US4151341A
Expired / Lapsed
US
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Novel polymers and polymeric salts
Assignee: Dow Chemical Co
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Filing: 1978-04-05
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Granted: 1979-04-24
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Expires: 1998-04-05
Abstract
Abstract Novel low molecular weight interpolymers containing pendant lower alkyl capped poly(oxyethylene)ether groups are effective as aqueous dispersing agents for particulate matter and are particularly effective for difficult-to-disperse, finely divided inorganic solids such as precipitated calcium carbonate and satin white. The interpolymers comprise, in polymerized form, (1) an alkenyl benzyl ether of an ethoxylated lower alkane compound, which ether has the formula: ##STR1## (wherein R is hydrogen or methyl, R 1 is lower alkyl and m is a positive integer greater than 1) with (2) a copolymerizable ethylenically unsaturated acid such as acrylic acid, methacrylic acid, etc., or a copolymerizable ethylenically unsaturated dicarboxylic anhydride such as maleic anhydride and (3) a hydrophobic monomer such as styrene.
Inventors
- 👤 Robert H. Lalk
- 👤 Syamalarao Evani
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 03:06
CPC Classifications
C; C08; C08F; C08F222/00; C08F222/04; C08F222/06; C08F220/00; C08F220/02; C08F220/04; C08F220/06; C08F246/00; Y; Y10; Y10S; Y10S526/00; Y10S526/932
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
109 words
A low molecular weight interpolymer which is at least inherently water-dispersible and which comprises, in polymerized from and based upon the total moles of monomer, (a) from about 1 to about 25 mole percent of an alkenyl benzyl ether monomer having the formula: ##STR7## where R is hydrogen or methyl, R 1 is a lower alkyl group and m is a positive integer of from about 10 to about 100; (b) from about 20 to about 60 mole percent of a copolymerizable ethylenically unsaturated carboxylic acid monomer or a copolymerizable ethylenically unsaturated dicarboxylic anhydride monomer; and (c) from about 25 to about 75 mole percent of a hydrophobic monomer.
Claim 2
Dependent Claim
109 words
A low molecular weight interpolymer which is at least inherently water-dispersible and which comprises, in polymerized from and based upon the total moles of monomer, (a) from about 1 to about 25 mole percent of an alkenyl benzyl ether monomer having the formula: ##STR7## where R is hydrogen or methyl, R 1 is a lower alkyl group and m is a positive integer of from about 10 to about 100; (b) from about 20 to about 60 mole percent of a copolymerizable ethylenically unsaturated carboxylic acid monomer or a copolymerizable ethylenically unsaturated dicarboxylic anhydride monomer; and (c) from about 25 to about 75 mole percent of a hydrophobic monomer.
Claim 3
Dependent Claim
16 words
The interpolymer of claim 1 wherein the molecular weight is from about 1,000 to about 10,000.
Claim 4
Dependent Claim
9 words
The interpolymer of claim 1 wherein R is hydrogen.
Claim 5
Dependent Claim
10 words
The interpolymer of claim 1 wherein R 1 is methyl.
Claim 6
Dependent Claim
14 words
The interpolymer of claim 1 wherein m is from about 20 to about 40.
Claim 7
Dependent Claim
14 words
The interpolymer of claim 1 wherein the acid or anhydride monomer is maleic anhydride.
Claim 8
Dependent Claim
11 words
The interpolymer of claim 6 wherein the hydrophobic monomer is styrene.
Claim 9
Dependent Claim
86 words
The interpolymer of claim 1 (A) which comprises: (a) from about 5 to about 25 mole percent of the alkenyl benzyl ether monomer; (b) from about 30 to about 50 mole percent of the unsaturated acid or anhydride monomer; and (c) from about 30 to about 60 mole percent of the hydrophobic monomer, all based upon the total moles of monomer in the polymer; and (B) wherein, in the alkenyl benzyl ether monomer, the value of the integer m is from about 10 to about 40.
Claim 10
Dependent Claim
26 words
The interpolymer of claim 1 which comprises from about 5 to about 25 mole percent of the alkenyl benzyl ether monomer on a total mole basis.
Claim 11
Dependent Claim
26 words
An aqueous dispersion of water-insoluble organic or inorganic particulate matter containing an amount of the interpolymer of claim 1 which is sufficient to stabilize the dispersion.
Claim 12
Dependent Claim
18 words
The aqueous dispersion of claim 10 wherein the particulate matter comprises a film-forming natural or synthetic polymer particle.
Claim 13
Dependent Claim
15 words
The aqueous dispersion of claim 10 wherein the particulate matter comprises finely divided inorganic solids.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-04-23 | 1982-10-23 | 1983-04-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-04-23 | 1986-10-23 | 1987-04-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-04-23 | 1990-10-23 | 1991-04-24 | $7700.00 | Window Closed / Lapsed |