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US4140677A Expired / Lapsed US ⏱️ 0.0 years remaining

Shaped article of polymers prepared from (β-hydroxyethyl)-trimellitic acid imide

Assignee: Toyobo Co Ltd
•
Filing: 1977-06-10
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Granted: 1979-02-20
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Expires: 1997-06-10
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Abstract

Abstract A shaped article having a refractive index of not less than 1.625 at least in one direction and possessing excellent physical properties and various uses, which can be prepared by stretching a molded product, which is made of a polymeric material comprising at least 80 mol% of the repeating units of the formula: ##STR1## and having an intrinsic viscosity of not less than 0.25 dl/g when measured in a mixture of phenol and sym.-tetrachloroethane in a weight ratio of 6 : 4 at 30° C. and has a refractive index of not more than 1.610 at least in one direction, at a temperature of 120° to 230° C. with a stretch ratio of 2 to 20 in the same direction as the refractive index is measured, or by melt extruding the polymeric material at a temperature higher than 230° C. and not higher than 360° C. while or immediately followed by stretching with a deformation speed of not less than 20 times the speed of the melt extrusion.

Inventors

  • 👤 Keiichi Uno
  • 👤 Hikoichi Nagano
  • 👤 Tsuyoshi Hongo
  • 👤 Takahito Miyagawa
  • 👤 Koichi Matsunami

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 23:34
CPC Classifications
D; D01; D01F; D01F6/00; D01F6/58; D01F6/62; C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/16; D01F6/74

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 225 words
A shaped article, which is made of a polymeric material comprising at least 80 mol % of the repeating units of the formula: Table 4 ______________________________________ Run No. 9 (heat set) 10 (not heat set) Longitudi- Trans- Longitudi- Trans- Physical nal dir- verse nal dir- verse proper- ec direc- ec- direc- ties tion tion tion tion ______________________________________ Density (g/cm.sup.3) 1.448 1.435 Refractive index 1.693 1.652 1.700 1.663 Strength at break (kg/mm.sup.2) 20° C. 36.2 27.4 37.4 29.5 150° C. 25.3 19.4 -- -- Elongation at break (%) 20° C. 21 46 27 51 150° C. 54 68 -- -- Young's modulus 673 494 658 453 (kg/mm.sup.2) Degree of heat 2.7 2.3 38 27 shrinkage (%) Thickness of film 14 14 (μ) ______________________________________ and having (a) an intrinsic viscosity of not less than 0.25 dl/g when measured in a mixture of phenol and sym.-tetrachloroethane in a weight ratio of 6:4 at 30° C., (b) a refractive index of not less than 1.625 at least in one direction, (c) a density of not less than 1.430 g/cm 3 , and (d) the following physical values at 20° C. in the direction in which the refractive index is measured: (i) a tensile strength at break of 15 to 150 kg/mm 2 (ii) a Young's Modulus of 300 to 3,000 kg/mm 2 , and (iii) an elongation of 1-200%.
Claim 2
Dependent Claim 225 words
A shaped article, which is made of a polymeric material comprising at least 80 mol % of the repeating units of the formula: Table 4 ______________________________________ Run No. 9 (heat set) 10 (not heat set) Longitudi- Trans- Longitudi- Trans- Physical nal dir- verse nal dir- verse proper- ec direc- ec- direc- ties tion tion tion tion ______________________________________ Density (g/cm.sup.3) 1.448 1.435 Refractive index 1.693 1.652 1.700 1.663 Strength at break (kg/mm.sup.2) 20° C. 36.2 27.4 37.4 29.5 150° C. 25.3 19.4 -- -- Elongation at break (%) 20° C. 21 46 27 51 150° C. 54 68 -- -- Young's modulus 673 494 658 453 (kg/mm.sup.2) Degree of heat 2.7 2.3 38 27 shrinkage (%) Thickness of film 14 14 (μ) ______________________________________ and having (a) an intrinsic viscosity of not less than 0.25 dl/g when measured in a mixture of phenol and sym.-tetrachloroethane in a weight ratio of 6:4 at 30° C., (b) a refractive index of not less than 1.625 at least in one direction, (c) a density of not less than 1.430 g/cm 3 , and (d) the following physical values at 20° C. in the direction in which the refractive index is measured: (i) a tensile strength at break of 15 to 150 kg/mm 2 (ii) a Young's Modulus of 300 to 3,000 kg/mm 2 , and (iii) an elongation of 1-200%.
Claim 3
Dependent Claim 48 words
The shaped article according to claim 1, which has a degree of oriented crystallinity of not less than 10% with respect to the X-ray diffraction pattern obtained by irradiating the X-rays from the direction in a right angle to the direction in which the refractive index is measured.
Claim 4
Dependent Claim 42 words
The shaped article according to claim 1, which has the following physical values at 150° C. in the direction in which the refractive index is measured: Tensile strength at break = 5 to 50 kg/mm 2 ; Elongation = 3 to 300%.
Claim 5
Dependent Claim 26 words
The shaped article according to claim 1, wherein the polymeric material has a carboxyl group content of not more than 70 equivalents per 10 6 g.
Claim 6
Dependent Claim 21 words
The shaped article according to claim 1, wherein the intrinsic viscosity of the polymeric material is from 0.3 to 0.8 dl/g.
Claim 7
Dependent Claim 13 words
The shaped article according to claim 1, which is in a fibrous form.
Claim 8
Dependent Claim 23 words
The shaped article according to claim 1, which is in the form of fiber having a diameter of 0.1 micron to 5 mm.
Claim 9
Dependent Claim 13 words
The shaped article according to claim 1, which is in a filmy form.
Claim 10
Dependent Claim 23 words
The shaped article according to claim 8, which is in the form of film having a thickness of 1 micron to 5 mm.
Claim 11
Dependent Claim 14 words
The shaped article according to claim 1, which is in a hollow body form.
Claim 12
Dependent Claim 25 words
The shaped article according to claim 10, which is in the form of hollow body having a film thickness of 1 micron to 5 mm.

References Cited (Backward Citations)

US3060191A Cited
US3733302A Cited
US3880812A Cited
US4070524A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-02-19 1982-08-21 1983-02-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-02-19 1986-08-21 1987-02-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-02-19 1990-08-21 1991-02-20 $7700.00 Window Closed / Lapsed

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