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US4144216A Expired / Lapsed US ⏱️ 0.0 years remaining

Room temperature vulcanizable organic solvent dispersions of silicone elastomers

Assignee: Dow Silicones Corp
•
Filing: 1975-05-19
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Granted: 1979-03-13
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Expires: 1995-05-19
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Abstract

Abstract A mixture of a hydroxyl endblocked polydimethylsiloxane, ethylpolysilicate, monoorganotriacetoxysilane, organotin carboxylate, an extending filler and organic solvent provides dispersions which cure to silicone elastomers at room temperature. These compositions have long storage life and can be made into compositions which are storable for extended periods of time in a single container if kept under substantially anhydrous conditions. These compositions can be prepared extrudable or sprayable, are pigmentable, have high strengths, and are readily prepared.

Inventors

  • 👤 William H. Clark
  • 👤 Charles E. Skinner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 04:03
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08K; C08K5/00; C08K5/0008; C08K5/0016; C08K5/54; C08K5/56; C08K5/57; C08L83/02; C08G; C08G77/00; C08G77/02; C08G77/04; C08G77/14; C08G77/16

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 204 words
A silicone elastomeric composition obtained by mixing ingredients consisting essentially of (A) 100 parts by weight of a benzene soluble hydroxyl endblocked polydimethylsiloxane having a viscosity of at least 100,000 cps. at 25° C. (b) from 5 to 75 parts by weight of a soluble ethylpolysilicate, (C) from 1 to 20 parts by weight of monoorganotriacetoxysilane wherein the organic radical is an alkyl radical of less than four carbon atoms, (D) from 0.1 to 2 parts by weight of organotin carboxylate, (E) from 10 to 150 parts by weight of an extending filler, and (F) sufficient organic solvent to provide a solvent content of from 10 to 95 weight percent solvent based on the total weight of the composition, said organic solvent being selected from the group consisting of aliphatic hydrocarbons, chlorinated aliphatic hydrocarbons, aromatic hydrocarbons, ketones, esters, ethers and mixtures thereof wherein said organic solvent is a solvent for the silicon containing species and alcohol does not exceed 40 weight percent of the total solvent, the combined parts by weight of (B) and (C) being from 8 to 80 parts by weight based on 100 parts by weight of (A) and the weight ratio of (B) to (C) being from 0.6 to 40.
Claim 2
Dependent Claim 204 words
A silicone elastomeric composition obtained by mixing ingredients consisting essentially of (A) 100 parts by weight of a benzene soluble hydroxyl endblocked polydimethylsiloxane having a viscosity of at least 100,000 cps. at 25° C. (b) from 5 to 75 parts by weight of a soluble ethylpolysilicate, (C) from 1 to 20 parts by weight of monoorganotriacetoxysilane wherein the organic radical is an alkyl radical of less than four carbon atoms, (D) from 0.1 to 2 parts by weight of organotin carboxylate, (E) from 10 to 150 parts by weight of an extending filler, and (F) sufficient organic solvent to provide a solvent content of from 10 to 95 weight percent solvent based on the total weight of the composition, said organic solvent being selected from the group consisting of aliphatic hydrocarbons, chlorinated aliphatic hydrocarbons, aromatic hydrocarbons, ketones, esters, ethers and mixtures thereof wherein said organic solvent is a solvent for the silicon containing species and alcohol does not exceed 40 weight percent of the total solvent, the combined parts by weight of (B) and (C) being from 8 to 80 parts by weight based on 100 parts by weight of (A) and the weight ratio of (B) to (C) being from 0.6 to 40.
Claim 3
Dependent Claim 59 words
The silicone elastomeric composition according to claim 1 in which (B) is present in an amount of from 15 to 40, (C) is present in an amount of from 4 to 10, the combined parts by weight of (B) and (C) are from 19 to 50 and the weight ratio of (B) to (C) is from 2.5 to 10.
Claim 4
Dependent Claim 59 words
The silicone elastomeric composition according to claim 2 in which (B) is present in an amount of from 20 to 30, (C) is present in an amount of from 6 to 10, the combined parts by weight of (B) and (C) are from 26 to 40 and the weight ratio of (B) to (C) is from 2.5 to 5.
Claim 5
Dependent Claim 22 words
The silicone elastomeric composition according to claim 1 in which (A) has a viscosity of at least 1,000,000 cps. at 25° C.
Claim 6
Dependent Claim 22 words
The silicone elastomeric composition according to claim 2 in which (A) has a viscosity of at least 1,000,000 cps. at 25° C.
Claim 7
Dependent Claim 22 words
The silicone elastomeric composition according to claim 3 in which (A) has a viscosity of at least 1,000,000 cps. at 25° C.
Claim 8
Dependent Claim 33 words
The silicone elastomeric composition according to claim 1 in which the organic solvent is present in an amount of from 40 to 60 weight percent based on the total weight of the composition.
Claim 9
Dependent Claim 33 words
The silicone elastomeric composition according to claim 5 in which the organic solvent is present in an amount of from 40 to 60 weight percent based on the total weight of the composition.
Claim 10
Dependent Claim 21 words
The silicone elastomeric composition according to claim 1 in which the monoorganotriacetoxysilane of (C) is a mixture of methyltriacetoxysilane and ethyltriacetoxysilane.
Claim 11
Dependent Claim 21 words
The silicone elastomeric composition according to claim 8 in which the monoorganotriacetoxysilane of (C) is a mixture of methyltriacetoxysilane and ethyltriacetoxysilane.

References Cited (Backward Citations)

US2927907A Cited
US3133891A Cited
US3305502A Cited
US3308080A Cited
US3642692A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-03-12 1982-09-11 1983-03-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-03-12 1986-09-11 1987-03-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-03-12 1990-09-11 1991-03-13 $7700.00 Window Closed / Lapsed

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