US4141876A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Adhesive composition containing a polyphenylene ether resin
Assignee: Shell USA Inc
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Filing: 1977-09-23
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Granted: 1979-02-27
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Expires: 1997-09-23
Abstract
Abstract An adhesive composition having greatly improved high temperature properties is prepared by melt blending a polyphenylene ether resin, a selectively hydrogenated arene/conjugated diene block copolymer, tackifying resin, and optional hydrocarbon processing oil.
Inventors
- 👤 David R. Hansen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 15:33
CPC Classifications
C; C09; C09J; C09J153/00; C09J153/02; C09J153/025; C09J7/00; C09J7/20; C09J7/21; C09J7/22; C09J7/30; C09J7/38; C09J7/381; C09J7/387; C08; C08L; C08L2666/00; C08L2666/02
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
164 words
A hot melt adhesive composition comprising: (a) 100 parts by weight of a block copolymer having at least two polymer end blocks A and at least one polymer mid block B, each block A being a monoalkenyl arene polymer block having an average molecular weight of between about 2,000 and about 50,000, and each block B being an elastomeric hydrogenated polymer block of a conjugated diene, having an average molecular weight of between about 20,000 and about 300,000, said blocks A comprising 8-55% by weight of the block copolymer; (b) about 50 to about 200 parts by weight of a tackifying resin compatible with block B; (c) about 0 to about 200 parts by weight of a hydrocarbon extending oil; and (d) about 1 to about 100 parts by weight of a low molecular weight polyphenylene ether resin having a molecular weight (M vis ) of between about 6,000 and about 25,000 and a glass transition temperature of between 170° C. and 200° C.
Claim 2
Dependent Claim
164 words
A hot melt adhesive composition comprising: (a) 100 parts by weight of a block copolymer having at least two polymer end blocks A and at least one polymer mid block B, each block A being a monoalkenyl arene polymer block having an average molecular weight of between about 2,000 and about 50,000, and each block B being an elastomeric hydrogenated polymer block of a conjugated diene, having an average molecular weight of between about 20,000 and about 300,000, said blocks A comprising 8-55% by weight of the block copolymer; (b) about 50 to about 200 parts by weight of a tackifying resin compatible with block B; (c) about 0 to about 200 parts by weight of a hydrocarbon extending oil; and (d) about 1 to about 100 parts by weight of a low molecular weight polyphenylene ether resin having a molecular weight (M vis ) of between about 6,000 and about 25,000 and a glass transition temperature of between 170° C. and 200° C.
Claim 3
Dependent Claim
25 words
A composition according to claim 1 wherein the various components are melt blended at a temperature of between about 230° C. and about 260° C.
Claim 4
Dependent Claim
15 words
A composition according to claim 1 wherein the polyphenylene ether resin is poly (2,6-dimethyl-1,4-phenylene) ether.
Claim 5
Dependent Claim
26 words
A composition according to claim 1 wherein the monoalkenyl arene is styrene and the conjugated diene is selected from the group consisting of isoprene and butadiene.
Claim 6
Dependent Claim
41 words
A composition according to claim 4 wherein the number average molecular weight of the styrene blocks is between about 8,000 and about 35,000, and the number average molecular weight of the conjugated diene blocks is between about 25,000 and about 150,000.
Claim 7
Dependent Claim
23 words
A composition according to claim 4 wherein the block copolymer has the structure A-B-B-A) n , where n varies from 1 to 20.
Claim 8
Dependent Claim
22 words
A composition according to claim 1 wherein the amount of component d) is between about 5 and about 50 parts by weight.
Claim 9
Dependent Claim
46 words
A composition according to claim 1 including between about 0 and about 200 parts by weight of a high softening point resin compatible with block A, said high softening point resin being selected from the group consisting of coumarone-indene resins, vinyl toluene-alphamethylstyrene copolymers and polyindene resins.
Claim 10
Dependent Claim
23 words
A composition according to claim 1 wherein the amount of hydrocarbon extending oil is between about 25 and about 150 parts by weight.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-02-26 | 1982-08-28 | 1983-02-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-02-26 | 1986-08-28 | 1987-02-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-02-26 | 1990-08-28 | 1991-02-27 | $7700.00 | Window Closed / Lapsed |