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US4142986A Expired / Lapsed US ⏱️ 0.0 years remaining

Glasses suitable for laser application

Assignee: Schott Optical Glass Inc
•
Filing: 1978-04-20
•
Granted: 1979-03-06
•
Expires: 1998-04-20
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Abstract

Abstract Disclosed are phosphorus glasses containing beryllium and fluorine and Nd 3+ as the active lasing species.

Inventors

  • 👤 Charles F. Rapp

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 12:17
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/12; C03C3/23; C03C3/247; C03C4/00; C03C4/0071

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 187 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.h Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , neodymium is present in a laseable amount up to m = 0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2 total for all A atoms, k is 0.15 to 0.3 l is zero to 0.1, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 2
Dependent Claim 187 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.h Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , neodymium is present in a laseable amount up to m = 0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2 total for all A atoms, k is 0.15 to 0.3 l is zero to 0.1, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 3
Dependent Claim 157 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein neodymium is present in a laseable amount up to m=0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2, k is 0.15 to 0.3, l is zero to 0.1, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 4
Dependent Claim 157 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein neodymium is present in a laseable amount up to m=0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2, k is 0.15 to 0.3, l is zero to 0.1, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 5
Dependent Claim 182 words
A glass composition suitable for , K as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.H 38 Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2 total for all A atoms, k is 0.15 to 0.3 l is zero to 0.1, m is 0.0001 to 0.015, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statolts) 2
Claim 6
Dependent Claim 182 words
A glass composition suitable for , K as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.H 38 Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2 total for all A atoms, k is 0.15 to 0.3 l is zero to 0.1, m is 0.0001 to 0.015, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statolts) 2
Claim 7
Dependent Claim 152 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2, k is 0.15 to 0.3, m is 0.0001 to 0.015, l is zero to 0.1, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 8
Dependent Claim 152 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.08 to 0.2, k is 0.15 to 0.3, m is 0.0001 to 0.015, l is zero to 0.1, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 9
Dependent Claim 187 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.h Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , neodymium is present in a laseable amount up to m = 0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25 total for all A atoms, k is 0.1 to 0.35, l is zero to 0.15, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 10
Dependent Claim 187 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.h Be.sub.k.sup.2+ Al.sub.1.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , neodymium is present in a laseable amount up to m = 0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25 total for all A atoms, k is 0.1 to 0.35, l is zero to 0.15, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 11
Dependent Claim 159 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein neodymium is present in a laseable amont up to m = 0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25, k is 0.1 to 0.35, l is zero to 0.15, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 12
Dependent Claim 159 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein neodymium is present in a laseable amont up to m = 0.015, 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25, k is 0.1 to 0.35, l is zero to 0.15, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 13
Dependent Claim 179 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.h Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25 total for all A atoms, k is 0.1 to 0.35, l is zero to 0.15, m is 0.0001 to 0.015, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 14
Dependent Claim 179 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula A.sub.h Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein A is at least one of the group Na 1+ , Li 1+ , K 1+ , Rb 1+ and Cs 1+ , 2x plus y is always 1, h, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25 total for all A atoms, k is 0.1 to 0.35, l is zero to 0.15, m is 0.0001 to 0.015, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 15
Dependent Claim 151 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein 2x plus y is always 1, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25, k is 0.1 to 0.35, m is 0.0001 to 0.015, l is zero to 0.15, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2
Claim 16
Dependent Claim 151 words
A glass composition suitable for use as an active laser component and consisting essentially of the following components in the relationship expressed according to the following atomic formula Na.sub.h.sup.1+ Be.sub.k.sup.2+ Al.sub.l.sup.3+ Nd.sub.m.sup.3+ P.sub.n.sup.5+ (O.sub.x.sup.2- F.sub.y.sup.1-) wherein 2x plus y is always 1, k, l, m and n represent the number of atoms to which they are subscripted with relation to the sum of x plus y, h is 0.05 to 0.25, k is 0.1 to 0.35, m is 0.0001 to 0.015, l is zero to 0.15, n is 0.02 to 0.15, and x is 2 n to 3.2 n, and wherein said glass composition has a fluorescent decay time greater than 450 microseconds at a wave length of about 1050 nm, a cross-section of stimulated emission greater than 3.3 × 10 -20 cm. 2 , and an n 2 value of less than 0.6 × 10 -13 cm. 2 /(statvolts) 2

References Cited (Backward Citations)

US2511224A Cited
US2716069A Cited
FR2304582A1 Cited
US4075120A Cited
US4076541A Cited

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