Method for diffusion coating an Fe-Ni base alloy with chromium

Claim 1

A method for making an article consisting essentially of an Fe--Ni base alloy of the controlled linear thermal expansion type characterized by the substantial absence of Cr, having an inflection in its mean coefficient of linear thermal expansion in its curie temperature range, and having a mean coefficient of linear thermal expansion of less than about 4.7 inches X 10 -6 per inch per °F. at the inflection temperature, the alloy consisting essentially of, by weight, 30-40% Ni, 10-20% Co, 1-5% of the sum of Cb and Ta, 0.5-3% Ti, 0.2-3% Al, up to about 3% Hf, up to about 3% Zr, up to about 0.5% B, with the balance Fe and incidental impurities, a surface of the alloy having diffused therein a coating of a material selected from the group consisting of Cr and alloys of Cr and Ni, comprising the steps of: providing a powder mixture, by weight of 15-25% Cr powder, 1.5-2.5% of a chloride salt activator, with the balance alumina powder; placing the article and the powder mixture in a container with a non-oxidizing atmosphere; and then, heating the article and the mixture at a temperature in the range of about 1450°-1650° F. for a time sufficient for Cr to deposit on and diffuse into the surface.

Claim 2

A method for making an article consisting essentially of an Fe--Ni base alloy of the controlled linear thermal expansion type characterized by the substantial absence of Cr, having an inflection in its mean coefficient of linear thermal expansion in its curie temperature range, and having a mean coefficient of linear thermal expansion of less than about 4.7 inches X 10 -6 per inch per °F. at the inflection temperature, the alloy consisting essentially of, by weight, 30-40% Ni, 10-20% Co, 1-5% of the sum of Cb and Ta, 0.5-3% Ti, 0.2-3% Al, up to about 3% Hf, up to about 3% Zr, up to about 0.5% B, with the balance Fe and incidental impurities, a surface of the alloy having diffused therein a coating of a material selected from the group consisting of Cr and alloys of Cr and Ni, comprising the steps of: providing a powder mixture, by weight of 15-25% Cr powder, 1.5-2.5% of a chloride salt activator, with the balance alumina powder; placing the article and the powder mixture in a container with a non-oxidizing atmosphere; and then, heating the article and the mixture at a temperature in the range of about 1450°-1650° F. for a time sufficient for Cr to deposit on and diffuse into the surface.