 to 1.0 wt. %, based on the weight of the total composition, of a synergistic flow improving combination of (a) one part by weight of an oil soluble ethylene backbone polymer having a number average molecular weight of about 1,000 to about 4,000 per (b) 0.2 to 4 parts by weight of an oil soluble polyester having a number average molecular weight in the range of about 2,000 to 100,000; wherein said ethylene backbone polymer is a copolymer consisting essentially of 4 to 20 molar proportions of ethylene with a molar proportion of isobutyl acrylate; and, wherein said polyester consists of alkyl acrylate or alkyl methacrylate moieties, said moieties consisting essentially of C 8 to C 16 straight chain alkyl ester of acrylic or methacrylic acid.
Claim 2
Dependent Claim 178 words
A fuel oil consisting of a middle distillate petroleum fuel oil boiling in the range of about 150° C. to about 400° C., and of which at least 5 wt. % boils above 350° C., which has been improved in its low temperature flow properties, containing in the range of about 0.001 to 1.0 wt. %, based on the weight of the total composition, of a synergistic flow improving combination of (a) one part by weight of an oil soluble ethylene backbone polymer having a number average molecular weight of about 1,000 to about 4,000 per (b) 0.2 to 4 parts by weight of an oil soluble polyester having a number average molecular weight in the range of about 2,000 to 100,000; wherein said ethylene backbone polymer is a copolymer consisting essentially of 4 to 20 molar proportions of ethylene with a molar proportion of isobutyl acrylate; and, wherein said polyester consists of alkyl acrylate or alkyl methacrylate moieties, said moieties consisting essentially of C 8 to C 16 straight chain alkyl ester of acrylic or methacrylic acid.
Claim 3
Dependent Claim 15 words
A fuel oil according to claim 1, wherein said polyester is a homopolymer of tetradecylacrylate.
Claim 4
Dependent Claim 17 words
A fuel oil according to claim 1, wherein said polyester consists of hexadecyl acrylate and methyl methacrylate.
Claim 5
Dependent Claim 25 words
A fuel oil according to claim 1, wherein said polyester consists of polyalkyl methacrylate and wherein said alkyl groups average about 12 to 14 carbons.

References Cited (Backward Citations)

US3275427A Cited
US4010006A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-05-07 1982-11-06 1983-05-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-05-07 1986-11-06 1987-05-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-05-07 1990-11-06 1991-05-08 $7700.00 Window Closed / Lapsed

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