Heat hardenable powder coatings based on polyester resins containing carboxyl groups

Claim 2

A heat hardenable powder coating composition comprising a carboxy group containing polyester resin having an acid number between about 40 and about 100 mg KOH/g and a softening point of 70°-105° C., a 1,2-polyepoxide compound which is solid at room temperature and has at least 2 epoxide groups per molecule and a catalytic amount of a catalyst, said catalyst being a titanium or zirconium chelate which is solid at room temperature, said chelate having the formula ##STR2## wherein R is a propylene moiety which is substituted asymetrically by at least one alkyl group, R' is hydrogen, alkyl or hydroxyalkyl of up to 10 carbon atoms, cycloalkyl or hydroxycycloalkyl, or aralkyl or hydroxyaralkyl and Me is zirconium or titanium.

Claim 3

A composition according to claim 1 wherein the chelate is the reaction product of a titanium or zirconium alcoholate with 2 to 4 moles of a branched 1,3-diol.

Claim 4

A composition according to claim 2 wherein said diol is a diol having 2 to 3 alkyl substituents.

Claim 5

A composition according to claim 3 wherein said diol was selected from the group consisting of 2,2,4-trimethylpentanediol-1,3, 2-methylpentanediol-2,4, 2-ethylhexanediol-1,3, 2-methylpentanediol-1,3, 2-methyl-5-propylheptanediol-1,3 and mixtures thereof.

Claim 6

A composition according to claim 3 wherein said 1,3-diol is in admixture with another diol.

Claim 7

A composition according to claim 5 wherein said other diol is selected from the group consisting of ethyleneglycol, butanediol-1,4, hexanediol-1,6, cyclohexanedimethanol-1,4, bis-(2-hydroxyethoxy)-diphenylolpropane and p-xylylene glycol.

Claim 8

A composition according to claim 5 wherein said other diol is in admixture with a monoalcohol.

Claim 9

A composition according to claim 7 wherein said monoalcohol is selected from the group consisting of 2-ethylhexanol and benzyl alcohol.

Claim 10

A composition according to claim 3 wherein the 1,3-diol is 2,2,4-trimethylpentanediol-1,3 and the same is in admixture with cyclohexanedimethanol-1,4, bis-(2-hydroxyethoxy)-diphenylolpropane, hexanediol-1,6 or butanediol-1,4.

Claim 11

A composition according to claim 1 containing a pigment, filler or mixture thereof.

Claim 12

A composition according to claim 1 containing and additive, adjuvant or mixture thereof.

Claim 13

A composition according to claim 1 wherein the polyepoxide compound is one selected from the group consisting of solid bis-glycidyl ethers based on 4,4'-dioxyphenyl-2,2-propane or 1,2-epoxy-3-chloropropane, the epoxy resins, polyglycidylethers of phenyl-formaldehyde or cresol-formaldehyde novolacs, triglycidyl isocyanurate, the diglycidyl esters of the isomeric phthalic acids, the triglycidyl ester of trimellitic acid and the tetraglycidyl ester of pyromellitic acid.

Claim 14

A composition according to claim 1 wherein the carboxyl group containing polyester resin is one derived from the condensation of a polybasic aromatic, cycloaliphatic or aralphatic carboxylic acid with a polyvalent alcohol.

Claim 15

A composition according to claim 1 wherein the carboxyl group containing polyester resin is one obtained by the condensation of terephthalic acid, terephthalic acid dimethyl ester, isophthalic acid, phthalic acid, phthalic acid anhydride, trimellitic acid, trimellitic acid anhydride, pyromellitic acid, pyromellitic acid anhydride, tetrahydrophthalic acid, hexahydrophthalic acid, tetrahydrophthalic acid anhydride, hexahydrophthalic acid anhydride, adipic acid, azelaic acid or sebacic acid with a polyvalent alcohol selected from the group consisting of pentaerythritol, trimehylolethane, trimethylolpropane, glycerine, tris-hydroxyethylisocyanurate, ethylene glycol, propanediol-1,2, neopentylglycol, butanediol-1,3, butanediol-1,4, hexanediol-1,6, cyclohexanedimethanol, ethoxylated bisphenol A, and hydrogenated bisphenol A.

Claim 16

A composition according to claim 1 wherein the carboxyl group containing polyester and polyepoxide compound are present in a weight ratio to one another between 25:75 and 75:25.

Claim 17

A composition according to claim 17 wherein the carboxyl group containing polyester and polyepoxide compounds are present in a ratio of 50:50 parts by weight.

Claim 18

A composition according to claim 1 wherein the titanium or zirconium chelate is present in an amount of from 0.5 to 2% by weight.

Claim 19

A heat hardenable powder coating composition according to claim 1 wherein a mixture of titanium and zirconium chelates is employed as catalyst.