US4146658A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for producing an ultraviolet light stabilized polycarbonate article
Assignee: General Electric Co
•
Filing: 1978-04-12
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Granted: 1979-03-27
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Expires: 1998-04-12
Abstract
Abstract A process for preparing an ultraviolet light resistant polycarbonate article, which process comprises a surface impregnation of the article by bringing said article into contact with a composition containing (i) an acrylate, (ii) a hydroxy ether, and (iii) an ultraviolet light absorbent.
Inventors
- 👤 James S. Humphrey
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 20:48
CPC Classifications
C; C08; C08J; C08J7/00; C08J7/02; C08J7/04; C08J7/06; C08J7/065; C08J2369/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
243 words
A process for the manufacture of an aromatic polycarbonate article having improved resistance to degradation by ultraviolet light which comprises the steps of: I contacting said article with an impregnating solution containing (i) an ester of acrylic acid represented by the formula CH.sub.2 ═ CHCOOR wherein R is an alkyl containing from 1 to about 8 carbon atoms, (ii) a hydroxy ether represented by the general formula HO--R'--O--R.sup.2 wherein R' is selected from the group consisting of --CH 2 CH 2 --, --C 3 H 6 --, and --R 3 O) n wherein R 3 is --C 2 H 2 -- or --C 3 H 6 -- and n is an integer having a value of from 1 to 3, and R 2 is an alkyl containing from 1 to about 8 carbon atoms, and (iii) an ultraviolet light absorbent, said impregnating solution containing amounts of said ester of acrylic acid and hydroxy ether effective to sufficiently modify the surface of said polycarbonate to effectuate impregnation thereof by said ultraviolet light absorbent but insufficient to substantially deleteriously affect said polycarbonate; II keeping said impregnating solution in contact with said article for a period of time sufficient for said ultraviolet light absorbent to impregnate the surface of said article but insufficient to substantially deleteriously affect the surface of said polycarbonate article; and III removing said impregnating solution containing said ester of acrylic acid, hydroxy ether, and any unabsorbed ultraviolet light absorbent from said article.
Claim 2
Dependent Claim
243 words
A process for the manufacture of an aromatic polycarbonate article having improved resistance to degradation by ultraviolet light which comprises the steps of: I contacting said article with an impregnating solution containing (i) an ester of acrylic acid represented by the formula CH.sub.2 ═ CHCOOR wherein R is an alkyl containing from 1 to about 8 carbon atoms, (ii) a hydroxy ether represented by the general formula HO--R'--O--R.sup.2 wherein R' is selected from the group consisting of --CH 2 CH 2 --, --C 3 H 6 --, and --R 3 O) n wherein R 3 is --C 2 H 2 -- or --C 3 H 6 -- and n is an integer having a value of from 1 to 3, and R 2 is an alkyl containing from 1 to about 8 carbon atoms, and (iii) an ultraviolet light absorbent, said impregnating solution containing amounts of said ester of acrylic acid and hydroxy ether effective to sufficiently modify the surface of said polycarbonate to effectuate impregnation thereof by said ultraviolet light absorbent but insufficient to substantially deleteriously affect said polycarbonate; II keeping said impregnating solution in contact with said article for a period of time sufficient for said ultraviolet light absorbent to impregnate the surface of said article but insufficient to substantially deleteriously affect the surface of said polycarbonate article; and III removing said impregnating solution containing said ester of acrylic acid, hydroxy ether, and any unabsorbed ultraviolet light absorbent from said article.
Claim 3
Dependent Claim
20 words
The process of claim 1 wherein said ultraviolet light absorbent is selected from the group consisting of benzophenones, and benzotriazoles.
Claim 4
Dependent Claim
38 words
A process of claim 5 wherein the impregnating solution contains from about 1 to about 50 volume percent of the acrylate swellng agent and from about 50 to about 99 volume percent of the hydroxy ether mitigating agent.
Claim 5
Dependent Claim
13 words
The process of claim 2 wherein said ester of acrylic acid is butylacrylate.
Claim 6
Dependent Claim
11 words
The process of claim 4 wherein said hydroxy ether is 2-butoxyethanol.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-03-26 | 1982-09-25 | 1983-03-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-03-26 | 1986-09-25 | 1987-03-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-03-26 | 1990-09-25 | 1991-03-27 | $7700.00 | Window Closed / Lapsed |