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US4146586A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester/substantially amorphous polyolefin hot-melt adhesive blends

Assignee: Eastman Chemical Co
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Filing: 1977-07-06
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Granted: 1979-03-27
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Expires: 1997-07-06
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Abstract

Abstract This invention relates to blends of polyesters and substantially amorphous polyolefins such as amorphous polypropylene. Even small amounts of substantially amorphous polypropylene (5-10 weight percent) substantially lowers the melt viscosity of polyesters at application temperatures and reduces the temperature required for application of the adhesive blend without deleteriously affecting the bond strengths normally achieved on many substrates including fabrics, plastics, and metals. Blends of polyesters and 5-10% substantially amorphous polyolefins are also non-tacky and can be pelletized and used as pellets without difficulty.

Inventors

  • 👤 Richard L. McConnell
  • 👤 Jimmy R. Trotter
  • 👤 Frederick B. Joyner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 18:55
CPC Classifications
C; C09; C09J; C09J167/00; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/04

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 213 words
An adhesive composition capable of being used as a hot melt adhesive comprising a blend of about 1 to 20 percent by weight of at least one substantially amorphous polyolefin and at least one polyester having a heat of fusion of about 1 to about 12 calories per gram, a melting point within the range of about 80° C. to 225° C., and an inherent viscosity of at least 0.5 as measured at 25° C., using 0.50 gram of polyester per 100 ml. of a solvent consisting of 60 percent by volume phenol and 40 percent by volume tetrachloroethane, wherein said substantially amorphous polyolefin is a member of the group selected from substantially amorphous homopolymers of 1-olefins containing 3 to 5 carbon atoms, substantially amorphous copolymers prepared from ethylene and 1-olefins containing 3 to 5 carbon atoms, substantially amorphous copolymers prepared from propylene and 1-butene, substantially amorphous copolymers prepared from amorphous propylene and a higher 1-olefin containing less than 65 mole percent of at least one higher 1-olefin of the group consisting of 1-hexene, 1-heptene, 1-octene, 1-nonene and 1-decene, and substantially amorphous copolymers prepared from 1-butene and a higher 1-olefin containing less than 65 mole percent of at least one higher 1-olefin of the group consisting of 1-hexene, 1-heptene, 1-octene, 1-nonene and 1-decene.
Claim 2
Dependent Claim 213 words
An adhesive composition capable of being used as a hot melt adhesive comprising a blend of about 1 to 20 percent by weight of at least one substantially amorphous polyolefin and at least one polyester having a heat of fusion of about 1 to about 12 calories per gram, a melting point within the range of about 80° C. to 225° C., and an inherent viscosity of at least 0.5 as measured at 25° C., using 0.50 gram of polyester per 100 ml. of a solvent consisting of 60 percent by volume phenol and 40 percent by volume tetrachloroethane, wherein said substantially amorphous polyolefin is a member of the group selected from substantially amorphous homopolymers of 1-olefins containing 3 to 5 carbon atoms, substantially amorphous copolymers prepared from ethylene and 1-olefins containing 3 to 5 carbon atoms, substantially amorphous copolymers prepared from propylene and 1-butene, substantially amorphous copolymers prepared from amorphous propylene and a higher 1-olefin containing less than 65 mole percent of at least one higher 1-olefin of the group consisting of 1-hexene, 1-heptene, 1-octene, 1-nonene and 1-decene, and substantially amorphous copolymers prepared from 1-butene and a higher 1-olefin containing less than 65 mole percent of at least one higher 1-olefin of the group consisting of 1-hexene, 1-heptene, 1-octene, 1-nonene and 1-decene.
Claim 3
Dependent Claim 15 words
An adhesive composition according to claim 1 wherein said substantially amorphous polyolefin is amorphous polypropylene.
Claim 4
Dependent Claim 16 words
An adhesive composition according to claim 1 wherein said substantially amorphous polyolefin is amorphous poly 1-butene.
Claim 5
Dependent Claim 16 words
An adhesive composition according to claim 1 wherein said substantially amorphous polyolefin is amorphous poly 1-pentene.
Claim 6
Dependent Claim 29 words
An adhesive composition according to claim 1 wherein said substantially amorphous polyolefin is at least one amorphous copolymer prepared from ethylene and 1-olefins containing 3 to 5 carbon atoms.
Claim 7
Dependent Claim 44 words
An adhesive composition according to claim 1 wherein said substantially amorphous polyolefin is at least one amorphous propylene/higher 1-olefin copolymer containing less than 65 mole percent of at least one higher 1-olefin of the group consisting essentially of 1-hexene, 1-heptene, 1-octene, 1-nonene and 1-decene.
Claim 8
Dependent Claim 18 words
An adhesive composition according to claim 1 wherein said substantially amorphous polyolefin is at least one propylene/1-butene copolymer.

References Cited (Backward Citations)

US3397169A Cited
US3657389A Cited
US3728212A Cited
US3923726A Cited
US3701760A Cited
US3970709A Cited
US3980735A Cited
US3969294A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-03-26 1982-09-25 1983-03-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-03-26 1986-09-25 1987-03-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-03-26 1990-09-25 1991-03-27 $7700.00 Window Closed / Lapsed

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