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US4153422A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymer combinations useful in distillate hydrocarbon oils to improve cold flow properties

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1975-04-07
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Granted: 1979-05-08
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Expires: 1995-04-07
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Abstract

Abstract Oil soluble ethylene-vinyl ester copolymers having a Mn less than about 4000 in combination with an oil soluble polyester material, such as a homopolymer or copolymer, comprising at least 10% by weight C14 to C16 substantially straight-chain alkyl esters of acrylic or methacrylic acid, are useful in improving the cold flow properties of distillate hydrocarbon oils.

Inventors

  • 👤 Max J. Wisotsky

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 21:55
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/146; C10L1/16; C10L1/1625; C10L1/1633; C10L1/1641; C10L1/18; C10L1/192; C10L1/195; C10L1/196; C10L1/1963; C10L1/1966; C10L1/197; C10L1/1973; C10L1/20; C10L1/206; C10L1/207; C10L1/208; C10L1/22; C10L1/234; C10L1/236; C10L1/2362; C10L1/2364

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 229 words
A fuel oil consisting of a wax containing atmospheric middle distillate petroleum fuel oil boiling in the range of 120° to 480° C., having at least 30 wt. % boiling between about 120° to about 230° C. and at least 5 wt. % boiling above 350° C., said oil having a viscosity of 1.6 to 7.5 centistokes at 38° C. and leaving less than 3 wt. %, based on the total weight of the fuel, of n-paraffin wax boiling above 350° C. and separable from said oil at a temperature of about 7° C. below the cloud point of said oil, said oil containing in the range of about 0.005 to 0.1 wt. %, based on the weight of the total composition, of a synergistic flow improving combination of (a) one part by weight of an oil soluble ethylene-ester copolymer having a number average molecular weight less than about 4000 per (b) 0.2 to 4 parts by weight of an oil-soluble polyester having a number average molecular weight in the range of about 2000 to 100,000; wherein said ethylene-ester copolymer consists essentially of 4 to 20 molar proportions of ethylene with a molar proportion of vinyl acetate; and wherein said polyester consists of alkyl acrylate or alkyl methacrylate moieties, and said moieties consist essentially of C 14 to C 16 straight chain alkyl ester of acrylic or methacrylic acid.
Claim 2
Dependent Claim 229 words
A fuel oil consisting of a wax containing atmospheric middle distillate petroleum fuel oil boiling in the range of 120° to 480° C., having at least 30 wt. % boiling between about 120° to about 230° C. and at least 5 wt. % boiling above 350° C., said oil having a viscosity of 1.6 to 7.5 centistokes at 38° C. and leaving less than 3 wt. %, based on the total weight of the fuel, of n-paraffin wax boiling above 350° C. and separable from said oil at a temperature of about 7° C. below the cloud point of said oil, said oil containing in the range of about 0.005 to 0.1 wt. %, based on the weight of the total composition, of a synergistic flow improving combination of (a) one part by weight of an oil soluble ethylene-ester copolymer having a number average molecular weight less than about 4000 per (b) 0.2 to 4 parts by weight of an oil-soluble polyester having a number average molecular weight in the range of about 2000 to 100,000; wherein said ethylene-ester copolymer consists essentially of 4 to 20 molar proportions of ethylene with a molar proportion of vinyl acetate; and wherein said polyester consists of alkyl acrylate or alkyl methacrylate moieties, and said moieties consist essentially of C 14 to C 16 straight chain alkyl ester of acrylic or methacrylic acid.
Claim 3
Dependent Claim 17 words
A fuel oil according to claim 1 wherein said polyester is a homopolymer consisting of tetradecylacrylate moieties.
Claim 4
Dependent Claim 21 words
A fuel oil according to claim 1 wherein said polyester is a copolymer consisting of hexadecyl acrylate and methyl methacrylate moieties.

References Cited (Backward Citations)

FR1323547A Cited
US3275427A Cited
US3792983A Cited
US3620696A Cited
US3832150A Cited
US3661541A Cited
US4010006A Cited
US3726653A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-05-07 1982-11-06 1983-05-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-05-07 1986-11-06 1987-05-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-05-07 1990-11-06 1991-05-08 $7700.00 Window Closed / Lapsed

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