US4141886A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Essentially linear polymer having a plurality of amide, imide, and ester groups therein and a method of making the same
Assignee: Phelps Dodge Industries Inc
•
Filing: 1976-08-11
•
Granted: 1979-02-27
•
Expires: 1996-08-11
Abstract
Abstract An essentially linear polymer having a plurality of amide, imide and ester groups therein, which is the condensation product of (1) at least one polycarboxylic acid five member ring forming reactant, (2) at least one ethylenically unsaturated polycarboxylic acid five or six member lactam ring forming reactant, (3) at least one polyfunctional amino five or six member ring forming reactant, (4) at least one glycol, (5) at least one other polyfunctional hydroxyl compound, and (6) at least one other carboxylic acid ester reactant chosen from the group consisting of the acids, esters, anhydrides, and akylesters of terephthalic, isophthalic, and benzophenone dicarboxylic acids. The molar ratio of the functional hydroxyl groups of said glycol and hydroxyl compound to the functional ester forming carboxyl groups of said acid reactants is greater than about 1.3 to 1. The molar ratio of the functional imide-forming groups of said polycarboxylic acid five member ring forming reactant and said polyfunctional amino reactant to the functional lactam-forming groups of said ethylenically unsaturated acid reactant and said polyfunctional amino reactant are greater than about 0.5 to 1 and less than about 3.0 to 1. The molar ratio of said functional ester forming carboxyl groups to said functional imide-forming and lactam-forming groups are greater than about 1.0 to 1 and less than about 3.0 to 1. The method of forming said polymer includes placing the reactants in a solvent of the polymer having a boiling point in excess of about 150° C. such as cresylic acid, heating the reactants and solvent at atmospheric pressure from about 120° C. to about 220° C., adding a suitable condensation catalyst after a reaction commences, and diluting or cooling resulting polymer solution to terminate the reaction.
Inventors
- 👤 George H. Sollner
- 👤 Keith D. Bultemeier
- 👤 Richard D. Remaks
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 12:28
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/16; C08G69/00; C08G69/44; C08G73/1075; C08G73/1082; H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/303; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31681
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
216 words
An essentially linear resin having a plurality of amide, imide and ester groups therein and the physical mechanical, chemical and electrical properties of a magnet wire insulation material comprising the condensation product of at least one polycarboxylic acid five member ring forming reactant, at least one ethylenically unsaturated polycarboxylic acid five or six member lactam ring forming reactant, at least one polyfunctional amino five or six member ring forming reactant, at least one glycol, at least one other polyfunctional hydroxyl compound, at least one carboxylic acid ester reactant chosen from the group consisting of the acids, esters, anhydrides, and akylesters of terephthalic, isophthalic and benzophenone dicarboxylic acids, the molar ratio of the functional hydroxyl groups of said glycol and hydroxyl compound to the functional ester-forming carboxyl groups of said acid reactants being greater than about 1.3 to 1, the molar ratio of the functional imide-forming groups of said polycarboxylic acid five member ring forming reactant and said polyfunctional amino reactants to the functional lactam-forming groups of said ethylenically unsaturated acid and polyfunctional amino reactants being greater than about 0.5 to 1 and less than about 3.0 to 1, the molar ratio of said ester-forming groups to said functional imide-forming and lactam-forming groups being greater than about 1.0 to 1 and less than about 3.0 to 1.
Claim 2
Dependent Claim
216 words
An essentially linear resin having a plurality of amide, imide and ester groups therein and the physical mechanical, chemical and electrical properties of a magnet wire insulation material comprising the condensation product of at least one polycarboxylic acid five member ring forming reactant, at least one ethylenically unsaturated polycarboxylic acid five or six member lactam ring forming reactant, at least one polyfunctional amino five or six member ring forming reactant, at least one glycol, at least one other polyfunctional hydroxyl compound, at least one carboxylic acid ester reactant chosen from the group consisting of the acids, esters, anhydrides, and akylesters of terephthalic, isophthalic and benzophenone dicarboxylic acids, the molar ratio of the functional hydroxyl groups of said glycol and hydroxyl compound to the functional ester-forming carboxyl groups of said acid reactants being greater than about 1.3 to 1, the molar ratio of the functional imide-forming groups of said polycarboxylic acid five member ring forming reactant and said polyfunctional amino reactants to the functional lactam-forming groups of said ethylenically unsaturated acid and polyfunctional amino reactants being greater than about 0.5 to 1 and less than about 3.0 to 1, the molar ratio of said ester-forming groups to said functional imide-forming and lactam-forming groups being greater than about 1.0 to 1 and less than about 3.0 to 1.
Claim 3
Dependent Claim
33 words
The resin of claim 1 wherein said polycarboxylic acid five member ring forming reactant is chosen from the group consisting of tricarboxylic and tetracarboxylic acids, the anhydrides thereof, and combinations of the same.
Claim 4
Dependent Claim
42 words
The resin of claim 1 wherein said polycarboxylic acid five member ring forming reactant is chosen from the group consisting of trimellitic; pyromellitic; 2,3,6,7 naphthalene tetracarboxylic; benzophenone 2,3,2',3' tetracarboxylic; and 3,3',4,4' diphenyl tetracarboxylic acids, the anhydrides of said acids and combinations thereof.
Claim 5
Dependent Claim
24 words
The resin of claim 1 wherein said ethylenically unsaturated reactant is chosen from the group consisting of itaconic or aconitic acid and combinations thereof.
Claim 6
Dependent Claim
57 words
The resin of claim 1 wherein said polyfunctional hydroxyl compound is chosen from the group consisting of ethylene glycol, glycerin, pentaerythrytol, 1,1,1 trimethylol ethane, 1,1,1 trimethylol propane, zorbitol, manitol, dipentaerythritol, and α, ω aliphatic hydrocarbon diols having four to five carbon atoms; hydroquinone dibetahydroxy ethyl ether; 1,4 cyclohexane dimethylol; polyethylene glycol; polytetramethylene oxide glycol and combination thereof.
Claim 7
Dependent Claim
28 words
The resin of claim 1 wherein said molar ratio of said hydroxyl groups to said ester-forming groups is from about 1.3 to 1 to about 1.6 to 1.
Claim 8
Dependent Claim
26 words
The resin of claim 1 wherein said molar ratio of said imide-forming to lactam-forming groups is from about 1.0 to 1 to about 2.5 to 1.
Claim 9
Dependent Claim
30 words
The resin of claim 1 wherein said molar ratio of said ester-forming groups to said imide-forming and lactam-forming groups is from about 1.3 to 1 to about 2.5 to 1.
Claim 10
Dependent Claim
28 words
The resin of claim 8 wherein said molar ratio of said hydroxyl groups to said ester-forming groups is from about 1.34 to 1 to about 1.40 to 1.
Claim 11
Dependent Claim
40 words
The resin of claim 9 wherein said molar ratio of said imide-forming groups to lactam-forming groups is about 2 to 1, and said molar ratio of said ester-forming groups to said imide and lactam-forming groups is about 2 to 1.
Claim 12
Dependent Claim
26 words
The resin of claim 10 comprising essentially of the condensation product of trimellitic acid anhydride, itaconic acid, methylene dianiline, ethylene glycol, 1,1,1-trimethylol propane and dimethyl isophthalate.
Claim 13
Independent Claim
251 words
A method of forming a polymer having reocurring amide, imide and ester groups therein comprising the steps of placing in a solvent for said polymer, at least one glycol, at least one polyfunctional hydroxyl compound, at least one carboxylic acid ester forming reactant chosen from the groups consisting of the acids, esters, anhydrides, and alkylesters of terephthalic, isophthalic and benzophenone dicarboxylic acids, reacting said glycol and hydroxyl compound and carboxylic acid ester forming reactant, thereby forming a solution of a reaction product, placing in said solution said reaction product, at least one polycarboxylic acid five member ring forming reactant, at least one ethylenically unsaturated polycarboxylic acid five or six member lactam ring forming reactant, at least one polyfunctional amino five or six member ring forming reactant, the molar ratio of the functional hydroxyl groups of said glycol and hydroxyl compound to the functional ester-forming carboxyl groups of said acid reactants being greater than about 1.3 to 1, the molar ratio of the functional imide-forming groups of said polycarboxylic acid five member ring forming reactant and said polyfunctional amino reactant to the functional lactam-forming groups of said ethylenically unsaturated acid and polyfunctional amino reactants being greater than about 0.5 to 1 and less than about 3.0 to 1, the molar ratio of said functional ester-forming groups to said functional imide-forming and lactam-forming groups being greater than about 1.0 to 1 and less than about 3.0 to 1, thereby forming a reaction mixture, reacting said mixture in the presence of a condensation catalyst.
Claim 14
Independent Claim
251 words
A method of forming a polymer having reocurring amide, imide and ester groups therein comprising the steps of placing in a solvent for said polymer, at least one glycol, at least one polyfunctional hydroxyl compound, at least one carboxylic acid ester forming reactant chosen from the groups consisting of the acids, esters, anhydrides, and alkylesters of terephthalic, isophthalic and benzophenone dicarboxylic acids, reacting said glycol and hydroxyl compound and carboxylic acid ester forming reactant, thereby forming a solution of a reaction product, placing in said solution said reaction product, at least one polycarboxylic acid five member ring forming reactant, at least one ethylenically unsaturated polycarboxylic acid five or six member lactam ring forming reactant, at least one polyfunctional amino five or six member ring forming reactant, the molar ratio of the functional hydroxyl groups of said glycol and hydroxyl compound to the functional ester-forming carboxyl groups of said acid reactants being greater than about 1.3 to 1, the molar ratio of the functional imide-forming groups of said polycarboxylic acid five member ring forming reactant and said polyfunctional amino reactant to the functional lactam-forming groups of said ethylenically unsaturated acid and polyfunctional amino reactants being greater than about 0.5 to 1 and less than about 3.0 to 1, the molar ratio of said functional ester-forming groups to said functional imide-forming and lactam-forming groups being greater than about 1.0 to 1 and less than about 3.0 to 1, thereby forming a reaction mixture, reacting said mixture in the presence of a condensation catalyst.
Claim 15
Dependent Claim
65 words
The method of claim 12 wherein said ratio of said ester-forming groups to said imide-forming and lactam-forming groups is from about 1.3 to 1 to about 2.5 to 1, said ratio of said hydroxyl groups to said ester-forming groups is from about 1.34 to 1 to about 1.40 to 1, and said ratio of said imide-forming groups to lactam-forming groups is about 2 to 1.
Claim 16
Dependent Claim
58 words
The resin of claim 5, wherein said aliphatic hydrocarbon diols having four to five carbon atoms are chosen from the group consisting of 1,4 butane diol; 1,5 pentane glycol; neopentylene glycol; (1,4-butene-2-diol) propylene glycol; and wherein said cyclic glycols are chosen from the group consisting of 2,2,4,4 tetramethyl 1,3 cyclobutane diol and tris(2hydroxy ethyl) isocyanurate and combinations thereof.
Claim 17
Dependent Claim
26 words
The method of claim 12 wherein both of said reacting steps are accomplished at atmospheric pressure and a temperature from about 120° to about 220° C.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-02-26 | 1982-08-28 | 1983-02-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-02-26 | 1986-08-28 | 1987-02-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-02-26 | 1990-08-28 | 1991-02-27 | $7700.00 | Window Closed / Lapsed |