US4148894A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of making molten silicon infiltration reaction products and products made thereby
Assignee: General Electric Co
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Filing: 1977-11-07
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Granted: 1979-04-10
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Expires: 1997-11-07
Abstract
Abstract Infiltration reaction products are provided of molten silicon and certain blends of particulated carbon and various particulated inorganic materials substantially unreactive to molten silicon, such as boron nitride particles. These molten silicon infiltration products of reaction are readily machinable and can be applied, or formed in-situ as contiguous layers on silicon carbide, or silicon-silicon carbide substrates, etc., to produce multilayer composites having an improved strength over the base refractory structure.
Inventors
- 👤 William B. Hillig
- 👤 Charles R. Morelock
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 18:30
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/515; C04B35/58; C04B35/583; C04B35/56; C04B35/565; C04B35/573; Y; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12486; Y10T428/16; Y10T428/163; Y10T428/164; Y10T428/166; Y10T428/30; Y10T442/00; Y10T442/30
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
155 words
Composites comprising, (A) a contiguous machinable exterior layer, and (B) a refractory base structure, where the contiguous machinable exterior layer (A) is the infiltration product of reaction by molten silicon, and a substantially uniform mixture comprising by volume, from 45% to 90% of particulated carbon having up to an equal proportion by volume, based on the total volume of the mixture, of silicon carbide particles, and from 10% to 55% of a particulated inorganic material selected from the class consisting of boron nitride, aluminum oxide, magnesium oxide, and silicon nitride, substantially inert to molten silicon at temperatures up to 1600° C., having an average particle size of from 0.1 to 2000 microns, and a Mohs hardness value falling within the range of 1-7, and the refractory base structure (B) is a member selected from the class of shaped silicon carbide refractories and the infiltration product of reaction by molten silicon and a carbon fiber preform.
Claim 2
Dependent Claim
155 words
Composites comprising, (A) a contiguous machinable exterior layer, and (B) a refractory base structure, where the contiguous machinable exterior layer (A) is the infiltration product of reaction by molten silicon, and a substantially uniform mixture comprising by volume, from 45% to 90% of particulated carbon having up to an equal proportion by volume, based on the total volume of the mixture, of silicon carbide particles, and from 10% to 55% of a particulated inorganic material selected from the class consisting of boron nitride, aluminum oxide, magnesium oxide, and silicon nitride, substantially inert to molten silicon at temperatures up to 1600° C., having an average particle size of from 0.1 to 2000 microns, and a Mohs hardness value falling within the range of 1-7, and the refractory base structure (B) is a member selected from the class of shaped silicon carbide refractories and the infiltration product of reaction by molten silicon and a carbon fiber preform.
Claim 3
Dependent Claim
29 words
A composite in accordance with claim 1, where the contiguous layer is based on the infiltration by molten silicon into a mixture of carbon particles and boron nitride particles.
Claim 4
Dependent Claim
17 words
A composite in accordance with claim 1, where the refractory base structure is a silicon carbide substrate.
Claim 5
Dependent Claim
17 words
A composite in accordance with claim 1, where the refractory base structure is a silicon-silicon carbide substrate.
Claim 6
Dependent Claim
36 words
A composite in accordance with claim 1, where the contiguous layer is a multi-layer infiltration product of reaction of a mixture of boron nitride and carbon particles on both sides of an intermediate carbon fiber layer.
Claim 7
Dependent Claim
16 words
A composite in accordance with claim 1, in the form of a gas turbine shroud section.
Claim 8
Dependent Claim
16 words
A composite in accordance with claim 1, in the form of an aircraft engine shroud section.
Claim 9
Dependent Claim
16 words
A composite in accordance with claim 1, in the form of a gas turbine transition piece.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-04-09 | 1982-10-09 | 1983-04-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-04-09 | 1986-10-09 | 1987-04-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-04-09 | 1990-10-09 | 1991-04-10 | $7700.00 | Window Closed / Lapsed |