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US4147683A Expired / Lapsed US ⏱️ 0.0 years remaining

Fluorocarbon polymer-polymeric adjunct coating compositions stabilized against discoloration

Assignee: EIDP Inc
•
Filing: 1977-08-02
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Granted: 1979-04-03
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Expires: 1997-08-02
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Abstract

Abstract The discoloration of finishes derived from coating compositions containing (a) fluorocarbon polymer, along with (b) a polymeric adjunct, and (c) a liquid carrier, can be significantly reduced by adding to the composition, before it is applied, a compound which decomposes to an oxide or hydroxide of a particular metal.

Inventors

  • 👤 Eustathios Vassiliou
  • 👤 William Van Hoeven, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 09:08
CPC Classifications
C; C09; C09D; C09D127/00; C09D127/02; C09D127/12; C08; C08K; C08K3/00; C08K3/18; C08K3/20; C08K3/22; C08K3/28; C08K5/00; C08K5/0008; C08K5/0016; C08K5/04; C08K5/09; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/3154; Y10T428/31544; Y10T428/31678; Y10T428/31692

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 205 words
A composition suitable for making a light-colored fused fluorocarbon polymer coating, said composition consisting essentially of (a) about 25%-95%, by weight of the total of (a) and (b), of a fluorocarbon polymer polymerized or copolymerized from monomers selected from monoethylenically unsaturated hydrocarbon monomers and hydrocarbon ether monomers, said monomers being completely substituted with fluorine atoms or a combination of fluorine atoms and chlorine atoms, the polymer having a number average molecular weight of at least 20,000; (b) about 2%-75%, by weight of the total of (a), (b) and (c), of a polymer of ethylenically unsaturated monomers which depolymerizes, and whose depolymerization products vaporize in the temperature range of about 150° C. below the fusion temperature of the fluorocarbon polymer used to about the fluorocarbon polymer's decomposition temperature; the amounts of (a) and (b) totaling 100%; (c) enough of at least one compound of at least one of the metals ______________________________________ cobalt cerium iron and [bismuth] manganese ______________________________________ which compound decomposes in the temperature range of about 100° C.-500° C. to give at least 0.2%, by weight of the metal in the compound, of an oxide or hydroxide, to provide at least about 0.005 parts of metal per hundred of (a); and (d) a liquid carrier.
Claim 2
Dependent Claim 205 words
A composition suitable for making a light-colored fused fluorocarbon polymer coating, said composition consisting essentially of (a) about 25%-95%, by weight of the total of (a) and (b), of a fluorocarbon polymer polymerized or copolymerized from monomers selected from monoethylenically unsaturated hydrocarbon monomers and hydrocarbon ether monomers, said monomers being completely substituted with fluorine atoms or a combination of fluorine atoms and chlorine atoms, the polymer having a number average molecular weight of at least 20,000; (b) about 2%-75%, by weight of the total of (a), (b) and (c), of a polymer of ethylenically unsaturated monomers which depolymerizes, and whose depolymerization products vaporize in the temperature range of about 150° C. below the fusion temperature of the fluorocarbon polymer used to about the fluorocarbon polymer's decomposition temperature; the amounts of (a) and (b) totaling 100%; (c) enough of at least one compound of at least one of the metals ______________________________________ cobalt cerium iron and [bismuth] manganese ______________________________________ which compound decomposes in the temperature range of about 100° C.-500° C. to give at least 0.2%, by weight of the metal in the compound, of an oxide or hydroxide, to provide at least about 0.005 parts of metal per hundred of (a); and (d) a liquid carrier.
Claim 3
Dependent Claim 14 words
The composition of claim 1 wherein the polymer in (a) is a perfluoroolefin polymer.
Claim 4
Dependent Claim 11 words
The composition of claim 2 wherein the perfluoroolefin polymer is polytetrafluoroethylene.
Claim 5
Dependent Claim 13 words
The composition of claim 3 wherein the compound in (c) is of cerium.
Claim 6
Dependent Claim 23 words
The composition of claim 4 wherein the cerium compound is a cerium nitrate, or a salt of cerium hydroxide and an organic acid.
Claim 7
Dependent Claim 10 words
The composition of claim 5 wherein the carrier is water.
Claim 8
Dependent Claim 12 words
An article bearing a fused coating of the composition of claim 1.
Claim 9
Dependent Claim 12 words
An article bearing a fused coating of the composition of claim 2.
Claim 10
Dependent Claim 12 words
An article bearing a fused coating of the composition of claim 3.
Claim 11
Dependent Claim 12 words
An article bearing a fused coating of the composition of claim 4.
Claim 12
Dependent Claim 12 words
An article bearing a fused coating of the composition of claim 5.
Claim 13
Dependent Claim 12 words
An article bearing a fused coating of the composition of claim 6.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-04-02 1982-10-02 1983-04-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-04-02 1986-10-02 1987-04-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-04-02 1990-10-02 1991-04-03 $7700.00 Window Closed / Lapsed

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