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US4146387A Expired / Lapsed US ⏱️ 0.0 years remaining

Synergistic herbicidal compositions

Assignee: Zeneca Inc
•
Filing: 1977-11-25
•
Granted: 1979-03-27
•
Expires: 1997-11-25
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Abstract

Abstract Synergistic herbicidal activity is displayed by compositions comprising the following two components:

Inventors

  • 👤 Gerald H. Thiele

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 17:05
CPC Classifications
A; A01; A01N; A01N39/00; A01N39/02

Claims Analysis

Total Claims: 28
Claim 1
Independent Claim 168 words
A synergistic herbicidal composition comprising a mixture of (1) a herbicidally effective amount of an amide of the formula ##STR8## in which R 1 is substituted phenyl, with one to three substituents independently selected from the group consisting of chlorine, bromine, iodine, or C 1 -C 4 alkyl, R 2 , r 3 , and R 4 are independently C 1 -C 4 alkyl, and R 5 is hydrogen or C 1 -C 4 alkyl, and (2) a herbicidally effective amount of a haloacetanilide of the formula ##STR9## in which R 6 and R 7 are independently selected from the group consisting of hydrogen and C 1 -C 6 alkyl, R 8 is a member selected from the group consisting of C 1 -C 6 alkyl and -R 9 -O-R 10 , in which R 9 is C 1 -C 3 alkylene and R 10 is C 1 -C 3 alkyl, and X is chlorine, bromine, or iodine, in a weight ratio of amide to haloacetanilide of 0.01-10:1.
Claim 2
Dependent Claim 168 words
A synergistic herbicidal composition comprising a mixture of (1) a herbicidally effective amount of an amide of the formula ##STR8## in which R 1 is substituted phenyl, with one to three substituents independently selected from the group consisting of chlorine, bromine, iodine, or C 1 -C 4 alkyl, R 2 , r 3 , and R 4 are independently C 1 -C 4 alkyl, and R 5 is hydrogen or C 1 -C 4 alkyl, and (2) a herbicidally effective amount of a haloacetanilide of the formula ##STR9## in which R 6 and R 7 are independently selected from the group consisting of hydrogen and C 1 -C 6 alkyl, R 8 is a member selected from the group consisting of C 1 -C 6 alkyl and -R 9 -O-R 10 , in which R 9 is C 1 -C 3 alkylene and R 10 is C 1 -C 3 alkyl, and X is chlorine, bromine, or iodine, in a weight ratio of amide to haloacetanilide of 0.01-10:1.
Claim 3
Dependent Claim 28 words
A composition according to claim 1 in which R 1 is substituted phenyl, with one to three substituents independently selected from the group consisting of chlorine and methyl.
Claim 4
Dependent Claim 14 words
A composition according to claim 1 in which R 1 is 3,5-dichlorophenyl or 3,5-dimethylphenyl.
Claim 5
Dependent Claim 11 words
A composition according to claim 1 in which X is chlorine.
Claim 6
Dependent Claim 19 words
A composition according to claim 1 in which said amide is N-(1,1-dimethyl-2-butynyl)-α-(3,5-dichlorophenoxy) butyramide and said haloacetanilide is N-[(3'-methoxypropyl-(2)]2-methyl-6-ethyl chloroacetanilide.
Claim 7
Dependent Claim 19 words
A composition according to claim 1 in which said amide is N-(1,1-dimethyl-2-butynyl)-α-(3,5-dichlorophenoxy) butyramide and said haloacetamide is N-methoxymethyl-2,6-diethyl chloroacetanilide.
Claim 8
Dependent Claim 19 words
A composition according to claim 1 in which said amide is N-(1,1-dimethyl-2-butynyl)-α-(3,5-dichlorophenoxy) butyramide and said haloacetamide is N-isopropyl chloroacetanilide.
Claim 9
Dependent Claim 20 words
A composition according to claim 1 in which said amide is N-(1,1-dimethyl-2-butynyl)-α-(3,5-dimethylphenoxy) butyramide and said haloacetanilide is N-[3'-methoxy propyl-(2)]-2-methyl-6-ethyl chloroacetanilide.
Claim 10
Dependent Claim 19 words
A composition according to claim 1 in which said amide is N-(1,1-dimethyl-2-butynyl)-α-(3,5-dimethylphenoxy) butyramide and said haloacetanilide is N-methoxymethyl-2,6-diethyl chloroacetanilide.
Claim 11
Dependent Claim 19 words
A composition according to claim 1 in which said amide is N-(1,1-dimethyl-2-butynyl)-α-(3,5-dimethylphenoxy) butyramide and said haloacetanilide is N-isopropyl chloroacetanilide.
Claim 12
Dependent Claim 19 words
A composition according to claim 1 in which said amide is N-(1,1-dimethyl-2-propynyl)-α-(3,5-dichlorophenoxy) butyramide and said haloacetanilide is N-[3'-methoxypropyl-(2)]-2-methyl-6-ethyl chloroacetanilide.
Claim 13
Dependent Claim 19 words
A composition according to claim 1 in which said amide is N-(1,1-dimethyl-2-propynyl)-α-(3,5-dichlorophenoxy) butyramide and said haloacetanilide is N-methoxymethyl-2,6-diethyl chloroacetanilide.
Claim 14
Dependent Claim 19 words
A composition according to claim 1 in which said amide is N-(1,1-dimethyl-2-propynyl)-α-(3,5-dichlorophenoxy) butyramide and said haloacetanilide is N-isopropyl chloroacetanilide.
Claim 15
Independent Claim 184 words
A method of controlling undesired vegetation which comprises applying to the locus where control is desired a synergistic herbicidal composition comprising a mixture of (1) a herbicidally effective amount of an amide of the formula ##STR10## in which R 1 is substituted phenyl, with one to three substituents independently selected from the group consisting of chlorine, bromine, iodine, or C 1 -C 4 alkyl, R 2 , r 3 , and R 4 are independently C 1 -C 4 alkyl, and R 5 is hydrogen or C 1 -C 4 alkyl, and (2) a herbicidally effective amount of a haloacetanilide of the formula ##STR11## in which R 6 and R 7 are independently selected from the group consisting of hydrogen and C 1 -C 6 alkyl, R 8 is a member selected from the group consisting of C 1 -C 6 alkyl and -R 9 -O-R 10 , in which R 9 is C 1 -C 3 alkylene and R 10 is C 1 -C 3 alkyl, and X is chlorine, bromine, or iodine, in a weight ratio of amide to haloacetanilide of 0.01-10:1.
Claim 16
Independent Claim 184 words
A method of controlling undesired vegetation which comprises applying to the locus where control is desired a synergistic herbicidal composition comprising a mixture of (1) a herbicidally effective amount of an amide of the formula ##STR10## in which R 1 is substituted phenyl, with one to three substituents independently selected from the group consisting of chlorine, bromine, iodine, or C 1 -C 4 alkyl, R 2 , r 3 , and R 4 are independently C 1 -C 4 alkyl, and R 5 is hydrogen or C 1 -C 4 alkyl, and (2) a herbicidally effective amount of a haloacetanilide of the formula ##STR11## in which R 6 and R 7 are independently selected from the group consisting of hydrogen and C 1 -C 6 alkyl, R 8 is a member selected from the group consisting of C 1 -C 6 alkyl and -R 9 -O-R 10 , in which R 9 is C 1 -C 3 alkylene and R 10 is C 1 -C 3 alkyl, and X is chlorine, bromine, or iodine, in a weight ratio of amide to haloacetanilide of 0.01-10:1.
Claim 17
Dependent Claim 28 words
A method according to claim 14 in which R 1 is substituted phenyl, with one to three substituents independently selected from the group consisting of chlorine and methyl.
Claim 18
Dependent Claim 14 words
A method according to claim 14 in which R 1 is 3,5-dichlorophenyl or 3,5-dimethylphenyl.
Claim 19
Dependent Claim 11 words
A method according to claim 14 in which X is chlorine.
Claim 20
Dependent Claim 20 words
A method according to claim 14 in which said amide is N-(1,1-dimethyl-2-butynyl)-α-(3,5-dichlorophenoxy) butyramide and said haloacetanilide is N-[3'-methoxypropyl -(2)]-2-methyl-6-ethyl chloroacetanilide.
Claim 21
Dependent Claim 19 words
A method according to claim 14 in which said amide is N-(1,1-dimethyl-2-butynyl)-α-(3,5-dichlorophenoxy) butyramide and said haloacetanilide is N-methoxymethyl-2,6-diethyl chloroacetanilide.
Claim 22
Dependent Claim 19 words
A method according to claim 14 in which said amide is N-(1,1-dimethyl-2-butynyl)-α-(3,5-dichlorophenoxy) butyramide and said haloacetanilide is N-isopropyl chloroacetanilide.
Claim 23
Dependent Claim 19 words
A method according to claim 14 in which said amide is N-(1,1-dimethyl-2-butynyl)-α-(3,5-dimethylphenoxy) butyramide and said haloacetanilide is N-[3'-methoxypropyl-(2)]-2-methyl-6-ethyl chloroacetanilide.
Claim 24
Dependent Claim 19 words
A method according to claim 14 in which said amide is N-(1,1-dimethyl-2-butynyl)-α-(3,5-dimethylphenoxy) butyramide and said haloacetanilide is N-methoxymethyl-2,6-diethyl chloroacetanilide.
Claim 25
Dependent Claim 19 words
A method according to claim 14 in which said amide is N-(1,1-dimethyl-2-butynyl)-α-(3,5-dimethylphenoxy) butyramide and said haloacetanilide is N-isopropyl chloroacetanilide.
Claim 26
Dependent Claim 19 words
A method according to claim 14 in which said amide is N-(1,1-dimethyl-2-propynyl)-α-(3,5-dichlorophenoxy) butyramide and said haloacetanilide is N-[3'-methoxypropyl-(2)]-2-methyl-6-ethyl chloroacetanilide.
Claim 27
Dependent Claim 19 words
A method according to claim 14 in which said amide is N-(1,1-dimethyl-2-propynyl)-α-(3,5-dichlorophenoxy) butyramide and said haloacetanilide is N-methoxymethyl-2,6-diethyl chloroacetanilide.
Claim 28
Dependent Claim 19 words
A method according to claim 14 in which said amide is N-(1,1-dimethyl-2-propynyl)-α-(3,5-dichlorophenoxy) butyramide and said haloacetanilide is N-isopropyl chloroacetanilide.

References Cited (Backward Citations)

US3272844A Cited
US3457156A Cited
US3557209A Cited
US3547620A Cited
US4022611A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-03-26 1982-09-25 1983-03-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-03-26 1986-09-25 1987-03-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-03-26 1990-09-25 1991-03-27 $7700.00 Window Closed / Lapsed

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