Stabilized isocyanate compositions

Claim 2

An isocyanate composition stabilized against color formation which comprises an organic isocyanate, which is normally susceptible to color formation on storage, having incorporated therein a color stabilizing amount of a compound having the formula ##STR6## wherein R 1 is selected from the group consisting of lower-alkyl and aryl, having from 6 to 12 carbon atoms, inclusive, R 2 represents lower-alkyl, R 1 and R 2 taken together represent lower-alkylene having 2 to 3 carbon atoms in the chain which with the ##STR7## group forms the residue of a heterocyclic ring containing from 5 to 6 ring atoms and R 3 represents a group selected from the class consisting of hydrogen, lower-alkyl, and aralkyl having from 7 to 13 carbon atoms, inclusive.

Claim 3

A composition according to claim 1 wherein said isocyanate contains a color stabilizing amount of 2-ethyloxazoline.

Claim 4

A composition according to claim 1 wherein said isocyanate contains a color stabilizing amount of ethyl N-phenylformimidate.

Claim 5

A composition according to claim 1 wherein said isocyanate contains a color stabilizing amount of 2-benzyl-5,6-dihydro-4,4,6-trimethyl-4H-1,3-oxazine.

Claim 6

A composition according to claim 1 wherein said isocyanate contains a color stabilizing amount of 2-methyloxazoline.

Claim 7

A composition according to claim 1 wherein said isocyanate contains a color stabilizing amount of 2,4,4-trimethyloxazoline.

Claim 8

A composition according to claim 1 wherein said isocyanate is methylenebis(phenyl isocyanate).

Claim 9

A composition according to claim 1 wherein said isocyanate is a prepolymer of methylenebis(phenyl isocyanate) and an aliphatic diol.

Claim 10

An isocyanate composition stabilized against color formation which comprises an organic isocyanate selected from methylenebis(phenyl isocyanate) and prepolymers thereof with aliphatic diols, said isocyanate having incorporated therein a color stabilizing amount of a compound having the formula: ##STR8## wherein R 1 is selected from the group consisting of lower-alkyl and aryl, having from 6 to 12 carbon atoms, inclusive, R 2 represents lower-alkyl, R 1 and R 2 taken together represent lower-alkylene having 2 to 3 carbon atoms in the chain which with the ##STR9## group forms the residue of a heterocyclic ring containing from 5 to 6 ring atoms, and R 3 represents a group selected from the class consisting of hydrogen, lower-alkyl, and aralkyl having from 7 to 13 carbon atoms, inclusive.

Claim 11

An isocyanate composition stabilized against color formation which comprises an organic isocyanate selected from methylenebis(phenyl isocyanate) and prepolymers thereof with aliphatic diols, said isocyanate having incorporated therein a color stabilizing amount of a compound having the formula: ##STR8## wherein R 1 is selected from the group consisting of lower-alkyl and aryl, having from 6 to 12 carbon atoms, inclusive, R 2 represents lower-alkyl, R 1 and R 2 taken together represent lower-alkylene having 2 to 3 carbon atoms in the chain which with the ##STR9## group forms the residue of a heterocyclic ring containing from 5 to 6 ring atoms, and R 3 represents a group selected from the class consisting of hydrogen, lower-alkyl, and aralkyl having from 7 to 13 carbon atoms, inclusive.

Claim 12

A composition according to claim 9 wherein the color stabilizing compound is 2-ethyloxazoline.

Claim 13

A composition according to claim 9 wherein the color stabilizing compound is ethyl N-phenylformimidate.

Claim 14

A composition according to claim 9 wherein the color stabilizing compound is 2-benzyl-5,6-dihydro-4,4,6-trimethyl-4H-1,3-oxazine.

Claim 15

A composition according to claim 9 wherein the color stabilizing compound is 2-methyloxazoline.

Claim 16

A composition according to claim 9 wherein the color stabilizing compound is 2,4,4-trimethyloxazoline.

Claim 17

A composition according to claim 9 which also comprises color stabilizing amounts of triphenyl phosphite and 2,6-di-tert.-butyl-4-methylphenol.

Claim 18

A composition stabilized against the formation of color comprising 4,4'-methylenebis(phenyl isocyanate) and a color stabilizing amount of 2-ethyloxazoline.

Claim 19

A composition stabilized against the formation of color comprising 4,4'-methylenebis(phenyl isocyanate) and a color stabilizing amount of 2-ethyloxazoline.

Claim 20

A composition according to claim 16 which also comprises color stabilizing amounts of triphenyl phosphite and 2,6-di-tert.-butyl-4-methylphenol.

Claim 21

A composition stabilized against the formation of color comprising 4,4'-methylenebis(phenyl isocyanate) and a color stabilizing amount of 2-methyloxazoline.

Claim 22

A composition stabilized against the formation of color comprising 4,4'-methylenebis(phenyl isocyanate) and a color stabilizing amount of 2-methyloxazoline.

Claim 23

A process for discharging the color which has formed on storage of an aromatic isocyanate containing a methylene group bridging two aromatic nuclei which process comprises incorporating into said isocyanate a color discharging quantity of a compound having the formula: ##STR10## wherein R 1 is selected from the group consisting of lower-alkyl and aryl, R 2 represents lower-alkyl, R 1 and R 2 taken together with the ##STR11## group to which they are attached form the residue of a heterocyclic ring selected from oxazoline and oxazine, and R 3 represents a group selected from the class consisting of hydrogen, lower-alkyl, and aralkyl having from 7 to 13 carbon atoms, inclusive.

Claim 24

A process for discharging the color which has formed on storage of an aromatic isocyanate containing a methylene group bridging two aromatic nuclei which process comprises incorporating into said isocyanate a color discharging quantity of a compound having the formula: ##STR10## wherein R 1 is selected from the group consisting of lower-alkyl and aryl, R 2 represents lower-alkyl, R 1 and R 2 taken together with the ##STR11## group to which they are attached form the residue of a heterocyclic ring selected from oxazoline and oxazine, and R 3 represents a group selected from the class consisting of hydrogen, lower-alkyl, and aralkyl having from 7 to 13 carbon atoms, inclusive.

Claim 25

A process according to claim 19 wherein said color discharging compound is 2-ethyloxazoline.

Claim 26

A process according to claim 19 wherein said aromatic isocyanate is 4,4'-methylenebis(phenyl isocyanate).

Claim 27

A process according to claim 19 wherein said aromatic isocyanate is a prepolymer of 4,4'-methylenebis(phenyl isocyanate) and at least one aliphatic diol.