Method and apparatus for precipitating metal cement

Claim 2

In a method for the precipitation of metal cement from a metal-solution mixed with a precipitant, wherein an aqueous solution of a first metal in salt form is contacted with pieces of a second metal, the second metal being less noble than the first metal in the electromotive series, the improvement which comprises conducting such precipitation in a chamber which is oscillating at a frequency of at least about 8 Hz and discharging from such chamber an aqueous suspension containing metal cement particles while adding to such suspension during such discharging sufficient acid to substantially prevent chemical reaction between such metal particles and other components present in such suspension.

Claim 3

The method of claim 1 wherein said oscillating occurs at an amplitude diameter ranging from about 4 mm to 25 mm.

Claim 4

The method of claim 1 wherein said method is carried out in said chamber at a temperature of from about 20° to 120° C.

Claim 5

The method of claim 1 wherein said second metal pieces are in the form of granulate lumps.

Claim 6

The method of claim 1 wherein said first metal solution and said second metal pieces are fed to said chamber at respective opposite ends thereof.

Claim 7

The method of claim 1 wherein an acid is added in the discharge area of said chamber container to establish a pH-value such that the filterability of the discharged product is assured.

Claim 8

A process for the preparation of cement metal comprising the steps of (A) simultaneously (1) contacting in a horizontally elongated zone having a generally uniform cross-sectional configuration and having a length at least twice the average cross sectional dimension an aqueous medium having dissolved therein salts of metal to be precipitated, said medium initially containing at least about 500 milligrams per liter of said metal to be precipitated with pieces comprised of metal less noble than such metal to be precipitated, said pieces being at least about 2 millimeters in average particle size, said zone being initially charged volumetrically with over about 50% of the volume of said zone with said pieces, and with less than about 50% but greater than about 25% of said volume with said aqueous medium, (2) maintaining said medium at a temperature from about 20° to 120° C., (3) continuously vibrating said ball mill zone at a frequency of from about 8 to 20 hertz at a rotational oscillatory amplitude of from about 4 to 25 millimeters, (B) and then separating the resulting said aqueous medium from the resulting said pieces after a contacting time ranging from about 15 to 200 seconds while separating from such chamber an aqueous suspension containing metal cement particles while adding to such suspension during such separating sufficient acid to substantially prevent chemical reaction between such metal particles and other components present in such suspension.

Claim 9

A process for the preparation of cement metal comprising the steps of (A) simultaneously (1) contacting in a horizontally elongated zone having a generally uniform cross-sectional configuration and having a length at least twice the average cross sectional dimension an aqueous medium having dissolved therein salts of metal to be precipitated, said medium initially containing at least about 500 milligrams per liter of said metal to be precipitated with pieces comprised of metal less noble than such metal to be precipitated, said pieces being at least about 2 millimeters in average particle size, said zone being initially charged volumetrically with over about 50% of the volume of said zone with said pieces, and with less than about 50% but greater than about 25% of said volume with said aqueous medium, (2) maintaining said medium at a temperature from about 20° to 120° C., (3) continuously vibrating said ball mill zone at a frequency of from about 8 to 20 hertz at a rotational oscillatory amplitude of from about 4 to 25 millimeters, (B) and then separating the resulting said aqueous medium from the resulting said pieces after a contacting time ranging from about 15 to 200 seconds while separating from such chamber an aqueous suspension containing metal cement particles while adding to such suspension during such separating sufficient acid to substantially prevent chemical reaction between such metal particles and other components present in such suspension.

Claim 10

The process of claim 7 wherein said medium initially contains at least about 30 grams per liter of said metal to be precipitated.

Claim 11

The process of claim 7 wherein said medium moves countercurrently through said pieces.