US4153422A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polymer combinations useful in distillate hydrocarbon oils to improve cold flow properties
Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1975-04-07
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Granted: 1979-05-08
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Expires: 1995-04-07
Abstract
Abstract Oil soluble ethylene-vinyl ester copolymers having a Mn less than about 4000 in combination with an oil soluble polyester material, such as a homopolymer or copolymer, comprising at least 10% by weight C14 to C16 substantially straight-chain alkyl esters of acrylic or methacrylic acid, are useful in improving the cold flow properties of distillate hydrocarbon oils.
Inventors
- 👤 Max J. Wisotsky
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 21:55
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/146; C10L1/16; C10L1/1625; C10L1/1633; C10L1/1641; C10L1/18; C10L1/192; C10L1/195; C10L1/196; C10L1/1963; C10L1/1966; C10L1/197; C10L1/1973; C10L1/20; C10L1/206; C10L1/207; C10L1/208; C10L1/22; C10L1/234; C10L1/236; C10L1/2362; C10L1/2364
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
229 words
A fuel oil consisting of a wax containing atmospheric middle distillate petroleum fuel oil boiling in the range of 120° to 480° C., having at least 30 wt. % boiling between about 120° to about 230° C. and at least 5 wt. % boiling above 350° C., said oil having a viscosity of 1.6 to 7.5 centistokes at 38° C. and leaving less than 3 wt. %, based on the total weight of the fuel, of n-paraffin wax boiling above 350° C. and separable from said oil at a temperature of about 7° C. below the cloud point of said oil, said oil containing in the range of about 0.005 to 0.1 wt. %, based on the weight of the total composition, of a synergistic flow improving combination of (a) one part by weight of an oil soluble ethylene-ester copolymer having a number average molecular weight less than about 4000 per (b) 0.2 to 4 parts by weight of an oil-soluble polyester having a number average molecular weight in the range of about 2000 to 100,000; wherein said ethylene-ester copolymer consists essentially of 4 to 20 molar proportions of ethylene with a molar proportion of vinyl acetate; and wherein said polyester consists of alkyl acrylate or alkyl methacrylate moieties, and said moieties consist essentially of C 14 to C 16 straight chain alkyl ester of acrylic or methacrylic acid.
Claim 2
Dependent Claim
229 words
A fuel oil consisting of a wax containing atmospheric middle distillate petroleum fuel oil boiling in the range of 120° to 480° C., having at least 30 wt. % boiling between about 120° to about 230° C. and at least 5 wt. % boiling above 350° C., said oil having a viscosity of 1.6 to 7.5 centistokes at 38° C. and leaving less than 3 wt. %, based on the total weight of the fuel, of n-paraffin wax boiling above 350° C. and separable from said oil at a temperature of about 7° C. below the cloud point of said oil, said oil containing in the range of about 0.005 to 0.1 wt. %, based on the weight of the total composition, of a synergistic flow improving combination of (a) one part by weight of an oil soluble ethylene-ester copolymer having a number average molecular weight less than about 4000 per (b) 0.2 to 4 parts by weight of an oil-soluble polyester having a number average molecular weight in the range of about 2000 to 100,000; wherein said ethylene-ester copolymer consists essentially of 4 to 20 molar proportions of ethylene with a molar proportion of vinyl acetate; and wherein said polyester consists of alkyl acrylate or alkyl methacrylate moieties, and said moieties consist essentially of C 14 to C 16 straight chain alkyl ester of acrylic or methacrylic acid.
Claim 3
Dependent Claim
17 words
A fuel oil according to claim 1 wherein said polyester is a homopolymer consisting of tetradecylacrylate moieties.
Claim 4
Dependent Claim
21 words
A fuel oil according to claim 1 wherein said polyester is a copolymer consisting of hexadecyl acrylate and methyl methacrylate moieties.
References Cited (Backward Citations)
FR1323547A
Cited
US3275427A
Cited
US3792983A
Cited
US3620696A
Cited
US3832150A
Cited
US3661541A
Cited
US4010006A
Cited
US3726653A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-05-07 | 1982-11-06 | 1983-05-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-05-07 | 1986-11-06 | 1987-05-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-05-07 | 1990-11-06 | 1991-05-08 | $7700.00 | Window Closed / Lapsed |