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US4148894A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of making molten silicon infiltration reaction products and products made thereby

Assignee: General Electric Co
•
Filing: 1977-11-07
•
Granted: 1979-04-10
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Expires: 1997-11-07
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Abstract

Abstract Infiltration reaction products are provided of molten silicon and certain blends of particulated carbon and various particulated inorganic materials substantially unreactive to molten silicon, such as boron nitride particles. These molten silicon infiltration products of reaction are readily machinable and can be applied, or formed in-situ as contiguous layers on silicon carbide, or silicon-silicon carbide substrates, etc., to produce multilayer composites having an improved strength over the base refractory structure.

Inventors

  • 👤 William B. Hillig
  • 👤 Charles R. Morelock

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 18:30
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/515; C04B35/58; C04B35/583; C04B35/56; C04B35/565; C04B35/573; Y; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12486; Y10T428/16; Y10T428/163; Y10T428/164; Y10T428/166; Y10T428/30; Y10T442/00; Y10T442/30

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 155 words
Composites comprising, (A) a contiguous machinable exterior layer, and (B) a refractory base structure, where the contiguous machinable exterior layer (A) is the infiltration product of reaction by molten silicon, and a substantially uniform mixture comprising by volume, from 45% to 90% of particulated carbon having up to an equal proportion by volume, based on the total volume of the mixture, of silicon carbide particles, and from 10% to 55% of a particulated inorganic material selected from the class consisting of boron nitride, aluminum oxide, magnesium oxide, and silicon nitride, substantially inert to molten silicon at temperatures up to 1600° C., having an average particle size of from 0.1 to 2000 microns, and a Mohs hardness value falling within the range of 1-7, and the refractory base structure (B) is a member selected from the class of shaped silicon carbide refractories and the infiltration product of reaction by molten silicon and a carbon fiber preform.
Claim 2
Dependent Claim 155 words
Composites comprising, (A) a contiguous machinable exterior layer, and (B) a refractory base structure, where the contiguous machinable exterior layer (A) is the infiltration product of reaction by molten silicon, and a substantially uniform mixture comprising by volume, from 45% to 90% of particulated carbon having up to an equal proportion by volume, based on the total volume of the mixture, of silicon carbide particles, and from 10% to 55% of a particulated inorganic material selected from the class consisting of boron nitride, aluminum oxide, magnesium oxide, and silicon nitride, substantially inert to molten silicon at temperatures up to 1600° C., having an average particle size of from 0.1 to 2000 microns, and a Mohs hardness value falling within the range of 1-7, and the refractory base structure (B) is a member selected from the class of shaped silicon carbide refractories and the infiltration product of reaction by molten silicon and a carbon fiber preform.
Claim 3
Dependent Claim 29 words
A composite in accordance with claim 1, where the contiguous layer is based on the infiltration by molten silicon into a mixture of carbon particles and boron nitride particles.
Claim 4
Dependent Claim 17 words
A composite in accordance with claim 1, where the refractory base structure is a silicon carbide substrate.
Claim 5
Dependent Claim 17 words
A composite in accordance with claim 1, where the refractory base structure is a silicon-silicon carbide substrate.
Claim 6
Dependent Claim 36 words
A composite in accordance with claim 1, where the contiguous layer is a multi-layer infiltration product of reaction of a mixture of boron nitride and carbon particles on both sides of an intermediate carbon fiber layer.
Claim 7
Dependent Claim 16 words
A composite in accordance with claim 1, in the form of a gas turbine shroud section.
Claim 8
Dependent Claim 16 words
A composite in accordance with claim 1, in the form of an aircraft engine shroud section.
Claim 9
Dependent Claim 16 words
A composite in accordance with claim 1, in the form of a gas turbine transition piece.

References Cited (Backward Citations)

US2992127A Cited
US3095316A Cited
US3131089A Cited
US3458341A Cited
US3462340A Cited
US4119189A Cited
US3955038A Cited
US4035541A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-04-09 1982-10-09 1983-04-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-04-09 1986-10-09 1987-04-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-04-09 1990-10-09 1991-04-10 $7700.00 Window Closed / Lapsed

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