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US4147690A Expired / Lapsed US ⏱️ 0.0 years remaining

Smoke and fire resistant compositions

Assignee: Burns and Russell Co
•
Filing: 1977-12-13
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Granted: 1979-04-03
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Expires: 1997-12-13
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Abstract

Abstract A combination of (1) magnesium hydroxide and (2) alumina trihydrate has been found to have synergestic properties in reducing smoke and/or flame spread in many polymer compositions when compared to the use of either alone. In some cases even better results are obtained by including antimony trioxide or antimony trioxide together with finely divided silica.

Inventors

  • 👤 Russell P. Rich

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 09:51
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/18; C08K3/20; C08K3/22

Claims Analysis

Total Claims: 58
Claim 1
Independent Claim 245 words
A composition comprising (I) a mixture comprising (a) magnesium hydroxide and (b) alumina trihydrate and (II) a polymer which is (A) a polyester, (B) an epoxy resin, (C) a vinyl chloride polymer or (D) a polyurethane, the mixture of magnesium hyroxide and alumina trihydrate being present in an amount sufficient to impart improved flame or smoke resistance, wherein (1) when the polymer is a non-halogenated polyester there is employed 25 to 100 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 95:5; (2) when the polymer is a halogenated polyester there is employed 5 to 100 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 2:1; (3) when the polymer is an epoxy resin there is employed 5 to 100 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 9:95 to 2:1 at 5 to 90 parts per 100 parts of polymer and 5:95 to 1:1 at above 90 up to 100 parts per 100 parts of polymer (4) when the polymer is a vinyl chloride polymer there is employed 4 to 50 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being 5:95 to 95:5; and (5 ) when the polymer is a polyurethane there is employed 50 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being 1:1.
Claim 2
Dependent Claim 245 words
A composition comprising (I) a mixture comprising (a) magnesium hydroxide and (b) alumina trihydrate and (II) a polymer which is (A) a polyester, (B) an epoxy resin, (C) a vinyl chloride polymer or (D) a polyurethane, the mixture of magnesium hyroxide and alumina trihydrate being present in an amount sufficient to impart improved flame or smoke resistance, wherein (1) when the polymer is a non-halogenated polyester there is employed 25 to 100 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 95:5; (2) when the polymer is a halogenated polyester there is employed 5 to 100 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 2:1; (3) when the polymer is an epoxy resin there is employed 5 to 100 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 9:95 to 2:1 at 5 to 90 parts per 100 parts of polymer and 5:95 to 1:1 at above 90 up to 100 parts per 100 parts of polymer (4) when the polymer is a vinyl chloride polymer there is employed 4 to 50 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being 5:95 to 95:5; and (5 ) when the polymer is a polyurethane there is employed 50 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being 1:1.
Claim 3
Dependent Claim 13 words
A composition according to claim 1 wherein the polymer is a non-halogenated polyester.
Claim 4
Dependent Claim 41 words
A composition according to claim 2 wherein the mixture (I) consists of mangesium hydroxide and alumina trihydrate and is present in an amount sufficient to impart improved flame resistance, there being employed 25 parts of (I) per 100 parts of polymer.
Claim 5
Dependent Claim 52 words
A composition according to claim 2 wherein the mixture (I) consists of magnesium hydroxide and alumina trihydrate and is present in an amount sufficient to impart improved smoke resistance, there being employed 25 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 1:1.
Claim 6
Dependent Claim 51 words
A composition according to claim 2 wherein the mixture (I) consists of magnesium hydroxide and alumina trihydrate is present in an amount sufficient to impart improved smoke resistance, there being employed 100 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 1:1.
Claim 7
Dependent Claim 13 words
A composition according to claim 1 wherein the polymer is a halogenated polyester.
Claim 8
Dependent Claim 69 words
A composition according to claim 6 wherein the mixture (I) consists of (a) magnesium hydroxide, (b), alumina trihydrate and (c) a mixture of antimony trioxide and silica in the ratio of 1:3, the ratio of (a) to (b) to (c) being 6:3:1 and (I) being present in an amount sufficient to impart improved smoke resistance, there being employed 25 to 50 parts of (I) per 100 parts of polymer.
Claim 9
Dependent Claim 54 words
A composition according to claim 6 wherein the mixture (I) consists of magnesium hydroxide and alumina trihydrate and is present in an amount sufficient to impart improved smoke resistance, there being employed 5 to 100 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 2:1.
Claim 10
Dependent Claim 32 words
A composition according to claim 8 wherein there is employed 5 to 25 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 2:1.
Claim 11
Dependent Claim 30 words
A composition according to claim 9 wherein there is employed 5 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 1:2.
Claim 12
Dependent Claim 27 words
A composition according to claim 9 wherein there is employed 5 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being 2:1.
Claim 13
Dependent Claim 30 words
A composition according to claim 9 wherein there is employed 10 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 2:1.
Claim 14
Dependent Claim 18 words
A composition according to claim 12 wherein the ratio of (a) to (b) is from 1:2 to 2:1.
Claim 15
Dependent Claim 30 words
A composition according to claim 9 wherein there is employed 25 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 2:1.
Claim 16
Dependent Claim 18 words
A composition according to claim 14 wherein the ratio of (a) to (b) is from 1:2 to 2:1.
Claim 17
Dependent Claim 15 words
A composition according to claim 15 wherein the ratio of (a) to (b) is 1:2.
Claim 18
Dependent Claim 32 words
A composition according to claim 8 wherein there is employed 25 to 100 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 2:1.
Claim 19
Dependent Claim 32 words
A composition according to claim 17 wherein there is employed 50 to 100 parts of (I) per 100 parts ogf polymer, the ratio of (a) to (b) being from 1:2 to 2:1.
Claim 20
Dependent Claim 30 words
A composition according to claim 18 wherein there is employed 50 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 1:1 to 1:2.
Claim 21
Dependent Claim 15 words
A composition according to claim 19 wherein the ratio of (a) to (b) is 1:1.
Claim 22
Dependent Claim 19 words
A composition according to claim 18 wherein there is employed 100 parts of (I) per 100 parts of polymer.
Claim 23
Dependent Claim 15 words
A composition according to claim 21 wherein the ratio of (a) to (b) is 1:2.
Claim 24
Dependent Claim 15 words
A composition according to claim 21 wherein the ratio of (a) to (b) is 2:1.
Claim 25
Dependent Claim 54 words
A composition according to claim 1 wherein the polymer is a polyurethane and the mixture consists of magnesium hydroxide and alumina trihydrate and is present in an amount sufficient to impart improved smoke resistance, there being employed 50 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being 1:1.
Claim 26
Dependent Claim 14 words
A composition according to claim 1 wherein the polymer is a vinyl chloride polymer.
Claim 27
Dependent Claim 54 words
A composition according to claim 25 wherein the mixture (I) consists of magnesium hydroxide and alumina trihydrate and is present in an amount sufficient to impart improved smoke resistance, there being employed 4 to 50 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 2:1.
Claim 28
Dependent Claim 21 words
A composition according to claim 26 wherein there is employed 4 to 20 parts of (I) per 100 parts of polymer.
Claim 29
Dependent Claim 18 words
A composition according to claim 27 wherein the ratio of (a) to (b) is from 1:2 to 2:1.
Claim 30
Dependent Claim 21 words
A composition according to claim 28 wherein there is employed 5.8 to 11.5 parts of (I) per 100 parts of resin.
Claim 31
Dependent Claim 19 words
A composition according to claim 29 wherein there is employed 11.5 parts of (I) per 100 parts of resin.
Claim 32
Dependent Claim 15 words
A composition according to claim 30 wherein the ratio of (a) to (b) is 2:1.
Claim 33
Dependent Claim 15 words
A composition according to claim 27 wherein the ratio of (a) to (b) is 5:95.
Claim 34
Dependent Claim 54 words
A composition according to claim 25 wherein the mixture (I) consists of magnesium hydroxide and alumina trihydrate and is present in an amount sufficient to impart improved smoke resistance, there being employed 25 to 50 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 95:5 to 1:2.
Claim 35
Dependent Claim 18 words
A composition according to claim 33 wherein the ratio of (a) to (b0) is from 2:1 to 1:2.
Claim 36
Dependent Claim 26 words
A composition according to claim 33 wherein there is employed 25 parts of (I) and the ratio of (a) to (b) is from 95:5 to 2:1.
Claim 37
Dependent Claim 15 words
A composition according to claim 35 wherein the ratio of (a) to (b) is 2:1.
Claim 38
Dependent Claim 26 words
A composition according to claim 33 wherein there is employed 50 parts of (I) and the ratio of (a) to (b) is from 2:1 to 1:2.
Claim 39
Dependent Claim 15 words
A composition according to claim 37 wherein the ratio of (a) to (b) is 2:1.
Claim 40
Dependent Claim 15 words
A composition according to claim 38 wherein the ratio of (a) to (b) is 1:2.
Claim 41
Dependent Claim 54 words
A composition according to claim 25 whein the mixture (I) consists of magnesium hydroxide and alumina trihydrate and is present in an amount sufficient to impart improved flame resistance, there being employed 5.8 to 11.5 parts of (I) per 100 parts of polymer and the ratio of (a) to (b) being 5:95 to 95:5.
Claim 42
Dependent Claim 19 words
A composition according to claim 40 wherein there is employed 11.5 parts of (I) per 100 parts of polymer.
Claim 43
Dependent Claim 15 words
A composition according to claim 41 wherein the ratio of (a) to (b) is 2:1.
Claim 44
Dependent Claim 13 words
A composition according to claim 1 wherein the polymer is an epoxy resin.
Claim 45
Dependent Claim 54 words
A composition accordng to claim 43 wherein the mixture (I) consists of magnesium hydroxide and alumina trihydrate and is present in an amount sufficient to impart improved smoke resistance, there being employed 30 to 90 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 2:1.
Claim 46
Dependent Claim 18 words
A composition according to claim 44 wherein the ratio of (a) to (b) is from 5:95 to 1:2.
Claim 47
Dependent Claim 18 words
A composition according to claim 44 wherein the ratio of (a) to (b) is from 5:95 to 1:1.
Claim 48
Dependent Claim 21 words
A composition according to claim 44 wherein there is employed 75 to 90 parts of (I) per 100 parts of polymer.
Claim 49
Dependent Claim 28 words
A composition according to claim 47 wherein the ratio of (a) to (b) is 5:95 and there is employed 90 parts of (I) per 100 parts of polymer.
Claim 50
Dependent Claim 28 words
A composition according to claim 47 wherein there is employed 90 parts of (I) per 100 parts of polymer and the ratio of (a) to (b) is 1:1.
Claim 51
Dependent Claim 28 words
A composition according to claim 47 wherein there is employed 90 parts of (I) per 100 parts of polymer and the ratio of (a) to (b) is 1:1.
Claim 52
Dependent Claim 28 words
A composition according to claim 47 wherein there is employed 75 parts of (I) per 100 parts of polymer and the ratio of (a) to (b) is 5:95.
Claim 53
Dependent Claim 28 words
A composition according to claim 47 wherein there is employed 75 parts of (I) per 100 parts of polymer and the ratio of (a) to (b) is 1:1.
Claim 54
Dependent Claim 28 words
A composition according to claim 47 wherein there is employed 75 parts of (I) per 100 parts of polymer and the ratio of (a) to (b) is 2:1.
Claim 55
Dependent Claim 52 words
A composition according to claim 43 wherein the mixture (I) consists of magnesium hydroxide and alumina trihydrate and is present in an amount sufficient to impart improved smoke resistance, there being employed 10 parts of (I) per 100 parts of polymer, the ratio of (a) to (b) being from 5:95 to 1:1.
Claim 56
Dependent Claim 15 words
A composition according to claim 54 wherein the ratio of (a) to (b) is 5:95.
Claim 57
Dependent Claim 15 words
A composition according to claim 54 wherein the ratio of (a) to (b) is 1:1.
Claim 58
Dependent Claim 15 words
A composition according to claim 54 wherein the ratio of (a) to (b) is 1:2.

References Cited (Backward Citations)

GB1080468A Cited
US3816367A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-04-02 1982-10-02 1983-04-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-04-02 1986-10-02 1987-04-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-04-02 1990-10-02 1991-04-03 $7700.00 Window Closed / Lapsed

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