US4142895A
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Photographic color developer composition
Assignee: Agfa Gevaert AG
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Filing: 1978-01-05
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Granted: 1979-03-06
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Expires: 1998-01-05
Abstract
Abstract A color developer composition is provided which has substantially improved protection against oxidation of the color developer and excellent sequestering properties characterized in that the composition comprises an α-aminocarbonyl compound, an organo-phosphonic acid and an aminocarboxylic acid.
Inventors
- 👤 Karl Frank
- 👤 Arnfried Melzer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 18:52
CPC Classifications
G; G03; G03C; G03C5/00; G03C5/26; G03C5/29; G03C5/305
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
241 words
Photographic color developer composition for color development containing a developer compound of the p-phenylene diamine series, an antioxidizing agent comprised of an α-aminocarbonyl compound, a compound which stabilizes the antioxidizing agent and a sequestering agent, characterized in that compound which stabilizes the antioxidizing agent is a complex-forming organophosphonic acid or a water soluble salt of this acid, which inhibits decomposition of the α-aminocarbonyl compound, and the sequestering agent used is an aminocarboxylic acid or a water soluble salt of this acid and the α-aminocarbonyl compound is represented by the following general formula I or the corresponding enol form: ##STR14## in which R 1 , R 2 , R 3 and R 4 which may be the same or different, represent hydrogen; hydrocarbon groups, including alkyl, cycloalkyl or aryl groups, which groups may in turn be substituted, or 5-membered or 6-membered heterocyclic groups containing N and/or O and/or S as ring members, provided that not all four of the groups R 1 , r 2 , r 3 and R 4 may be hydrogen; on in which R 1 and R 2 together represent the atoms required to complete a heterocyclic ring and/or R 2 and R 3 together represent the atoms required to complete a heterocyclic ring and/or R 3 and R 4 together represent the atoms required to complete a heterocyclic or carbocyclic ring and/or R 4 and R 1 together represent the atoms required to complete a heterocyclic ring.
Claim 2
Dependent Claim
241 words
Photographic color developer composition for color development containing a developer compound of the p-phenylene diamine series, an antioxidizing agent comprised of an α-aminocarbonyl compound, a compound which stabilizes the antioxidizing agent and a sequestering agent, characterized in that compound which stabilizes the antioxidizing agent is a complex-forming organophosphonic acid or a water soluble salt of this acid, which inhibits decomposition of the α-aminocarbonyl compound, and the sequestering agent used is an aminocarboxylic acid or a water soluble salt of this acid and the α-aminocarbonyl compound is represented by the following general formula I or the corresponding enol form: ##STR14## in which R 1 , R 2 , R 3 and R 4 which may be the same or different, represent hydrogen; hydrocarbon groups, including alkyl, cycloalkyl or aryl groups, which groups may in turn be substituted, or 5-membered or 6-membered heterocyclic groups containing N and/or O and/or S as ring members, provided that not all four of the groups R 1 , r 2 , r 3 and R 4 may be hydrogen; on in which R 1 and R 2 together represent the atoms required to complete a heterocyclic ring and/or R 2 and R 3 together represent the atoms required to complete a heterocyclic ring and/or R 3 and R 4 together represent the atoms required to complete a heterocyclic or carbocyclic ring and/or R 4 and R 1 together represent the atoms required to complete a heterocyclic ring.
Claim 3
Dependent Claim
102 words
Color developer composition according to claim 1, containing an organo phosphonic acid or a water-soluble salt of the acid represented by the general formula R.sup.5 R.sup.6 C(PO.sub.3 M).sub.2 in which R 5 represents a hydrogen atom, an alkyl group preferably having from 1 to 4 carbon atoms, which may be substituted, an aryl group which may be substituted, an aralkyl group, an alicyclic group, a heterocyclic group or a PO 3 M 2 -group; R 6 represents a hydrogen atom, a hydroxyl group or an alkyl group which may be substituted; M represents a hydrogen atom, water-solubilizing atom, or a water-solubilizing group.
Claim 4
Dependent Claim
64 words
Colour developer composition according to claim 1, characterized in that it contains, as antioxidising agent, a compound of the following formula II ##STR15## in which R 1 to R 2 together represent the atoms required to complete a heterocyclic ring and R 3 and R 4 which may be the same or different, represent hydrogen, alkyl, including substituted alkyl groups, aryl or heterocyclic groups.
Claim 5
Dependent Claim
64 words
Colour developer composition according to claim 1, characterised in that it contains, as antioxidising agent, a compound represented by the following formula III ##STR16## in which R 1 and R 4 which may be the same or different, represent hydrogen, alkyl including substituted alkyl groups, aryl or heterocyclic groups; R 2 and R 3 together represent the atoms required to complete a heterocyclic ring.
Claim 6
Dependent Claim
67 words
Colour developer composition according to claim 1, characterized in that it contains, as antioxidising agent, a compound represented by the following formula IV: ##STR17## in which R 1 and R 2 which may be the same or different, represent hydrogen or alkyl, including substituted alkyl groups, aryl or heterocyclic groups; R 3 and R 4 together represent the atoms required to complete a heterocyclic or carbocyclic ring.
Claim 7
Dependent Claim
64 words
Colour developer composition according to claim 1, characterised in that it contains, as antioxidising agent, a compound represented by the following formula V: ##STR18## in which R 1 and R 4 together represent the atoms required to complete a heterocyclic ring, R 2 and R 3 which may be the same or different, represent hydrogen, alkyl, including substituted alkyl groups, aryl or heterocyclic groups.
Claim 8
Dependent Claim
37 words
Colour developer composition according to claim 1, characterised in that it contains at least one of the following amino carboxylic acids or a water soluble salt thereof: ethylenediaminetetraacetic acid, 2-hydroxypropane-1,3-diaminetetraacetic acid, diethylenetriaminepentaacetic acid, N-hydroxyethyl-ethylenediaminetriacetic acid, cyclohexane-1,2-diaminetetraacetic acid.
Claim 9
Dependent Claim
34 words
Colour developer composition according to claim 1, characterised in that it contains at least one of the following organophosphonic acids or a water soluble salt thereof: 1-hydroxyethane-1,1-diphosphonic acid, ethane-1,1,1-triphosphonic acid, 1-hydroxypropane-1,1-diphosphonic acid 1-hydroxy-2-phenylethane-1,1-diphosphonic acid.
Claim 10
Dependent Claim
29 words
Colour developer composition according to claim 1, characterised in that at least one of the groups represented by R 3 and R 4 is a hydroxyl substituted alkyl group.
Claim 11
Dependent Claim
15 words
Colour developer composition according to claim 1, characterised in that it contains D-glucosamine or 1-desoxy-1-piperidino-D-fructose.
Claim 12
Dependent Claim
22 words
Colour developer composition according to claim 1, characterised in that it contains 1-hydroxyethane-1,1-diphosphonic acid or a water soluble salt of this acid.
Claim 13
Dependent Claim
22 words
Colour developer composition according to claim 1, characterised in that it contains ethylenediaminetetraacetic acid or a water soluble salt of this acid.
Claim 14
Dependent Claim
24 words
Colour developer composition according to claim 1, characterised in that it contains D-glucosamine, 1-hydroxyethane-1,1-diphosphonic acid and ethylenediaminetetraacetic acid or a water soluble salt thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-03-05 | 1982-09-04 | 1983-03-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-03-05 | 1986-09-04 | 1987-03-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-03-05 | 1990-09-04 | 1991-03-06 | $7700.00 | Window Closed / Lapsed |