US4142986A
Expired / Lapsed
US
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Glasses suitable for laser application
Assignee: Schott Optical Glass Inc
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Filing: 1978-04-20
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Granted: 1979-03-06
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Expires: 1998-04-20
Abstract
Abstract Disclosed are phosphorus glasses containing beryllium and fluorine and Nd 3+ as the active lasing species.
Inventors
- 👤 Charles F. Rapp
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 12:17
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/12; C03C3/23; C03C3/247; C03C4/00; C03C4/0071
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
187 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.h Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , neodymium is present in a laseable amount up to m = 0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2 total for all A atoms, k is 0.15 to 0.3 l is zero to 0.1, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 2
Dependent Claim
187 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.h Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , neodymium is present in a laseable amount up to m = 0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2 total for all A atoms, k is 0.15 to 0.3 l is zero to 0.1, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 3
Dependent Claim
157 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein neodymium is present in a laseable amount up to m=0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2, k is 0.15 to 0.3, l is zero to 0.1, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 4
Dependent Claim
157 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein neodymium is present in a laseable amount up to m=0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2, k is 0.15 to 0.3, l is zero to 0.1, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 5
Dependent Claim
182 words
A glass composition suitable for , K as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.H 38 Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2 total for all A atoms, k is 0.15 to 0.3 l is zero to 0.1, m is 0.0001 to 0.015, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statolts) 2
Claim 6
Dependent Claim
182 words
A glass composition suitable for , K as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.H 38 Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2 total for all A atoms, k is 0.15 to 0.3 l is zero to 0.1, m is 0.0001 to 0.015, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statolts) 2
Claim 7
Dependent Claim
152 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2, k is 0.15 to 0.3, m is 0.0001 to 0.015, l is zero to 0.1, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 8
Dependent Claim
152 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2, k is 0.15 to 0.3, m is 0.0001 to 0.015, l is zero to 0.1, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 9
Dependent Claim
187 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.h Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , neodymium is present in a laseable amount up to m = 0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25 total for all A atoms, k is 0.1 to 0.35, l is zero to 0.15, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 10
Dependent Claim
187 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.h Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , neodymium is present in a laseable amount up to m = 0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25 total for all A atoms, k is 0.1 to 0.35, l is zero to 0.15, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 11
Dependent Claim
159 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein neodymium is present in a laseable amont up to m = 0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25, k is 0.1 to 0.35, l is zero to 0.15, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 12
Dependent Claim
159 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein neodymium is present in a laseable amont up to m = 0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25, k is 0.1 to 0.35, l is zero to 0.15, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 13
Dependent Claim
179 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.h Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25 total for all A atoms, k is 0.1 to 0.35, l is zero to 0.15, m is 0.0001 to 0.015, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 14
Dependent Claim
179 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.h Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25 total for all A atoms, k is 0.1 to 0.35, l is zero to 0.15, m is 0.0001 to 0.015, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 15
Dependent Claim
151 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein 2x plus y is always 1, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25, k is 0.1 to 0.35, m is 0.0001 to 0.015, l is zero to 0.15, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 16
Dependent Claim
151 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein 2x plus y is always 1, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25, k is 0.1 to 0.35, m is 0.0001 to 0.015, l is zero to 0.15, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
References Cited (Backward Citations)
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1982-03-05 | 1982-09-04 | 1983-03-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-03-05 | 1986-09-04 | 1987-03-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-03-05 | 1990-09-04 | 1991-03-06 | $7700.00 | Window Closed / Lapsed |