Patent US1290111A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4145428A Expired / Lapsed US ⏱️ 0.0 years remaining

Fungicidally active 2-acyloxy-1-phenoxy-1-(1,2,4-triazolyl)-3,3-dimethyl-butanes

Assignee: Bayer AG
•
Filing: 1976-12-21
•
Granted: 1979-03-20
•
Expires: 1996-12-21
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract 1-Phenoxy-1-(1,2,4-triazolyl)-3,3-dimethyl-butanes of the formula ##STR1## in which R represents alkyl, alkenyl, alkynyl, cycloalkyl, halogenoalkyl, optionally substituted phenyl, optionally substituted phenoxyalkyl, alkylamino, dialkylamino or optionally substituted phenylamino, X represents halogen, alkyl, cycloalkyl, alkoxy, halogenoalkyl, alkylthio, alkoxycarbonyl, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl, amino, cyano or nitro, N represents 0, 1, 2, 3, 4 or 5, and Az represents the 1,2,4-triazolyl-1 or the 1,2,4-triazolyl-4 radical, In the form of the free base, a salt with a physiologically tolerated acid or a complex with a metal salt, which possess fungicidal properties.

Inventors

  • 👤 Wolfgang Kramer
  • 👤 Karl H. Buchel
  • 👤 Wilhelm Brandes
  • 👤 Paul-Ernst Frohberger

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 02:45
CPC Classifications
C; C07; C07D; C07D231/00; C07D231/02; C07D231/10; C07D231/12; C07D233/00; C07D233/54; C07D233/56; C07D249/00; C07D249/02; C07D249/08

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 289 words
A 2-acyloxy-1-phenoxy-1-(1,2,4-triazolyl)-3,3-dimethyl-butane of the formula ##STR124## in which R represents straight-chain or branched alkyl with 1 to 8 carbon atoms, straight-chain or branched alkenyl or alkynyl, each with 2 to 4 carbon atoms, halogenoalkyl with 1 to 2 carbon atoms and 1 to 5 halogen atoms, cycloalkyl with 5 to 7 carbon atoms, or optionally substituted phenyl or phenoxyalkyl which is optionally substituted in the phenyl part and has up to 2 carbon atoms in the alkyl part, in either case the substituents being selected from halogens, amino, cyano, nitro and alkyl with 1 or 2 carbon atoms, or alkyl-amino or dialkylamino with 1 to 4 carbon atoms in each alkyl part, or phenylamino which may optionally be substituted by halogen, nitro or cyano; X represents halogen, amino, cyano, nitro, straight-chain or branched alkyl with up to 4 carbon atoms, cycloalkyl with 5 to 7 carbon atoms, halogenoalkyl with up to 2 carbon atoms and up to 5 halogen atoms, alkoxy-carbonyl with a total of up to 5 carbon atoms, alkoxy or alkylthio each with up to 2 carbon atoms, phenyl or phenoxy, either of which may optionally carry one or more substituents selected from halogens, amino, cyano, nitro and alkyl with 1 to 2 carbon atoms, or phenylalkyl with 1 or 2 carbon atoms in the alkyl part, in which alkylcarbonyloxy with a total of up to 3 carbon atoms may be a substituent in the alkyl part and halogen, nitro or cyano may be a substituent in the phenyl part, n represents 0, 1, 2 or 3, and Az represents the 1,2,4-triazolyl-1 or the 1,2,4-triazolyl-4 radical, in the form of the free base, a salt with a physiologically tolerated acid or a complex with a metal salt.
Claim 2
Dependent Claim 289 words
A 2-acyloxy-1-phenoxy-1-(1,2,4-triazolyl)-3,3-dimethyl-butane of the formula ##STR124## in which R represents straight-chain or branched alkyl with 1 to 8 carbon atoms, straight-chain or branched alkenyl or alkynyl, each with 2 to 4 carbon atoms, halogenoalkyl with 1 to 2 carbon atoms and 1 to 5 halogen atoms, cycloalkyl with 5 to 7 carbon atoms, or optionally substituted phenyl or phenoxyalkyl which is optionally substituted in the phenyl part and has up to 2 carbon atoms in the alkyl part, in either case the substituents being selected from halogens, amino, cyano, nitro and alkyl with 1 or 2 carbon atoms, or alkyl-amino or dialkylamino with 1 to 4 carbon atoms in each alkyl part, or phenylamino which may optionally be substituted by halogen, nitro or cyano; X represents halogen, amino, cyano, nitro, straight-chain or branched alkyl with up to 4 carbon atoms, cycloalkyl with 5 to 7 carbon atoms, halogenoalkyl with up to 2 carbon atoms and up to 5 halogen atoms, alkoxy-carbonyl with a total of up to 5 carbon atoms, alkoxy or alkylthio each with up to 2 carbon atoms, phenyl or phenoxy, either of which may optionally carry one or more substituents selected from halogens, amino, cyano, nitro and alkyl with 1 to 2 carbon atoms, or phenylalkyl with 1 or 2 carbon atoms in the alkyl part, in which alkylcarbonyloxy with a total of up to 3 carbon atoms may be a substituent in the alkyl part and halogen, nitro or cyano may be a substituent in the phenyl part, n represents 0, 1, 2 or 3, and Az represents the 1,2,4-triazolyl-1 or the 1,2,4-triazolyl-4 radical, in the form of the free base, a salt with a physiologically tolerated acid or a complex with a metal salt.
Claim 3
Dependent Claim 16 words
A compound according to claim 1 wherein such compound is 2-acetoxy-1-(4-chlorophenoxy)-1- 1,2,4-triazolyl-(1)!-3,3-dimethyl-butane of the formula ##STR125##
Claim 4
Dependent Claim 16 words
The compound according to claim 1 wherein such compound is 2-acetoxy-1-(2,4-dichlorophenoxy)-1- 1,2,4-triazolyl-(1)!-3,3-dimethyl-butane of the formula ##STR126##
Claim 5
Dependent Claim 16 words
The compound according to claim 1 wherein such compound is 2-acetoxy-1-(4-diphenoxy)-1- 1,2,4-triazolyl-(1)!-3,3-dimethyl-butane of the formula ##STR127##
Claim 6
Dependent Claim 16 words
The compound according to claim 1 wherein such compound is 2-methylcarbamoyloxy-1-(4-diphenoxy)-1- 1,2,4-triazolyl-(1)!-3,3-dimethyl-butane of the formula ##STR128##
Claim 7
Dependent Claim 16 words
A compound according to claim 1 wherein such compound is 2-acetoxy-1-(4-bromophenoxy)-1- 1,2,4-triazolyl-(1)!-3,3-dimethyl-butane of the formula ##STR129##
Claim 8
Dependent Claim 23 words
A fungicidal composition containing as active ingredient a fungicidally effective amount of a compound according to claim 1 in admixture with a diluent.
Claim 9
Dependent Claim 27 words
A method of combating fungi which comprises applying to the fungi, or to a habitat thereof, a fungicidally effective amount of a compound according to claim 1.
Claim 10
Dependent Claim 22 words
The method according to claim 8 in which said compound is: 2-acetoxy-1-(4-chlorophenoxy)-1- 1,2,4-triazolyl-(1)!-3,3-dimethyl-butane; 2-acetoxy-1-(2,4-dichlorophenoxy)-1- 1,2,4-triazolyl-(1)!-3,3-dimethyl-butane; 2-acetoxy-1-(4-diphenoxy)-1- 1,2,4-triazolyl-(1)!-3,3-dimethyl-butane; 2-methylcarbamoyloxy-1-(4-diphenoxy)-1- 1,2,4-triazolyl-(1)!-3,3-dimethyl-butane; or 2-acetoxy-1-(4-bromophenoxy)-1- 1,2,4-triazolyl(1)!-3,3-dimethyl-butane.

References Cited (Backward Citations)

CH500663A Cited
US3952002A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-03-19 1982-09-18 1983-03-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-03-19 1986-09-18 1987-03-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-03-19 1990-09-18 1991-03-20 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag